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15 pages, 14032 KB  
Article
Preliminary Study on the Activity of the Rupture Zone in the Eastern Segment of the Ba Co Fault in Ngari Prefecture, Tibet
by Yunsheng Yao, Yanxiu Shao and Bo Zhang
Geosciences 2025, 15(10), 377; https://doi.org/10.3390/geosciences15100377 - 1 Oct 2025
Cited by 1 | Viewed by 544
Abstract
The lack of research on the slip behavior of the NW-trending faults in the central Tibetan Plateau constrains our understanding of the deformation models for this region. The Ba Co Fault, located in the central Tibetan Plateau, is a NW–SE-trending right-lateral strike-slip fault. [...] Read more.
The lack of research on the slip behavior of the NW-trending faults in the central Tibetan Plateau constrains our understanding of the deformation models for this region. The Ba Co Fault, located in the central Tibetan Plateau, is a NW–SE-trending right-lateral strike-slip fault. Its eastern section has been active in the Holocene and plays an important accommodating role in the northward compression and east–west extension of the Tibetan Plateau. This study presents a detailed analysis of the geomorphic features of the eastern section of the Ba Co Fault in the Ngari Prefecture of Tibet, precisely measuring the newly discovered surface rupture zone on its eastern side and preliminarily discussing the activity of the fault based on the optically stimulated luminescence (OSL) dating results. The results reveal that the eastern segment of the Ba Co Fault displays geomorphic evidence of offset, including displaced Holocene alluvial–fluvial fans at the mountain front and partially offset ridges. A series of pressure ridges, trenches, counter-slope scarps, and shutter ridge ponds have developed along the fault trace. Some gullies exhibit a cumulative dextral displacement of approximately 16–52 m. The newly discovered co-seismic surface rupture zone extends for a total length of ~21 km, with a width ranging from 30 to 102 m. Pressure ridges within the rupture zone reach heights of 0.3–5.5 m, while trenches exhibit depths of 0.6–15 m. Optically stimulated luminescence (OSL) dating constrains the timing of the surface-rupturing earthquake to after 5.73 ± 0.17 ka. The eastern segment of the Ba Co Fault experienced a NW-trending compressional deformation regime during the Holocene, manifesting as a transpressional dextral strike-slip fault. Magnitude estimation indicates that this segment possesses the potential to generate earthquakes of M ≥ 6. The regional tectonic analysis indicates that the activity of the eastern section of the Ba Co Fault is related to the shear model of the conjugate strike-slip fault zone in the central Tibetan Plateau and may play a boundary role between different shear zones. Full article
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21 pages, 3367 KB  
Article
Factors Affecting Distribution of Pharmaceutically Active Compounds in Bottom Sediments of Odra River Estuary (SW Baltic Sea)
by Joanna Giebułtowicz, Dawid Kucharski, Grzegorz Nałęcz-Jawecki, Artur Skowronek, Agnieszka Strzelecka, Łukasz Maciąg and Przemysław Drzewicz
Molecules 2025, 30(19), 3935; https://doi.org/10.3390/molecules30193935 - 1 Oct 2025
Viewed by 742
Abstract
The results from previous environmental studies on the physicochemical properties of bottom sediments from the Odra River estuary (SW Baltic Sea) and their contamination by pharmaceutically active compounds (PhACs) were compiled and analyzed by the use of various statistical methods (Principal Component Analysis, [...] Read more.
