Search Results (93)

The problem of the conversion of diesel buses to electric ones in connection with the inevitable introduction of the EURO 7 emission standards entails an automatic requirement to follow several additional United Nations Economic Commission for Europe rules, like R100 regulations. They regulate the preservation of battery units at longitudinal 12 g and transverse 10 g accelerations without penetrating into the elements of the bus body. Three models (12 modes in total) of battery units with frames made of S235 steel were analysed. The maximum stress value varies between 364.89 MPa and 439.08 MPa in 10 g and 12 g modes, respectively, which is beyond the tensile strength (360 MPa) and provokes plastic deformations. The max deformations were recorded in the models with the highest average stress: 63.04 mm in the 12 g mode with an average stress of 83.18 MPa. The minimum deformations of 6.95 and 7.95 mm were found in the 10 g modes (left and right acceleration direction, respectively), which meet the manufacturer’s requirements (45–50 mm maximum). The study’s primary contribution lies in developing a practical method for assessing battery unit integrity and structural behaviour during the conversion of diesel buses to electric propulsion, fully compliant with R100 regulations. By combining transient structural simulation, mathematical centre modelling of acceleration propagation, and centre of gravity prediction, the proposed approach enables engineers to evaluate electric conversions’ safety and certification feasibility without modifying the existing bus body. Full article

This study presents the design and techno-economic comparison of two standalone photovoltaic (PV) systems, each supplying a 1 kW critical load with 100% reliability under Cairo’s climatic conditions. These systems are modeled for both the constant and the night load scenarios, accounting for the worst-case weather conditions involving 3.5 consecutive cloudy days. The primary comparison focuses on traditional lead-acid battery storage versus green hydrogen storage via electrolysis, compression, and fuel cell reconversion. Both the configurations are simulated using a Python-based tool that calculates hourly energy balance, component sizing, and economic performance over a 21-year project lifetime. The results show that the PV/H₂ system significantly outperforms the PV/lead-acid battery system in both the cost and the reliability. For the constant load, the Levelized Cost of Electricity (LCOE) drops from 0.52 USD/kWh to 0.23 USD/kWh (a 56% reduction), and the payback period is shortened from 16 to 7 years. For the night load, the LCOE improves from 0.67 to 0.36 USD/kWh (a 46% reduction). A supplementary cost analysis using lithium-ion batteries was also conducted. While Li-ion improves the economics compared to lead-acid (LCOE of 0.41 USD/kWh for the constant load and 0.49 USD/kWh for the night load), this represents a 21% and a 27% reduction, respectively. However, the green hydrogen system remains the most cost-effective and scalable storage solution for achieving 100% reliability in critical off-grid applications. These findings highlight the potential of green hydrogen as a sustainable and economically viable energy storage pathway, capable of reducing energy costs while ensuring long-term resilience. Full article

In this study, the lithium-ion (Li-ion) battery type, which has a high-power density and utilizes lithium as the primary conductive terminal, has been employed. Within the scope of this research, a one-dimensional isothermal Li-ion battery model has been investigated under various electrolyte (both liquid and solid) and electrode materials using the COMSOL Multiphysics software. The obtained simulation results have been corroborated with information sourced from the literature and establish a foundational framework for future studies. The average range of electrolyte salt concentration in battery components is slightly higher for batteries utilizing polymer electrolytes compared to those with liquid electrolytes. During discharge at five different C-rates, Li-ion batteries with liquid electrolytes displayed higher voltage than those with polymer electrolytes. On the other hand, the one with the lithium iron phosphate (LFP) positive electrode exhibits the greatest variation in lithium concentration at the surface of the positive electrode at the end of discharge. Conversely, the battery using a LiNiO₂ cathode shows the smallest surface lithium concentration variation during the same period. This pattern is similarly observed for the lithium concentration at the center of the electrode particles. The presented model can be used to explore innovative electrolyte and electrode materials to improve the design of Li-ion batteries. Full article

