Search Results (7)

The continuous cooling transformation (CCT) curves of undercooled austenite serve as crucial references for obtaining desired microstructures and properties in metallic materials (particularly deformed metals) through heat treatment. In this study, static and dynamic CCT curves were constructed for experimental steels micro-doped with rare earth element Ce by combining temperature-dilatometric curves recorded after austenitization at 900 °C with microstructural characterization and microhardness measurements. Comparative analyses were conducted on the microstructures and microhardness of three experimental steels with varying Ce contents subjected to sizing (reducing) diameter deformation at 850 °C and 950 °C. The CCT experimental results revealed that the microhardness of the tested steels increased with cooling rates. Notably, dynamic CCT specimens cooled at 50 °C/s to room temperature following superheated deformation exhibited 56.7 HV5 higher microhardness than static CCT specimens, accompanied by increased martensite content. The reduction of deformation temperature from 950 °C to 850 °C resulted in the expansion of the bainitic phase region. The incorporation of trace Ce elements demonstrated a significant enhancement in the microhardness of 30MnNbRE steel. This research proposes an effective processing route for improving strength-toughness combination in microalloyed oil well tubes: introducing trace Ce additions followed by sizing (reducing) diameter deformation at 950 °C and subsequent ultra-fast cooling at 50 °C/s to room temperature. This methodology facilitates the production of high-strength/toughness steels containing abundant martensitic microstructures. Full article

In high-speed steel, carbides are essential phase constituents, which have a direct impact on engineering performance and qualities of high-speed steel. The formation, morphology, and distribution of carbides are dictated by alloying elements. In this paper, various types of carbides in high-speed steel are presented. The effects of different alloying elements such as C, W, Mo, Cr, and V on the formation of carbides in high-speed steel are discussed. Research progresses on carbide improvement by microalloying elements such as N, B, Mg, and rare earth (RE) elements are reviewed. It is reported that Cr promotes the precipitation of M₂C, N enhances the formation of fibrous M₂C, Mg effectively shatters the large-size carbide grid, Nb refines granular carbide MC, and rare earth elements encourage the formation of M₆C, resulting in irregular M₂C lamellae. The incorporation of microalloying elements improves the distribution and size of carbides and also refines the solidification structure of high-speed steel. Full article

Microalloying and heat treatment have been regarded as an efficient way to get higher wear resistance in high manganese steel, and multiscale precipitates can be obtained randomly by the aging process; however, most of the previous work on heat treatment was more concerned with peak aging time and not the synergistic mechanism of different sized precipitates. Here, we propose a novel wear-resistant mechanism by multiscale precipitates regulated via a retrogression and re-aging (RRA) process. Micron, submicron, and nano precipitates are obtained by the RRA process and jointly form micro-scale ultrafine precipitation zones (MUPZs), which can protect the matrix surface and reduce the abrasive embedded probability, thus ameliorating the micro-cutting and micro-plowing mechanisms. This novel wear-resistant mechanism induced by MUPZs shows better effect under high impact energy due to sufficient work hardening caused by the interaction between dislocations and multi-scale precipitates in MUPZs. This work was investigated using SEM, EDS, and TEM, combined with mechanical properties and impact abrasive wear tests. Full article

This laboratory study aimed to reveal the inner connects between the microstructure and corrosion properties of a RE microalloyed ultra-thin cast strip (UCS) steel. The microstructure mainly consisted of homogeneous polygonal ferrite (PF) with a small amount of pearlite (P), while adding multiple alloying elements led to the appearance of granular bainite (GB) and bainitic ferrite (BF). RE elements strongly promoted the homogenization and refinement of microstructure by segregating towards the solid–liquid interface. Potentiodynamic polarization, EIS, and weight loss curves under wet–dry immersion test confirmed that the corrosion behavior was significantly improved by RE, while the addition of RE had no obvious change on tensile strength. The corrosion resistance of the homogeneous single-phase microstructure was proved to be better than that of multiphase microstructure. Hence, RE had a remarkable influence on improving corrosion resistance when the experimental steels processed single-phase microstructures. Full article

Shielded metal arc welding and welding thermal simulation experiment were carried out for constructional steel containing 0% V and 0.10% V, and the microstructure, precipitation feature, microhardness HV0.2, and −20 °C impact value in the welding heat affected zone (HAZ) were investigated. The results showed that in the coarse-grained heat affected zone (CGHAZ), V and N were completely dissolved in the matrix of steel containing 0.10% V to promote the growth of prior austenite grains, meanwhile the fraction of high angle grain boundaries (HAGBs) decreased, thereby leading to the mean −20 °C impact value decreases from 87 J to 18 J. In the grain refined heat affected zone (GRHAZ), V(C, N) precipitates experience re-dissolution and re-precipitation at grain boundaries, V–N microalloying changes the microstructure from lath bainite + granular bainite + small amount of polygonal ferrite to polygonal ferrite + pearlite + martensite, thereby leading to the mean microhardness decreases from 335 HV0.2 to 207 HV0.2, and the mean −20 °C impact value decreased from 117 J to 103 J. In the intercritical heat affected zone (ICHAZ), V(C, N) precipitates experience re-dissolution, re-precipitation, and growth, causing the formation of micro-sized V(C, N) precipitates, thereby leading to the mean −20 °C impact value decreases from 93 J to 62 J. Full article

In this study, the corrosion behavior of rare earth (RE) microalloyed steels was first evaluated through potentiodynamic polarization tests and corrosion weight loss experiments, and then the corrosion morphologies were observed by scanning electron microscope (SEM). After immersion in a NaCl solution, the sulfides (or oxygen sulfides) dissolved preferentially, followed by corrosion at the boundary between the Fe matrix and oxides. Afterwards, the inclusions fell off as a whole, which promoted pitting nucleation. The first principle modeling demonstrated that the work functions of various kinds of inclusions descended in the following order: La₂Zr₂O₇ > LaAlO₃ > (La₂O₃ ≈ Fe ≈ La₂O₂S) > La₂S₃, which provided a theoretical explanation to the dissolution behaviors of inclusions. That is, inclusions containing sulfur tend to dissolve preferentially, whereas the oxides do not dissolve easily. Subsequently, the surface current distributions were detected by the scanning vibrating electrode technique (SVET), which provided more microscopic insight into the role of inclusions in the corrosion propagation. Results showed that the active sites of pitting nucleation accelerated the transverse propagation of corrosion. Finally, local corrosion spread to the whole surface as uniform corrosion. Full article

The main role of Rare Earth (RE) elements in the steelmaking industry is to affect the nature of inclusions (composition, geometry, size and volume fraction), which can potentially lead to the improvement of some mechanical properties such as the toughness in steels. In this study, different amounts of RE were added to a niobium microalloyed steel in as-cast condition to investigate its influence on: (i) type of inclusions and (ii) precipitation of niobium carbides. The characterization of the microstructure by optical, scanning and transmission electron microscopy shows that: (1) the addition of RE elements change the inclusion formation route during solidification; RE > 200 ppm promote formation of complex inclusions with a (La,Ce)(S,O) matrix instead of Al₂O₃-MnS inclusions; (2) the roundness of inclusions increases with RE, whereas more than 200 ppm addition would increase the area fraction and size of the inclusions; (3) it was found that the presence of MnS in the base and low RE-added steel provide nucleation sites for the precipitation of coarse niobium carbides and/or carbonitrides at the matrix–MnS interface. Thermodynamic calculations show that temperatures of the order of 1200 °C would be necessary to dissolve these coarse Nb-rich carbides so as to reprecipitate them as nanoparticles in the matrix. Full article