The results from previous environmental studies on the physicochemical properties of bottom sediments from the Odra River estuary (SW Baltic Sea) and their contamination by pharmaceutically active compounds (PhACs) were compiled and analyzed by the use of various statistical methods (Principal Component Analysis, ANOVA/Kruskal–Wallis, Spearman correlation analysis, Partial Least Squares Discriminant Analysis, and Cluster Analysis). These studies included data on 130 PhACs determined in sediment samples collected from 70 sites across the Odra River estuary as well as the site distance to wastewater treatment plant discharge, PhACs’ physicochemical properties (Kd, Kow, pKa, solubility, metabolism), and sales data. Additionally, total organic carbon, total nitrogen, total phosphorus, acid volatile sulfides, clay mineral content, and trace elements such as As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sn, and Zn were analyzed. Clay mineral content and TP were identified as the key physicochemical factors influencing the spatial distribution of PhACs in bottom sediments, exerting a greater impact than the distance of sampling sites from WWTP discharge points. The distribution of PhACs in the estuary was also influenced by the Kd and solubility of the compounds. More soluble pharmaceuticals with low adsorption affinity to sediments were detected more frequently and transported to distant locations, whereas less soluble compounds with high adsorption affinity settled down in bottom sediments near contamination sources. Neither the proportion of a drug excreted unchanged, nor its prescription frequency and sales volume, influenced the spatial distribution of PhACs. In general, Kd may be a useful parameter in the planning of environmental monitoring and tracing migration of PhACs in aquatic environments. Full article
(This article belongs to the Section Cross-Field Chemistry)
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12 pages, 761 KB  
Article
The Iron Age npš and the Utility of Egyptian Comparative Evidence
by Shane M. Thompson
Religions 2025, 16(9), 1117; https://doi.org/10.3390/rel16091117 - 28 Aug 2025
Viewed by 1193
Abstract
This purpose of this article is twofold. Firstly, I present an overview of the Egyptian concepts of the ba and ka, as well as the attestations of npš extant in the Iron Age Levant. This brief investigation is meant to illustrate the [...] Read more.
This purpose of this article is twofold. Firstly, I present an overview of the Egyptian concepts of the ba and ka, as well as the attestations of npš extant in the Iron Age Levant. This brief investigation is meant to illustrate the second point, which is the utility of Egyptian evidence for the study of Levantine culture and religion. In addition, this article may stand as a starting point for further investigation of the npš through Egyptian comparative evidence, going beyond iconographic, archaeological, and textual comparison to include comparison of concepts and ideologies. Full article
(This article belongs to the Special Issue Hebrew Bible: Text, Culture, and Archaeology)
21 pages, 4357 KB  
Article
Flavor Characteristics of Sun-Dried Green Tea in Different Regions of Yunnan: Metabolite Basis and Soil Influencing Factors
by Miao Zhou, Xiujuan Deng, Qiaomei Wang, Zhenzhen Wei, Xinhua Wang, Wenxia Yuan, Limei Li, Man Zou, Weihao Liu, Shijie Lu, Yubo Sheng and Baijuan Wang
Foods 2025, 14(7), 1280; https://doi.org/10.3390/foods14071280 - 7 Apr 2025
Cited by 3 | Viewed by 1688
Abstract
To elucidate the regional flavor characteristics of sun-dried green tea (SDT) and their underlying influencing factors, a comprehensive analysis was conducted using metabolomics and flavoromics approaches. This study systematically examined SDT samples and their corresponding tea garden soils from 13 distinct regions in [...] Read more.