The rising demand for lithium-ion batteries (LIBs), driven by the growing consumption of electronic devices and the expansion of electric vehicles, is leading to a concerning depletion of primary metal resources and a significant accumulation of electronic waste. This urgent challenge highlights the need for sustainable recovery methods to extract valuable metals from spent LIBs, aligning with circular economy principles. In this study, the preparation of spent batteries for the bioleaching process was achieved with minimal manipulation. This included a preliminary discharge to ensure safety in subsequent processes and a brief crushing to facilitate the access of leaching agents to valuable metals. Unlike most studies that grind batteries to obtain powders between 70 and 200 microns, our approach works with particles sized around 5 mm. Additionally, our preparation process avoids any thermal or chemical treatments. This straightforward pre-treatment process marks a significant advancement by reducing the complexity and cost of processing. A systematic study was conducted on various fractions of the large particle sizes, using Fe (III) produced through bio-oxidation by A. ferrooxidans and biogenically obtained H2SO4 from A. thiooxidans. The highest metal extraction rates were achieved using the unsorted fraction, directly obtained from the black mass after the grinding process, without additional particle separation. When treated with bio-oxidized Fe (III), this fraction achieved a 95% recovery of Cu, Ni, and Al within 20 min, and over 90% recovery of Co, Mn, and Li within approximately 30 min. These recovery rates are attributed to the combined reducing power of Al and Cu already present in the black mass and the Fe (II) generated during the oxidation reactions of metallic Cu and Al. These elements actively facilitate the reduction of transition metal oxides into their more soluble, lower-valence states, enhancing the overall metal solubilization process. The extraction was carried out at room temperature in an acidic medium with a pH no lower than 1.5. These results demonstrate significant potential for efficient metal recovery from spent batteries with minimal pre-treatment, minimizing environmental impact. Additionally, the simplified residue preparation process can be easily integrated into existing waste management facilities without the need for additional equipment. Full article

Li/graphite fluoride (Li/CF_x) batteries display the highest energy densities among those of commercially available primary Li batteries but fail to satisfy the high-performance requirements of advanced applications. To address this drawback, two liquid organic dinitrates, namely, 1,4-butanediol dinitrate (BDE) and 2,2,3,3-tetrafluoro-1,4-butanediol dinitrate (TBD), were employed as high-energy energetic materials, and they were highly compatible with the electrolytes of Li/CF_x batteries. The use of Super P electrodes confirmed that the reduction reaction mechanisms of both nitrate ester-based compounds delivered considerable specific capacities, associated with discharge potentials matching that of the Li/CF_x battery. When considering the combined mass of the electrolyte and cathode as the active material, the overall energy densities of the Li/CF_x batteries increased by 25.3% (TBD) and 20.8% (BDE), reaching 1005.50 and 969.1 Wh/kg, respectively. The superior performance of TBD was due to the synergistic effects of the high electronegativities and levels of steric hindrance of the F atoms. Moreover, the nanocrystal LiF particles generated by TBD induced crack formation within the fluorinated graphite, increasing the lithium-ion accessible surface area and enhancing its utilization efficiency. These combined factors enhanced the reactivity of TBD and facilitated its involvement in electrochemical reactions, thus improving the capacity of the battery. The developed strategy enables the facile, cost-effective enhancement of the capacities of Li/CF_x batteries, paving the way for their practical use in energy-demanding devices. Full article

Lithium–oxygen batteries have attracted considerable attention in recent years due to their high energy density and potential applications. However, the slow kinetics of the cathode reaction and the unstable products in lithium–oxygen batteries have limited their practical applications. Metal–organic frameworks (MOFs) and their derivatives have emerged as a novel class of functional materials, thus becoming ideal candidates for the cathode of lithium–oxygen batteries. This is due to their high specific surface area, structural tunability, and abundant active sites. This paper presents a review of the research progress made in the field of MOFs and their derivatives in the cathode of lithium–oxygen batteries. It provides a summary of the design and synthesis strategies employed in the development of MOF-based catalysts, with a particular focus on the application of primary MOFs materials, MOF-derived materials and MOF composite materials in Li-O₂ batteries. Additionally, it analyses the catalytic mechanism of MOFs and their derivatives in the ORR/OER. The comprehensive analysis demonstrates that MOFs and their derivatives are ideal candidates for the cathodes of lithium–oxygen batteries due to their high specific surface area, structural tunability, and abundant active sites. However, the electrical conductivity of MOFs is usually low and needs to be enhanced by composites or derivative materials. This paper reviews the research progress on MOFs and their derivatives in lithium–oxygen battery cathodes, focuses on the design and synthesis strategies of MOF-based catalysts, and discusses their catalytic mechanisms in the ORR/OER. Full article

