Search Results (178)

The Oligocene Dongying Formation beach-bar system, widely distributed in the HHK Depression of the Bohai Bay Basin, constitutes a key target for mid-deep hydrocarbon exploration, though its provenance remains controversial due to complex peripheral source terrains. To address this, we developed an integrated methodology combining LA-ICP-MS zircon U-Pb dating with whole-rock rare earth element (REE) analysis, facilitating provenance studies in areas with limited drilling and heavy mineral data. Analysis of 849 high-concordance zircons (concordance >90%) from 12 samples across 5 wells revealed that Geochemical homogeneity is evidenced by strongly consistent moving-average trendlines of detrital zircon U-Pb ages among the southern/northern provenances and the central uplift zone, complemented by uniform REE patterns characterized by HREE (Gd-Lu) enrichment and LREE depletion; geochemical disparities manifest as dual dominant age peaks (500–1000 Ma and 1800–3100 Ma) in the southern provenance and central uplift samples, contrasting with three distinct peaks (65–135 Ma, 500–1000 Ma, and 1800–3100 Ma) in the northern provenance; spatial quantification via multidimensional scaling (MDS) demonstrates closer affinity between the southern provenance and central uplift (d_ij = 4.472) than to the northern provenance (d_ij = 6.708). Collectively, these results confirm a dual (north–south) provenance system for the central uplift beach-bar deposits, with the southern provenance dominant and the northern acting as a subsidiary source. This work establishes a dual-provenance beach-bar model, providing a universal theoretical and technical framework for provenance analysis in hydrocarbon exploration within analogous settings. Full article

Late Paleozoic to Early Mesozoic granitoids in the East Kunlun Orogenic Belt (EKOB) provide critical insights into the complex and debated relationship between Paleo–Tethyan magmatism and tectonics. This study presents integrated bulk-rock geochemical and zircon isotopic data for the Xingshugou monzogranite (MG) to address these controversies. LA-ICP-MS zircon U-Pb dating constrains the emplacement age of the MG to 247.1 ± 1.5 Ma. The MG exhibits a peraluminous and low Na₂O A₂-type granite affinity, characterized by high K₂O (4.69–6.80 wt.%) and Zr + Nb + Ce + Y (>350 ppm) concentrations, coupled with high Y/Nb (>1.2) and A/CNK ratios (1.54–2.46). It also displays low FeO^T, MnO, TiO₂, P₂O₅, and Mg^# values (26–49), alongside pronounced negative Eu anomalies (Eu/Eu* = 0.37–0.49) and moderately fractionated rare earth element (REE) patterns ((La/Yb)_N = 3.30–5.11). The MG exhibits enrichment in light rare earth elements (LREEs) and large ion lithophile elements (LILEs; such as Sr and Ba), and depletion in high field strength elements (HFSEs; such as Nb, Ta, and Ti), collectively indicating an arc magmatic affinity. Zircon saturation temperatures (T_Zr = 868–934 °C) and geochemical discriminators suggest that the MG was generated under high-temperature, low-pressure, relatively dry conditions. Combined with positive zircon ε_Hf(t) (1.8 to 4.7) values, it is suggested that the MG was derived from partial melting of juvenile crust. Synthesizing regional data, this study suggests that the Xingshugou MG was formed in an extensional tectonic setting triggered by slab rollback of the Paleo-Tethys Oceanic slab. Full article