To elucidate the regional flavor characteristics of sun-dried green tea (SDT) and their underlying influencing factors, a comprehensive analysis was conducted using metabolomics and flavoromics approaches. This study systematically examined SDT samples and their corresponding tea garden soils from 13 distinct regions in Yunnan Province. The results revealed that the SDT samples could be classified into two distinct groups based on their flavor profiles. Compared to the regions of Pa Sha (PS), Bang Dong (BD), Dong Ban Shan (DBS), Dong Guo (DG), Su Hu (SH), Gua Feng Zhai (GFZ), and Wu Liang Shan (WLS), the regions of Xin Nong (XN), Ba Ka Nuan (BKN), Mang Ang (MA), Man Nuan (MN), Bing Dao (BDao), and Bin Shan (BS) exhibited a significant upregulation of the tea polyphenols (TP)/free amino acids (FAA) ratio. The former group was characterized by a sweet mellow taste, while the latter displayed a stronger taste profile. Furthermore, the analysis of volatile compounds demonstrated that geraniol and linalool were significantly upregulated in the PS, BD, DBS, DG, BS, and BDao regions, which were associated with tender and floral aromas. In contrast, isophorone, 2-pentyl furan, 1-octanol, D-limonene, and benzaldehyde were markedly enriched in the XN, BKN, MA, MN, SH, GFZ, and WLS regions, contributing to sweet and honey-like aromatic profiles. Altitude and mineral element phosphorus are potential key factors affecting the regional flavor differences in SDT. Specifically, SDT cultivated at higher altitudes and in soils with elevated available phosphorus content exhibited a greater likelihood of accumulating sweet mellow and floral compounds. This study provides scientific evidence for understanding the characteristic flavor profiles of SDT across different regions, offering valuable insights into the factors contributing to regional flavor differentiation in tea production. Full article
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22 pages, 617 KB  
Article
The Cover of the Holy Building, the Symbol of Politics: The Historical Power Rivalry over the Kiswa of the Ka‘ba
by Esra Atmaca
Religions 2025, 16(3), 358; https://doi.org/10.3390/rel16030358 - 12 Mar 2025
Cited by 1 | Viewed by 4510
Abstract
For Muslims, the Ka‘ba holds immense significance as the destination of pilgrimage—an obligatory act of worship—and as the direction toward which prayers are performed. The kiswa is a cover that has been placed on the Ka‘ba, the holiest place in Islam, since the [...] Read more.
For Muslims, the Ka‘ba holds immense significance as the destination of pilgrimage—an obligatory act of worship—and as the direction toward which prayers are performed. The kiswa is a cover that has been placed on the Ka‘ba, the holiest place in Islam, since the Jāhiliyya period as an expression of respect for it. Although there are some exceptions in Islamic history, it is usually changed once a year and it was woven in different colours according to the period, and finally it became a tradition to be black. The kiswa of the Ka‘ba is one of the most important religious and political symbols of Islamic history. This article analyses the role of the kiswa of the Ka‘ba in the relations between Muslim rulers in the Islamic world throughout history. From the earliest periods of Islam, the kiswa has been recognized as a symbol of legitimacy and a means of asserting control over the administration of pilgrimage. Many states, such as the Abbāsids, Mamlūks, and Ottomans, expressed or reinforced their political legitimacy among Muslims by showing their influence over the Ka‘ba through the tradition of the kiswa. In the medieval Islamic world, Muslim states or local administrators of these states especially used the kiswa as a symbol of sovereignty, thus increasing their influence in the regions they governed. Some Muslim administrators who wanted to send the kiswa to the Ka‘ba competed with each other or prevented the other from sending the kiswa to the Ka‘ba because each year only one kiswa was sent to Mecca. In this study, the position of the kiswa as a political symbol in the quest for the legitimacy of Muslim rulers in Islamic history and the historical development of this issue are discussed and analysed with examples. Full article
1 pages, 1262 KB  
Article
Consecrated Medicines and Spiritual Practices: A Reflection on the Many Traditions Represented in the Relics by Zur mKhar ba mNyam nyid rdo rje
by Carmela Simioli
Religions 2025, 16(3), 324; https://doi.org/10.3390/rel16030324 - 4 Mar 2025
Cited by 2 | Viewed by 3154
Abstract
This contribution is aimed at analyzing a series of life-prolonging and rejuvenating treatments (bcud len), recipes of ambrosia for immortality (bdud rtsi sman), and yogic and meditative techniques incorporated in the Man ngag bye ba ring bsrel (Ten Million [...] Read more.