Lithium-ion (Li-ion) batteries have become essential in modern industries and domestic applications due to their high energy density and efficiency. However, they experience gradual degradation over time, which presents significant challenges in maintaining optimal battery performance and increases the risk of unexpected system failures. To ensure the reliability and longevity of Li-ion batteries in applications, various methods have been proposed for battery health monitoring and remaining useful life (RUL) prediction. This paper provides a comprehensive review and analysis of the primary approaches employed for battery health monitoring and RUL estimation under the categories of model-based, data-driven, and hybrid methods. Generally speaking, model-based methods use physical or electrochemical models to simulate battery behaviour, which offers valuable insights into the principles that govern battery degradation. Data-driven techniques leverage historical data, AI, and machine learning algorithms to identify degradation trends and predict RUL, which can provide flexible and adaptive solutions. Hybrid approaches integrate multiple methods to enhance predictive accuracy by combining the physical insights of model-based methods with the statistical and analytical strengths of data-driven techniques. This paper thoroughly evaluates these methodologies, focusing on recent advancements along with their respective strengths and limitations. By consolidating current findings and highlighting potential pathways for advancement, this review paper serves as a foundational resource for researchers and practitioners working to advance battery health monitoring and RUL prediction methods across both academic and industrial fields. Full article

The rapid evolution of Li-ion battery technologies and manufacturing processes demands a continual update of environmental impact data. The general objective of this paper is to publish up-to-date primary data on battery manufacturing, which is of great importance to the scientific community and decision-makers. The environmental impacts have been calculated and estimated based on publicly available data disclosed under Hungarian government regulations and official decrees. The gate-to-gate energy use, greenhouse gas (GHG) emissions, water consumption, and N-methyl-2-pyrrolidone (NMP) consumption are estimated for three battery factories in Hungary, with a total annual capacity of approximately 100 GWh. The factories use around 30–35 kWh energy per kWh of battery capacity and the associated GHG emissions are around 10 kgCO₂eq per kWh of cell production. The water consumption varies considerably among factories, with one plant using 28 L per kWh and the other two using 56 and 67 L per kWh. The specific consumption of NMP was calculated for two factories, resulting in close values of 0.51–0.56 kg per kWh of cell production. As a new approach, we distinguish between global and local GHG emissions related to battery production. The main component of the latter is carbon dioxide from the combustion of natural gas, but the local transport related to the battery factories is also a source of emissions. Our estimations include not only the consumptions required directly for the manufacturing technology, but also those for social purposes (e.g., heating offices), giving a more complete picture of the factory’s environmental impact. We believe that up-to-date primary data are crucial for ensuring transparency and holds significant value for both the scientific community and decision-makers. Full article

As the penetration of renewable energy sources (RESs) in power systems continues to increase, their volatility and unpredictability have exacerbated the burden of frequency regulation (FR) on conventional generator units (CGUs). Therefore, to reduce frequency deviations caused by comprehensive disturbances and improve system frequency stability, this paper proposes an integrated strategy for hybrid energy storage systems (HESSs) to participate in primary frequency regulation (PFR) of the regional power grid. Once the power grid frequency exceeds the deadband (DB) of the HESS, the high-frequency signs of the power grid frequency are managed by the battery energy storage system (BESS) through a division strategy, while the remaining parts are allocated to pumped hydroelectric energy storage (PHES). By incorporating positive and negative virtual inertia control and adaptive droop control, the BESS effectively maintains its state of charge (SOC), reduces the steady-state frequency deviation of the system, and provides rapid frequency support. When the system frequency lies within the DB of the HESS, an SOC self-recovery strategy restores the BESS SOC to an ideal range, further enhancing its long-term frequency regulation (FR) capability. Finally, a regional power grid FR model is established in the RT-1000 real-time simulation system. Simulation validation is conducted under three scenarios: step disturbances, short-term continuous disturbances, and long-term RES disturbances. The results show that the proposed integrated strategy for HESS participation in PFR not only significantly improves system frequency stability but also enhances the FR capability of the BESS. Full article