The attributes of Late Paleozoic magmatic events are of paramount significance in elucidating the tectonic evolution of the Ulanhot region, which is located in the middle of the Hegenshan–Heihe tectonic belt (HHTB). This study undertook a comprehensive investigation of the petrography, LA–ICP–MS zircon U–Pb dating, whole rock geochemistry, and zircon Hf isotopes of the Early Carboniferous volcanic rocks. The volcanic rocks are predominantly composed of andesite, schist (which protolith is rhyolitic tuff), and rhyolitic tuff. The results of zircon U–Pb dating reveal that the formation ages of volcanic rocks are Early Carboniferous (343–347.4 Ma). Geochemical characteristics indicate that the andesites possess a comparatively elevated concentration of Al₂O₃, alongside diminished levels of MgO and TiO₂, belonging to the high-K calc-alkaline series. The zircon εHf(t) of the andesites range from −13 to 9.4, while the two-stage Hf model ages span from 697 to 1937 Ma. The felsic volcanic rocks have high contents of SiO₂ and Na₂O + K₂O, low contents of MgO and TiO₂, and belong to high-K to normal calc-alkaline series. The zircon εHf(t) values of the felsic volcanic rocks range from −12.8 to 10, while the two-stage Hf model ages span from 693 to 2158 Ma. The Early Carboniferous volcanic rocks exhibit a notable enrichment in large ion lithophile elements (LILEs, such as Rb, K, Ba) and light rare earth elements (LREEs), depletion in high-field-strength elements (HFSEs, including Nb, Ta, Ti, Hf), as well as heavy rare earth elements (HREEs). The distribution patterns of the rare earth elements (REEs) demonstrate a conspicuous right-leaning tendency, accompanied by weak negative Eu anomalies. These characteristics indicate that the andesites represent products of multistage mixing and interaction between crustal and mantle materials in a subduction zone setting. The felsic volcanic rocks originated from the partial melting of crustal materials. Early Carboniferous igneous rocks formed in a volcanic arc setting are characteristic of an active continental margin. The identification of Early Carboniferous arc volcanic rocks in the Central Great Xing’an Range suggests that this region was under the subduction background of the oceanic plate subduction before the collision and amalgamation of the Erguna–Xing’an Block and the Songnen Block in the Early Carboniferous. Full article

Haigou deposit, located in Dunhua City, southeast Jilin Province, NE China, is a large-scale gold deposit. The gold ore body is categorized into two types: quartz-vein type and altered rock type, with the quartz-vein type being predominant. The vein gold ore body primarily occurs within the monzonite granite and monzonite rock mass in the Haigou area and is controlled by fault structures trending northeast, northwest, and near north-south. In order to constrain the age and tectonic setting of quartz vein-type gold mineralization, we conducted a detailed underground investigation and collected samples of monzonite granite and pyroxene diorite porphyrite veins related to quartz-vein-type gold mineralization for LA-ICP-MS zircon U-Pb dating and whole-rock main trace element data testing to confirm that monzonite granite is closely related to gold mineralization. Pyroxene diorite porphyry and gold mineralization were found in parallel veins. The zircon U-Pb weighted mean ages of monzonite and pyroxene diorite porphyrite veins are 317.1 ± 3.5 Ma and 308.8 ± 3.0 Ma, respectively, indicating that gold mineralization in monzonite, pyroxene diorite porphyrite veins, and quartz veins occurred in the Late Carboniferous. The monzonite granite and pyroxene diorite porphyrite veins associated with quartz vein-type gold mineralization have high SiO₂, high K, and high Al₂O₃ and are all metaluminous high-potassium calc-alkaline rock series. Both of them are relatively enriched in light rare earth elements (LREE) and macroionic lithophile elements (LILE: Rb, Ba, K, etc.), but deficient in heavy rare earth elements (HREE) and high field strength elements (HFSE: Nb, Ta, P, Ti, etc.), the monzonitic granite Eu is a weak positive anomaly (δEu = 1.15–1.46), the pyroxene diorite porphyre dyke Eu is a weak positive anomaly (δEu = 1.09–1.13), and the Nb and Ta are negative anomalies. The Th/Nb values are 0.28–0.73 and 1.48–2.05, and La/Nb are 2.61–4.74 and 4.59–5.43, respectively, suggesting that diagenetic mineralization is the product of subduction in an active continental margin environment. In recent years, scholarly research on Sr, Nd, and Pb isotopes in Haigou rock masses has indicated that the magmatic source region in the Haigou mining areas is complex. It is neither a singular crustal source nor a mantle source but rather a mixed crust-mantle source, primarily resulting from the partial melting of lower crustal materials, with additional contributions from mantle-derived materials. In summary, the metallogenic characteristics, chronology data, geochemical characteristics, and regional tectonic interpretation indicate that at least one phase of magmatic-hydrothermal gold mineralization was established in the Late Carboniferous as a result of the subduction of the Paleo-Asian ocean plate at the northern margin of the North China Craton. Full article