This contribution is aimed at analyzing a series of life-prolonging and rejuvenating treatments (bcud len), recipes of ambrosia for immortality (bdud rtsi sman), and yogic and meditative techniques incorporated in the Man ngag bye ba ring bsrel (Ten Million of Quintessential Instructions, The Relics; henceforth Ring bsrel), a medical corpus mainly authored by Zur mkhar ba mNyam nyid rdo rje (1439–1475). The many treads of mNyam nyid rdo rje’s literary production reflect his rNying ma and bKa’ brgyud spiritual legacies: the author systematically elaborated materials drawn from the rNying ma gter ma tradition and complex medico–alchemical practices ascribed to the third Karmapa Rang byung rdo rje (1284–1339) and O rgyan pa rin chen dpal (1230–1309). The key ingredients of the recipes include saxifrage [bdud rtsi ’od ldan; Micranthes melanocentra; Saxifraga melanocentra], purple sage [lug mur; Phlomoides bracteosa], potent substances such as black aconite [bstan dug; Aconitum spicatum;], nightshade [thang phrom; Anisodus spp.; Mandragora caulescens], mercury–sulfide ashes (zla bcud; bcud rgyal), aphrodisiacs containing salamander meat [da byid, gangs sbal; Batrachuporus pinchonii], caterpillar fungus [dByar rtswa dgun ’bu; Cordyceps sinensis], and other substances endowed with hot potencies that can enhance gtum mo practices such as the dwarf rhododendron [da lis; Rhododendron spp.] and compounds containing long peer [pi pi ling; Piper longum], black pepper, [pho bar is; Piper nigrum], ginger, and so forth. The consecrated medicines and the rituals can bestow protection from any sort of diseases, diseases-carrier forces (gdon), and poisoning and lead to spiritual achievements. The analysis of these scriptural materials brings into focus the historical interrelation of diverse traditions that are represented by the heterogeneity of ideas and practices handed down through the Zur medical lineage. Full article
(This article belongs to the Special Issue Materiality and Private Rituals in Tibetan and Himalayan Cultures)
30 pages, 363 KB  
Article
Monotheistic Hindus, Idolatrous Muslims: Muḥammad Qāsim Nānautvī, Dayānanda Sarasvatī, and the Theological Roots of Hindu–Muslim Conflict in South Asia
by Fuad S. Naeem
Religions 2025, 16(2), 256; https://doi.org/10.3390/rel16020256 - 18 Feb 2025
Cited by 1 | Viewed by 4104
Abstract
Contrary to popular notions of a perpetual antagonism between ‘Hinduism’ and ‘Islam’, played out on Indian soil over the centuries, this article examines the relatively recent origins of a Hindu–Muslim conflict in South Asia, situating it in the reconfigurations of ‘religion’ and religious [...] Read more.
Contrary to popular notions of a perpetual antagonism between ‘Hinduism’ and ‘Islam’, played out on Indian soil over the centuries, this article examines the relatively recent origins of a Hindu–Muslim conflict in South Asia, situating it in the reconfigurations of ‘religion’ and religious identity that occurred under British colonial rule in the nineteenth and twentieth centuries. The multivalent and somewhat fluid categories of religious identification found in pre-modern India gave way to much more rigid and oppositional modern and colonial epistemic categories. While much has been written on how colonial policies and incipient Hindu and Muslim nationalisms shaped the contours of modern Hindu–Muslim conflict, little work has been done on the important role religious actors like Muslim and Hindu scholars and reformers played in shaping the discourse around what constituted Hinduism and Islam, and the relationship between the two, in the modern period. This study examines the first-known public theological debates between a Hindu scholar and a Muslim scholar, respectively, Swami Dayānanda Sarasvatī (1824–1883), founder of the reformist Arya Samaj and first exponent of a Hindu polemic against other religions, and Mawlānā Muḥammad Qāsim Nānautvī (1832–1880), co-founder of the seminary at Deoband and an important exponent of Islamic theological apologetics in modern South Asia, and how they helped shape oppositional modern Hindu and Muslim religious theologies. A key argument that Nānautvī contended with was Dayānanda’s claim that Islam is idolatrous, based on the contention that Muslims worship the Ka’ba, and thus, it is not a monotheistic religion, Hinduism alone being so. The terms of this debate show how polemics around subjects like monotheism and idolatry introduced by Christian missionaries under colonial rule were internalized, as were broader colonial epistemic categories, and developed a life of their own amongst Indians themselves, thus resulting in new oppositional religious identities, replacing more complex and nuanced interactions between Muslims and followers of Indian religions in the pre-modern period. Full article
17 pages, 3310 KB  
Article
Comparison of Physical, Sensorial, and Microstructural Properties to Assess the Similarity Between Plant- and Animal-Based Meat Products
by Fouad Ali Abdullah Abdullah, Matej Pospiech, Dani Dordevic and Eliska Kabourkova
Appl. Sci. 2024, 14(24), 11513; https://doi.org/10.3390/app142411513 - 10 Dec 2024
Cited by 4 | Viewed by 3409
Abstract
The aim of this study was to compare the physical, sensorial, and microstructural properties of selected meat products with their plant-based alternatives to assess how closely the alternatives mimic the original products. Six meat analogue products, including Frankfurter sausage (SuA), steak (StA), Hungarian [...] Read more.