High-nickel ternary LiNi_0.6Co_0.2Mn_0.2O₂ (NCM622) is a promising cathode material for lithium-ion batteries due to its high discharge-specific capacity and energy density. However, problems of NCM622 materials, such as unstable surface structure, lithium–nickel co-segregation, and intergranular cracking, led to a decrease in the cycling performance of the material and an inability to fully utilize high specific capacity. Surface coating was the primary approach to address these problems. The effect of TiO₂ coating prepared by the sol–gel method on the performance of LiNi_0.6Co_0.2Mn_0.2O₂ was studied, mainly including the morphology, cell structure, and electrochemical properties. LiNi_0.6Co_0.2Mn_0.2O₂ was coated by TiO₂ with a thickness of about 5 nm. Compared with the pristine NCM622 electrode, the electrochemical performance of the TiO₂-coated NCM622 electrodes is improved. Among all TiO₂-coated NCM622, the NCM622 cathode with TiO₂ coating content of 0.5% demonstrates the highest capacity retention of 89.3% and a discharge capacity of 163.9 mAh g⁻¹, in contrast to 80.9% and145 mAh g⁻¹ for the pristine NCM622 electrode, after 100 cycles at 0.3 C between 3 and 4.3 V. The cycle life of the 5 wt% TiO₂-coated NCM622 electrode is significantly improved at a high cutoff voltage of 4.6 V. The significantly enhanced cycling performance of TiO₂-coated NCM622 materials could be attributed to the TiO₂ coating layer that could block the contact between the material surface and the electrolyte, reducing the interface side reaction and inhibiting the transition metal dissolution. At the same time, the coating layer maintained the stability of layered structures, thus reducing the polarization phenomenon of the electrode and alleviating the irreversible capacity loss in the cycle process. Full article

Carbon fiber-based batteries, integrating energy storage with structural functionality, are emerging as a key innovation in the transition toward energy sustainability. Offering significant potential for lighter and more efficient designs, these advanced battery systems are increasingly gaining ground. Through a bibliometric analysis of scientific literature, the study identifies three primary research areas: (i) the development of anodes for lithium-ion batteries, tackling challenges such as dendrite formation and performance degradation; (ii) the creation of new carbon fiber-based cathodes with coatings of LiFePO₄, LiCoO₂, or other nanoparticles, alongside efforts to develop cobalt-free alternatives; and (iii) the advancement of solid electrolytes that achieve a balance between ionic conductivity and mechanical strength. These advancements position carbon fiber-based batteries as promising solutions for seamless integration into various structural applications. The analysis of publication trends, citation patterns, and collaboration networks provides critical insights into the ongoing technological developments, current research challenges, and emerging trends in this field. Moreover, the study highlights potential research directions, underscoring the importance of continuous innovation to fully realize the potential of carbon fiber-based energy storage technologies. Full article

High Ni-content LiNi_xMn_yCo_zO₂ (NMC) cathodes (with x ≥ 0.8, x + y + z = 1) have gained attention recently for their high energy density in electric vehicle (EV) Li-ion batteries. However, Ni-rich cathodes pose challenges in capacity retention due to inherent structural and surface redox instabilities. One promising strategy is to make the Ni-rich NMC material in the form of single-crystal micron-sized particles, as they resist intergranular and surface degradation during cycling. Among various methods to synthesize single-crystal NMC (SC-NMC) particles, molten-salt-assisted calcination offers distinct processing advantages but at present, is not yet optimized or mechanistically clarified to yield the desired control over crystal growth and morphology. In this project, molten-salt-mediated transformation of Ni_0.85Mn_0.05Co_0.15(OH)₂ precursor (P-NMC) particles to LiNi_0.85Mn_0.05Co_0.15O₂ particles is investigated in terms of the crystal growth mechanism and its electrochemical response. Unlike previous studies that involved large volumes of molten salt, using a smaller volume of molten KCl is found to result in larger primary particles with improved cycling performance achieved via partial reactive dissolution and heterogeneous nucleation growth, suggesting that the ratio of molten salt volume to NMC mass is an important parameter in the synthesis of single-crystal Ni-rich NMC materials. Full article