The granitic rocks and the Dokhan Volcanics at the transect between Safaga and Qena, the Egyptian Northern Eastern Desert represent the northern termination of the Arabian–Nubian Shield (ANS), which, in turn, represents the northern part of the East African Orogeny (EAO). The geochronological development of the magmatic activities that constructed the ANS is critical in understanding these orogenies. The ANS was constructed through pre-collisional, syn-collisional, and post-collisional magmatic phases. The transition between these magmatic phases marks tectonic shifting from subduction to compressional and extensional tectonic settings, respectively. The chronological constraints of these tectonic–magmatic phases are still questionable. Our study aims to refine these chronological constraints through the dating of four calc-alkaline granitic rocks (722 ± 5 Ma–561 ± 4 Ma), five alkaline granitic rocks (758 ± 5 Ma–555 ± 4 Ma), and three Dokhan Volcanic rocks (618 ± 5 Ma–606 ± 5 Ma). Our results suggest the absence of any pre-collisional rocks. The syn-collisional magmatism extended here from 758 ± 5 Ma to 653 ± 7 Ma, demonstrating the chronological domination of the syn-orogenic compressional regime in the NED. The Dokhan Volcanic activity marked the shifting of the tectonic setting from a compressional to an extensional regime at 618 ± 5 Ma. Post-collisional plutonism dominated between 583 ± 5 Ma and 555 ± 4 Ma in the studied region, suggesting that ANS magmatic activity was extended to the Phanerozoic edge. These findings refute the classical interpretations of older magmatism as calc-alkaline granitoids and younger magmatism as alkaline granitoids. Pre-Neoproterozoic (pre-ANS) xenocrysts with ages of 1879 ± 22, 1401 ± 25, 1385 ± 12, 1232 ± 27, 1210 ± 18, and 1130 ± 15 Ma were yielded, which might support a local reworked ancient magmatic source. Full article

The Heilongjiang Complex provides a crucial geological record of the evolutionary history of the Mudanjiang Ocean, making it significant for understanding the accretion process between the Jiamusi Block and the Songliao Block. In this study, we analyzed samples from the Heilongjiang Complex in the Huanan region using zircon U-Pb and ⁴⁰Ar/³⁹Ar isotopic dating. The LA-ICP-MS U-Pb dating results show that the deposition time of the mica quartz schist is Late Triassic (237–207 Ma), while the protolith age of the amphibolite is Middle Triassic (245.5 ± 1.2 Ma). Detrital zircon ages from the mica quartz schist reveal four groups: 155–229 Ma, 237–296 Ma, 485–556 Ma, and 585–2238 Ma. The provenances are related to the magmatic and metamorphic activities at the junction of the Jiamusi Block and Songliao Block. ⁴⁰Ar/³⁹Ar isotopic dating yielded a plateau age of 183.40 ± 1.83 Ma for phengite in the mica quartz schist, with the metamorphic ages obtained from zircon U-Pb dating. We identify three major metamorphic events in the Heilongjiang Complex: (1) ~229 Ma, marking the earliest tectonic thermal disturbance in the complex; (2) 207–202 Ma, corresponding to the metamorphic event related to the collision between the Jiamusi Block and Songliao Block; and (3) ~183 Ma, indicating the closure of the Mudanjiang Ocean. Integrating these new findings with the results of previous research on magmatism and metamorphism, we reconstruct the tectonic evolution of the Mudanjiang Ocean from the Late Paleozoic to the Mesozoic. During the Early Permian, the Mudanjiang Ocean had already opened. Between the Middle Permian and Middle Triassic, bidirectional subduction occurred. In the Late Triassic, the Mudanjiang Ocean entered a subduction dormancy period. By the Early to Middle Jurassic, the Mudanjiang Ocean closed due to continental collision, leading to the final positioning of the Heilongjiang Complex. Full article