The aim of this study was to compare the physical, sensorial, and microstructural properties of selected meat products with their plant-based alternatives to assess how closely the alternatives mimic the original products. Six meat analogue products, including Frankfurter sausage (SuA), steak (StA), Hungarian sausage (KA), minced meat (MA), salami (SaA), and burger (BA), were compared with their corresponding meat products (SuM, StM, KM, MM, SaM, and BM, respectively). The study measured colour indicators, texture parameters, sensory attributes, and microstructural properties. The redness values (a*) of the external surfaces of SuM and KM, as well as the hardness of MM, were similar to those of their alternative products, with no statistically significant differences (p > 0.05). Sensory evaluation revealed similar ratings for two attributes: product similarity and overall appearance. However, significant differences were found in the descriptors for animal character and meat taste. Full article
(This article belongs to the Special Issue Recent Processing Technologies for Improving Meat Quality)
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24 pages, 15627 KB  
Article
New Data on Boletaceae (Agaricomycetes, Basidiomycota) from Central Vietnam with Description of Two New Species and Creation of a New Combination Based on Morphological and Phylogenetic Evidence
by Thi Ha Giang Pham, Eugene Popov, Alina Alexandrova, Daria Ivanova and Olga Morozova
J. Fungi 2024, 10(3), 223; https://doi.org/10.3390/jof10030223 - 19 Mar 2024
Cited by 3 | Viewed by 3729
Abstract
Two new species of Boletaceae (Hortiboletus rubroreticulatus and Tylopilus aurantiovulpinus) discovered during an investigation of the mycobiota of Central Vietnam (Kon Chu Rang Nature Reserve; Ta Dung National Park; Bidoup—Nui Ba National Park; Kon Ka Kinh National Park) are described on [...] Read more.
Two new species of Boletaceae (Hortiboletus rubroreticulatus and Tylopilus aurantiovulpinus) discovered during an investigation of the mycobiota of Central Vietnam (Kon Chu Rang Nature Reserve; Ta Dung National Park; Bidoup—Nui Ba National Park; Kon Ka Kinh National Park) are described on the basis of molecular and morphological data. Illustrated descriptions of their macro- and microscopic features and discussion on similar taxa are given. Additionally, eight species which were recorded for the first time in Vietnam are listed and illustrated here. A new combination Kgaria virescens was made for one of these species. These results were confirmed by the phylogenetic analysis based on nrITS1-5.8S-ITS2, nrLSU, and tef1α regions. Full article
(This article belongs to the Special Issue Taxonomy, Systematics and Evolution of Forestry Fungi, 2nd Edition)
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15 pages, 11986 KB  
Article
Phylogenetic Analysis of the PR-4 Gene Family in Euphorbiaceae and Its Expression Profiles in Tung Tree (Vernicia fordii)
by Chengbo Yang, Yaqi Yi, Jiabei Wang, Liu Ge, Lin Zhang and Meilan Liu
Plants 2023, 12(17), 3154; https://doi.org/10.3390/plants12173154 - 1 Sep 2023
Viewed by 1860
Abstract
Pathogenesis-related protein-4 (PR-4) is generally believed to be involved in physiological processes. However, a comprehensive investigation of this protein in tung tree (Vernicia fordii) has yet to be conducted. In this study, we identified 30 PR-4 genes in the [...] Read more.