This article presents a novel aging-coupled predictive thermo-electrical dynamic modeling tool tailored for primary lithium manganese dioxide ($Li\text{-}Mn{O}_2$) batteries in active implantable medical devices (AIMDs). The aging mechanisms of rechargeable lithium batteries are well documented using computationally intensive physics-based models, unsuitable for real-time onboard monitoring in AIMDs due to their high demands. There is a critical need for efficient, less demanding modeling tools for accurate battery health monitoring and end-of-life prediction as well as battery safety assessment in these devices. The presented model in this article simulates the battery terminal voltage, remaining capacity, temperature, and aging during active discharge, making it suitable for real-time health monitoring and end-of-life prediction. We incorporate a first-order dynamic for internal resistance growth, influenced by time, temperature, discharge depth, and load current. By adopting Arrhenius-type kinetics and polynomial relationships, this model effectively simulates the combined impact of these variables on battery aging under diverse operational conditions. The simulation handles both the continuous micro-ampere-level demands necessary for device housekeeping and periodic high-rate pulses needed for therapeutic functions, at a constant ambient temperature of 37 °C, mimicking human body conditions. Our findings reveal a gradual, nonlinear increase in internal resistance as the battery ages, rising by an order of magnitude over a period of 5 years. Sensitivity analysis shows that as the battery ages and load current increases, the terminal voltage becomes increasingly sensitive to internal resistance. Specifically, at defibrillation events, the ${\displaystyle \frac{\partial V}{\partial R}}$ trajectory dramatically increases from ${10}^{-12}$ to ${10}^{-8}$, indicating a fourth-order-of-magnitude enhancement in sensitivity. A model verification against experimental data shows an R² value of 0.9506, indicating a high level of accuracy in predicting the $Li\text{-}Mn{O}_2$ cell terminal voltage. This modeling tool offers a comprehensive framework for effectively monitoring and optimizing battery life in AIMDs, therefore enhancing patient safety. Full article

In lithium–polymer batteries, the electrolyte is an essential component that plays a crucial role in ion transport and has a substantial impact on the battery’s overall performance, stability, and efficiency. This article presents a detailed study on developing nanostructured composite polymer electrolytes (NCPEs), prepared using the solvent casting technique. The materials selected for this investigation include poly(vinyl chloride) (PVC) as the host polymer, lithium bromide (LiBr) as the salt, and silica (SiO₂) as the nanofiller. The addition of nano-SiO₂ dramatically enhanced the ionic conductivity of the electrolytes, with the highest value of 6.2 × 10⁻⁵ Scm⁻¹ observed for the sample containing 7.5 wt% nano-SiO₂. This improvement is attributed to an increased amorphicity resulting from the interactions between the polymer, salt, and filler components. A structural analysis of the prepared NCPEs using X-ray diffraction revealed the presence of both crystalline and amorphous phases, further validating the enhanced ionic transport. Additionally, the thermal stability of the NCPEs was found to be excellent, withstanding temperatures up to 334 °C, thereby reinforcing their potential application in lithium–polymer batteries. This work explores the electrochemical performance of a fabricated lithium-ion-conducting primary electrochemical cell (Zn + ZnSO₄·7H₂O|PVC: LiBr: SiO₂|PbO₂ + V₂O₅), which demonstrated an open circuit voltage of 2.15 V. The discharge characteristics of the fabricated cell were thoroughly studied, showcasing the promising potential of these NCPEs. With the support of superior morphological and electrical properties, as-prepared electrolytes offer an effective pathway for future advancements in lithium–polymer battery technology, making them a highly viable candidate for enhanced energy storage solutions. Full article

In the search for novel polymeric molecules that could be used as electroactive materials, seven novel polyenaminones were prepared in high yields by the transaminative polymerization of resorcinol-derived bis-enaminones with m- and p-phenylenediamine and with 2,5-diaminohydroquinone. The obtained polymers show very low solubility in organic solvents and absorb UV light and visible light at wavelengths below 500 nm. All the obtained polymeric products were tested for redox activity in a Li battery setup. The 2,5-diaminohydroquinone-derived compound showed the best redox activity, with a maximum capacity of 86 mAh/g and relatively good capacity retention, thus confirming the hydroquinone group as the primary redox-active group. Other potential redox-active groups, such as resorcinol and conjugated carbonyls, showed limited activity, while variations in the phenylene groups and the substitution of phenolic groups in the resorcinol residue did not impact the electrochemical activity of the polymers. Their electrochemical properties, together with their previously established chemical recyclability, make polyenaminones promising scaffolds for the development of materials for sustainable energy storage applications. Full article