Magma mixing or mingling is not just a geological phenomenon that widely occurs in granitoid magmatism, but a complex dynamic process that influences the formation of mafic microgranular enclaves (MMEs) and the diversity of granitic rocks. Herein, we carried out a comprehensive study that encompassed the petrology, mineral chemistry, zircon U-Pb ages, Lu-Hf isotopes, whole-rock elements, and Sr-Nd isotope compositions of the Menyuan Granodioritic Pluton in the northern margin of the Qilian Block, to elucidate the petrogenesis and physical and chemical processes occurring during magma mixing. The Menyuan Granodioritic Pluton is mainly composed of granodiorites accompanied by numerous mafic microgranular enclaves (MMEs) and is intruded by minor gabbro dikes. LA-ICP-MS zircon U-Pb dating reveals that these rocks possess a similar crystallization age of ca. 456 Ma. The Menyuan host granodiorites, characterized as metaluminous to weakly peraluminous, belong to subduction-related I-type calc-alkaline granites. The MMEs and gabbroic dikes have relatively low SiO₂ contents and high Mg^# values, probably reflecting a mantle-derived origin. They are enriched in large ion lithophile elements (LILEs) and light, rare earth elements (LREEs) but are depleted in high field strength elements (HFSEs), indicating continental arc-like geochemical affinities. The host granodiorites yield relatively enriched whole-rock Sr-Nd and zircon Hf isotopic compositions (⁸⁷Sr/⁸⁶Sr_i = 0.7072–0.7158; ε_Nd(t) = −9.21 to −4.23; ε_Hf(t) = −8.8 to −1.2), implying a derivation from the anatexis of the ancient mafic lower continental crust beneath the Qilian Block. The MMEs have similar initial Sr isotopes but distinct whole-rock Nd and zircon Hf isotopic compositions compared with the host granodiorites (⁸⁷Sr/⁸⁶Sr_i = 0.7078–0.7089; ε_Nd(t) = −3.88 to −1.68; ε_Hf(t) = −0.1 to +4.1). Field observation, microtextural and mineral chemical evidence, geochemical characteristics, and whole-rock Nd and zircon Hf isotopic differences between the host granodiorites and MMEs suggest insufficient magma mixing of lithospheric mantle mafic magma and lower continental crust felsic melt. In combination with evidence from regional geology, we propose that the anatexis of the ancient mafic lower continental crust and subsequent magma mixing formed in an active continental arc setting, which was triggered by the subducted slab rollback and mantle upwelling during the southward subduction of the Qilian Proto-Tethys Ocean during the Middle-Late Ordovician. Full article

The Chinese Altay is located in the western segment of the Central Asian Orogenic Belt (CAOB) and preserves critical records of the Paleo-Asian Ocean (PAO) Plate evolution during the Paleozoic era. This region also hosts significant mineral deposits, making it a focal point for geological research. In this paper, field investigation, petrology, mineralogy, and petrography studies were conducted on volcanic rocks in the Fuyun–Qinghe area, southern margin of the Chinese Altay, and the paper provided new zircon LA-ICP-MS dating data, Lu-Hf isotope data, and whole-rock geochemical data of the basaltic to andesitic volcanic rocks. Thus, the formation age, petrogenesis, and tectonic setting of these rocks were discussed, which was of great significance to reveal the nature of the PAO Plate. The findings showed that the basaltic andesitic volcanic breccia was formed at 382.9 ± 3.4 Ma, the basalt was 401.7 ± 4.7 Ma, and the andesites were 405.1 ± 5.6 Ma and 404.8 ± 6.7 Ma, which indicated that the above rocks were formed in the Early–Middle Devonian. The volcanic rock assemblages were hawaiite, mugearite, potassic trachybasalt, basaltic andesite, andesite, benmoreite, etc., which contained labeled magmatic rocks such as adakite, sub-boninite, niobium-enriched arc basalt (NEAB), picrite, high-magnesium andesite (HMA), and magnesium andesite (MA). Comprehensive analysis indicated that magma probably mainly originated from three sources: (1) partial melting of the PAO slab, (2) partial melting of the overlying garnet–spinel lherzolite mantle peridotite metasomatized by subducting-related fluids (melts), and (3) a possible input of the asthenosphere. Comparative analysis with modern analogs (e.g., Chile Triple Junction) indicates that ridge subduction of the PAO had existed in the Fuyun–Qinghe area during the Early–Middle Devonian. Based on available evidence, we tentatively named the oceanic plates in this region the central Fuyun–Qinghe Ridge and the Junggar Ocean Plates, separated by the ridge on both sides. Although the ocean had a certain scale, it had entered the climax period of transition from ocean to continent. Full article