Pathogenesis-related protein-4 (PR-4) is generally believed to be involved in physiological processes. However, a comprehensive investigation of this protein in tung tree (Vernicia fordii) has yet to be conducted. In this study, we identified 30 PR-4 genes in the genomes of Euphorbiaceae species and investigated their domain organization, evolution, promoter cis-elements, expression profiles, and expression profiles in the tung tree. Sequence and structural analyses indicated that VF16136 and VF16135 in the tung tree could be classified as belonging to Class II and I, respectively. Phylogenetic and Ka/Ks analyses revealed that Hevea brasiliensis exhibited a significantly expanded number of PR-4 genes. Additionally, the analysis of promoter cis-elements suggested that two VfPR-4 genes may play a role in the response to hormones and biotic and abiotic stress of tung trees. Furthermore, the expression patterns of VfPR-4 genes and their responses to 6-BA, salicylic acid, and silver nitrate in inflorescence buds of tung trees were evaluated using qRT-PCR. Notably, the expression of two VfPR-4 genes was found to be particularly high in leaves and early stages of tung seeds. These results suggest that VF16136 and VF16135 may have significant roles in the development of leaves and seeds in tung trees. Furthermore, these genes were found to be responsive to 6-BA, salicylic acid, and silver nitrate in the development of inflorescence buds. This research provides valuable insights for future investigation into the functions of PR-4 genes in tung trees. Full article
(This article belongs to the Section Plant Genetics, Genomics and Biotechnology)
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15 pages, 2969 KB  
Article
Marine Calcareous Biological Ooze Thermoluminescence and Its Application for Paleoclimate Change since the Middle Pleistocene
by Ping Zhang, Haisheng Liu, Shengli Hou, Nanping Wang and Nianqiao Fang
Water 2023, 15(14), 2618; https://doi.org/10.3390/w15142618 - 19 Jul 2023
Cited by 2 | Viewed by 2531
Abstract
Natural thermoluminescence (TL) from the core of MD81349 marine calcareous biological ooze samples in the Ninetyeast Ridge of the equatorial northeast Indian Ocean and from the core of IODP306-U1312B in the high latitudes of the North Atlantic Ocean was studied. The spurious TL [...] Read more.
Natural thermoluminescence (TL) from the core of MD81349 marine calcareous biological ooze samples in the Ninetyeast Ridge of the equatorial northeast Indian Ocean and from the core of IODP306-U1312B in the high latitudes of the North Atlantic Ocean was studied. The spurious TL intensity of 395 °C at its peak is dose independent when the heating rate is 6 °C/s in a nitrogen atmosphere. TL signals have exhibited a significant correlation with the marine isotope stages (MIS) in the two oceans since the mid-Pleistocene era. High TL intensity corresponds to a negative δ18O in the interglacial stages, and low TL intensity corresponds to a positive δ18O in the glacial stages. The TL of both cores from the two oceans reveal that global climate has experienced eight cold and warm cycles since the mid-Pleistocene era. In this study, a single-frequency spectrum analysis of the MD81349 and U1312B TL cores in the last 300 ka is performed. Near the equator of the northeast Indian Ocean, the short cycles of 38 ka and 5 ka are more significant, while the cycle of 8 ka is more significant in the North Atlantic Ocean. In addition, a correlation analysis shows that the TL has a significant positive correlation with the trace element 135Ba and a significant negative correlation with 47Ti. The impurity ions (e.g., Ba2+, Mn2+ and Ti2+) doped in carbonate act as activators and suppressants, respectively. A time series of the TL of the calcareous biological ooze tests provide an important record of climate change. The source of the TL signal is also discussed. Full article
(This article belongs to the Section Oceans and Coastal Zones)
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22 pages, 9291 KB  
Review
Recent Progress in Diboronic-Acid-Based Glucose Sensors
by Ke Nan, Yu-Na Jiang, Meng Li and Bing Wang
Biosensors 2023, 13(6), 618; https://doi.org/10.3390/bios13060618 - 4 Jun 2023
Cited by 19 | Viewed by 6005
Abstract
Non-enzymatic sensors with the capability of long-term stability and low cost are promising in glucose monitoring applications. Boronic acid (BA) derivatives offer a reversible and covalent binding mechanism for glucose recognition, which enables continuous glucose monitoring and responsive insulin release. To improve selectivity [...] Read more.