This study examines the origin, tectonic setting, and Cu–Pb–Zn polymetallic mineralization of the Yangjiayu Complex, situated on the southwestern margin of the Jiaolai Basin. We present detailed geochemical, zircon U–Pb geochronological, and Hf isotopic data for rhyolite porphyry and monzodiorite samples. Zircon U–Pb dating reveals that the emplacement of both intrusions occurred in the Early Cretaceous. While the monzodiorite (122.5 ± 0.7 Ma) is numerically slightly older than the rhyolite porphyry (121.2 ± 0.6 Ma), considering the error ranges, their ages are essentially similar. The rhyolite porphyry displays higher SiO₂ and Na₂O + K₂O contents and a lower Al₂O₃ content relative to the monzodiorite. Geochemically, both intrusions are classified as high-K calc-alkaline and peraluminous, characterized by enrichment in large-ion lithophile elements (LILEs; e.g., Ba, Rb, Pb) and light rare earth elements (LREEs), along with depletion in high-field-strength elements (HFSEs; e.g., Nb, P, Ta) and heavy rare earth elements (HREEs). The rhyolite porphyry further exhibits middle rare earth elements (MREEs; e.g., Eu, Gd, Tb, Dy) depletion. Similar zircon εHf(t) values (monzodiorite: −23.0 to −26.1; rhyolite porphyry: −23.2 to −25.0) suggest a shared source derived from partial melting of the thickened lower crustal rocks. In comparison to the monzodiorite, the rhyolite porphyry shows lower total REE contents, a more pronounced negative Eu anomaly and stronger MREE depletion, higher Rb, Th, and U concentrations, and more significant P depletion, features indicative of more extensive assimilation-fractional crystallization (AFC). These geochemical and geochronological data indicate that the Yangjiayu Complex originated within an extensional tectonic setting associated with the Early Cretaceous subduction of the Paleo-Pacific Plate underneath the Eurasian Plate. Cu–Pb–Zn mineralization, primarily localized within the monzodiorite, is interpreted to be generated by magmatic-hydrothermal fluids. Therefore, ~120 Ma dioritic intrusions within the Jiaolai Basin constitute prospective targets for (Cu)–Pb–Zn polymetallic exploration. Full article

The Qushi rhyolites, situated in the eastern sector of the Tengchong terrane, are critical to understanding the Early Cretaceous tectono-magmatic evolution of the Eastern Tethyan Tectonic Domain. Zircon LA-ICP-MS U-Pb geochronology indicates crystallization ages of 118.3–120.5 Ma, with Ti-in-zircon temperatures of 641–816 °C (mean = 716 °C), representing the Early Cretaceous magmatic activity in the Tengchong terrane. Inherited zircons within the rhyolites yield a zircon age of ca. 198.5 Ma, with corresponding Ti-in-zircon temperatures of 615–699 °C (mean = 657 °C), implying the potential presence of an Early Jurassic igneous basement beneath the Qushi region. Geochemically, the rhyolites are classified as calc-alkaline and weakly to moderately peraluminous (A/CNK = 1.07–2.86). These rocks display signatures typical of acidic magmas, marked by significant enrichments in light rare earth elements (LREE: La and Ce) and large ion lithophile elements (LILE: Rb, K, Th and U) while simultaneously exhibiting depletions in high-field-strength elements (HFSE: Nb, Ta, Ti, and P) and heavy rare earth elements (HREE). Trace element signatures further reveal marked depletions in Sr (12.4–244.7 ppm) and Ba while displaying enrichments in Zr and Hf. These geochemical features, including the huge range of the Sr content and A/CNK ratios, suggest both I-type and S-type granite affinities. The Early Cretaceous volcanism of the Qushi rhyolites is likely attributed to the combined effects of subduction and the closure of the Meso-Tethyan Ocean (MTO). This volcanic activity is interpreted to result from subduction-related processes associated with the MTO, potentially involving slab rollback, slab break-off, and subsequent asthenospheric upwelling. The formation of these rhyolites may also be linked to the final closure of the MTO, characterized by the Late Cretaceous collision and amalgamation of the Burma and Tengchong terranes. Full article

Rare metals such as lithium and beryllium are strategic mineral resources that play a highly significant role in the national aerospace, defense, and new energy industries. The western Kunlun–Songpan–Ganzi metallogenic belt is an important rare metal metallogenic belt in China that mainly consists of granite–pegmatite-type lithium–beryllium deposits with uncommon beryllium-only deposits. In the Jiulong area on the southeastern edge of this metallogenic belt, several deposits, including the Daqianggou lithium–beryllium, Luomo beryllium, Baitai beryllium, and Shangjigong beryllium deposits, have been identified. Unlike the northern areas of Jiajika, Ke’eryin, Zawulong, and the western regions of Dahongliutan and Bailongshan, this area contains beryllium-only deposits. In this paper, we examine representative beryllium deposits in the Jiulong area, including detailed petrographic observations and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb isotope dating of cassiterite and columbite–tantalite, to define the metallogenic age and summarize the spatiotemporal characteristics of the beryllium mineralization in this area. The research results show that the Daqianggou lithium–beryllium deposit is dominated by spodumene and beryl mineralization, while the Luomo and Baitai beryllium deposits primarily feature beryl mineralization. The dating results indicate that the U-Pb ages of the cassiterite and columbite–tantalite in the Daqianggou lithium–beryllium deposit are 157.3 ± 1.7 Ma and 164.1 ± 0.8 Ma, respectively. For the Luomo beryllium deposit, the U-Pb ages of the cassiterite and columbite–tantalite are 156.1 ± 1.5 Ma and 163.3 ± 0.8 Ma, respectively. For the Baitai beryllium deposit, the U-Pb age of the columbite–tantalite is 188.8 ± 1.1 Ma. Therefore, the Jiulong area experienced two pegmatite-type rare metal metallogenic events: a beryllium–niobium–tantalum–molybdenum event at 197~189 Ma and a lithium–beryllium–niobium–tantalum–rubidium event at 164~156 Ma. Based on the reported metallogenic ages, we suggest that the western Kunlun–Songpan–Ganzi rare metal metallogenic belt experienced three rare metal metallogenic events at 210~200 Ma, 200~180 Ma, and 170~150 Ma. Regarding exploration directions, early Yanshanian beryllium mineralization predominates in the Jiulong area along the southeastern edge of the belt, and deep exploration of the early Yanshanian rare metal mineralization within this belt should be strengthened to facilitate new breakthroughs. Full article