Non-enzymatic sensors with the capability of long-term stability and low cost are promising in glucose monitoring applications. Boronic acid (BA) derivatives offer a reversible and covalent binding mechanism for glucose recognition, which enables continuous glucose monitoring and responsive insulin release. To improve selectivity to glucose, a diboronic acid (DBA) structure design has been explored and has become a hot research topic for real-time glucose sensing in recent decades. This paper reviews the glucose recognition mechanism of boronic acids and discusses different glucose sensing strategies based on DBA-derivatives-based sensors reported in the past 10 years. The tunable pKa, electron-withdrawing properties, and modifiable group of phenylboronic acids were explored to develop various sensing strategies, including optical, electrochemical, and other methods. However, compared to the numerous monoboronic acid molecules and methods developed for glucose monitoring, the diversity of DBA molecules and applied sensing strategies remains limited. The challenges and opportunities are also highlighted for the future of glucose sensing strategies, which need to consider practicability, advanced medical equipment fitment, patient compliance, as well as better selectivity and tolerance to interferences. Full article
(This article belongs to the Section Biosensors and Healthcare)
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12 pages, 2425 KB  
Article
Mixed Metal Phosphonates: Structure and Proton Conduction Manipulation through Various Alkaline Earth Metal Ions
by Song-Song Bao, Nan-Zhu Li, Yu-Xuan Wu and Yang Shen
Crystals 2022, 12(11), 1648; https://doi.org/10.3390/cryst12111648 - 16 Nov 2022
Cited by 2 | Viewed by 1720
Abstract
Three new layered mixed metal phosphonates [CoMg(notpH2)(H2O)2]ClO4·nH2O (CoMg·nH2O), [Co2Sr2(notpH2)2(H2O)5](ClO4)2·nH2O (CoSr·nH [...] Read more.
Three new layered mixed metal phosphonates [CoMg(notpH2)(H2O)2]ClO4·nH2O (CoMg·nH2O), [Co2Sr2(notpH2)2(H2O)5](ClO4)2·nH2O (CoSr·nH2O), and [CoBa(notpH2)(H2O)1.5]ClO4 (CoBa) were synthesized by reacting a tripodal metalloligand CoIII(notpH3) [notpH6 = C9H18N3(PO3H2)3] with alkaline earth metal ions. Along with an increase in the radius of the alkaline earth metal ions, the 6-coordinate {MgO6}, 7-coordinate {SrO7}, and 9-coordinate {BaO9} geometries are the distorted octahedron, capped triangular prism, and tricapped triangular prism, respectively. Consequently, the metalloligand Co(notpH2) adopts variable coordination modes to bind the alkaline earth metal nodes, forming diverse layer topologies in the three mixed metal phosphonates. The AC impedance measurements revealed that the proton conductivities at 25 °C and 95% relative humidity (RH) follow the sequence: CoMg·nH2O > CoSr·nH2O > CoBa. As expected, CoMg·nH2O exhibits a 28-fold enhanced value for proton conductivity (4.36 × 10−4 S cm−1) compared with the previously reported isostructural compound, CoCa·nH2O, at 25 °C and 95% RH due to the greater Lewis acid strength of Mg(II) lowering the pKa of the coordinated water. Full article
(This article belongs to the Special Issue Mixed-Metal Coordination Polymers)
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11 pages, 1736 KB  
Article
The Use of Fluorescence Spectroscopic Data and Machine-Learning Algorithms to Discriminate Red Onion Cultivar and Breeding Line
by Kadir Sabanci, Muhammet Fatih Aslan, Vanya Slavova and Stefka Genova
Agriculture 2022, 12(10), 1652; https://doi.org/10.3390/agriculture12101652 - 9 Oct 2022
Cited by 6 | Viewed by 3108
Abstract
The objective of this study was to evaluate differences between the red onion cultivar and breeding line using models based on selected fluorescence spectroscopic data built using machine-learning algorithms from different groups of Trees, Functions, Bayes, Meta, Rules, and Lazy. The combination of [...] Read more.