This study sheds light on the origin and trade routes of early red coral artifacts found in Xinjiang, primarily dating to the Han and Jin dynasties. The red coral relics examined, excavated from the Shengjindian cemetery of the Western Han Dynasty in Turpan, offer critical insights into the material’s provenance and its introduction to this pivotal region along the ancient Silk Road. Advanced gemological, mineralogical, and geochemical analyses—utilizing computed tomography (CT), laser Raman spectroscopy, and laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS)—has revealed distinctive features. These include red coloration, a waxy luster, concentric ring structures in cross-section, and calcareous composition, identifying the coral as Sardinian (Corallium rubrum), likely originating from the western Mediterranean region. The findings carry significant archaeological implications. Red coral first appears in the archaeological record in Xinjiang during the Western Han period, facilitated by the thriving Silk Road trade and the expanding influence of Buddhist culture. This study not only confirms the Mediterranean origin of these artifacts but also highlights their integration into the cultural and economic networks of ancient Xinjiang, underscoring the significance of early long-distance trade and cultural exchange. Full article

Late Permian–Early Triassic basic rocks, which are widespread in the western margin of the Yangtze block (SW China), provide critical information for regional tectonic evolution. The Qiaoqi intrusion, distributed in the western margin of the Yangtze block, is selected as a representative for discussion in this paper. LA-ICP-MS zircon U-Pb dating results show that the Qiaoqi intrusion was formed at 245 ± 1 Ma. It belongs to the medium-K calc-alkaline and tholeiitic basalt series. It is characterized by high concentrations of Fe₂O₃^T (11.53 wt. % to 15.50 wt. %), TiO₂ (1.81 wt. % to 3.20 wt. %), Al₂O₃ (11.80 wt. % to 15.60 wt. %), and low concentrations of MgO (4.51 wt. % to 8.93 wt. %). The LREE and LILE (such as Cs, Rb, Ba and Th) are enriched, with insignificant Eu anomalies (Eu/Eu* = 0.92 to 1.13). The chondrite-normalized REE distribution diagram shows a right-leaning pattern, similar to ocean island basalts (OIB), displaying the geochemical characteristics of enriched mantle sources. The zircon εHf(t) values are relatively high (+12.7 to +15.5) and the single-stage Hf model ages are relatively young (t_DM = 272 to 386 Ma). Modeling further reveals that the parent magma was derived from 13% to 19% partial melting of garnet peridotite. Comprehensive analysis shows that the geochemical characteristics of the Qiaoqi intrusion bear resemblance to those of the Emeishan basalts, which are attributed to volumetrically minor melting of the fossil Emeishan plume head beneath the Yangtze crust following the eruption of the Emeishan Large Igneous Province (ELIP). This understanding further constrains the duration of the Emeishan Large Igneous Province and provides new support for understanding the formation, evolution and distribution of the Emeishan Large Igneous Province. Full article

Fersmite ([Ca,Ce,Na][Nb,Ta,Ti]₂[O,OH,F]₆) from the Mount Brussilof magnesite deposit, British Columbia, Canada occurs as accessory brittle, black, submetallic to vitreous lustre, acicular to platy crystals up to 2 cm long, developed in sparry dolomite, which lines cavities in sparry magnesite. Fersmite also occurs as smaller crystals (<3 mm) enclosed by dolomite, where it is commonly fractured or broken, formed during the final stage of dolomite crystallisation. Electron microprobe (WDS) major element data indicate that the grains confirmed to be fersmite by X-ray diffraction contain >50% Nb and are atypically Ta-poor. Fersmite contains significant U and Th (up to 4700 ppm and 6 wt.%, respectively) and therefore is a viable mineral for U-Pb geochronology. A series of laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) spot analyses and maps were collected on fersmite grains. Although the fersmite grains have considerable common Pb and have experienced Pb loss, the U-Pb spot data suggest growth or pervasive resetting at ca. 190 Ma. Some ⁴⁰Ar/³⁹Ar ages (two of four samples) are consistent with the ~190 Ma U-Pb date. Electron microprobe and LA-ICP-MS mapping indicate that the fersmite is middle to heavy rare earth element-rich. The ~190 Ma fersmite age estimate provides an approximate upper time constraint on the age of sparry magnesite mineralisation, sparry dolomitisation, and, indirectly, on the formation of MVT deposits in the Kicking Horse Rim area and possibly elsewhere in southeastern British Columbia. Full article