The objective of this study was to evaluate differences between the red onion cultivar and breeding line using models based on selected fluorescence spectroscopic data built using machine-learning algorithms from different groups of Trees, Functions, Bayes, Meta, Rules, and Lazy. The combination of fluorescence spectroscopy and machine learning is an original approach to the non-destructive and objective discrimination of red onion samples. The selected fluorescence spectroscopic data were used to build models using algorithms from the groups of Trees, Functions, Bayes, Meta, Rules, and Lazy. The most satisfactory results were obtained using J48 and LMT (Logistic Model Tree) from the group of Trees, Multilayer Perceptron, and QDA (Quadratic Discriminant Analysis) from Functions, Naive Bayes from Bayes, Logit Boost from Meta, JRip from Rules, and LWL (Locally Weighted Learning) from Lazy. The average accuracy of discrimination of onion bulbs belonging to ‘Asenovgradska kaba’ and a red breeding line equal to 100% was found in the case of models developed using the LMT, Multilayer Perceptron, Naive Bayes, Logit Boost, and LWL algorithms. The TPR (True Positive Rate), Precision, and F-Measure of 1.000 and FPR (False Positive Rate) of 0.000, as well as the Kappa statistic of 1.0, were determined. The results revealed the usefulness of the approach combining fluorescence spectroscopy and machine learning to distinguish red onion cultivars and breeding lines. Full article
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12 pages, 3346 KB  
Article
Geochronological Evidence Inferring Carbonate Compensation Depth Shoaling in the Philippine Sea after the Mid-Brunhes Event
by Dong Xu, Liang Yi, Haifan Yuan and Weiwei Chen
J. Mar. Sci. Eng. 2022, 10(6), 745; https://doi.org/10.3390/jmse10060745 - 28 May 2022
Cited by 6 | Viewed by 2712
Abstract
Carbonate compensation depth (CCD) is an important factor in the global deep ocean and in global carbon cycling; however, its variabilities have not been well documented in previous studies. In this study, we investigate two deep-sea cores collected from the Philippine Sea in [...] Read more.
Carbonate compensation depth (CCD) is an important factor in the global deep ocean and in global carbon cycling; however, its variabilities have not been well documented in previous studies. In this study, we investigate two deep-sea cores collected from the Philippine Sea in terms of geochronology and geochemical properties over the past ~900 kyr. The principle results are as follows: (1) Two magnetozones are determined from the sediment’s magnetic records, which can be correlated with the Brunhes and Matuyama chrons in the geomagnetic polarity timescale. (2) The age models can be refined by tuning the Ba and Sm intensities of the two studied cores to the global ice volume, and the estimated sediment accumulation rate is ~4 mm/kyr. (3) Chalky mud and the bulk carbon δ13C record vary abruptly at ~430 ka and imply 200 m shoaling of the CCD. Based on these results, a close link is inferred between marine productivity, aeolian dust, and CCD changes, which can be correlated with a major change that occurred during the Mid-Brunhes Event. Therefore, we propose that the sedimentary processes in the Philippine Sea are evidence of global climate change, providing a unique window to observe interactions between various environmental systems. Full article
(This article belongs to the Section Geological Oceanography)
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