Search Results (14)

The Permian Kupferschiefer shale, a key stratigraphic unit within the Zechstein sequence of the Fore-Sudetic Monocline, represents both a metal-rich lithofacies and a potential source rock for hydrocarbon generation. This study presents a comprehensive geochemical characterization of selected Kupferschiefer samples obtained from the Legnica–Głogów Copper District (LGOM) and exploratory boreholes. Analytical methods included Rock-Eval pyrolysis, Py-GC/FID, elemental analysis, TG-FTIR, biomarker profiling, and stable carbon isotope measurements. Results indicate that the shales contain significant amounts of Type II and mixed Type II/III kerogen, derived primarily from marine organic matter with minor terrestrial input. The organic matter maturity, expressed by T_max, places most samples within the oil window. Rock-Eval S2 values exceed 60 mg HC/g rock in some samples, confirming excellent generative potential. Py-GC/FID data further support high hydrocarbon yields, particularly in samples from the CG-4 borehole and LGOM mines. The thermal decomposition of kerogen reveals multiple degradation phases, with evolved gas analysis identifying sulfur-containing compounds and hydrocarbons indicative of sapropelic origin. Isotopic compositions of bitumen and kerogen suggest syngenetic relationships and marine depositional settings, with samples from a North Poland borehole showing isotopic enrichment consistent with post-depositional oxidation. Kinetic parameters calculated using the Kissinger–Akahira–Sunose method demonstrate variable activation energies (107–341 kJ/mol), correlating with differences in organic matter composition and mineral matrix. The observed variability in geochemical properties highlights both regional and facies-dependent influences on the shale’s generative capacity. The study concludes that the Kupferschiefer in southwestern and northern Poland exhibits substantial hydrocarbon generation potential. This potential has been previously underestimated due to the unit’s thinness, but localized zones with high TOC, favorable kerogen type, and low activation energy could be viable exploration targets for natural gas. Full article

The aim of this research was to determine a relationship that would allow the results of the enrichment process to be predicted from the mineral and chemical composition of the of sedimentary copper ores present in the Fore-Sudetic monocline (SW Poland). A series of laboratory flotation tests of feeds with different lithological compositions of copper ores (sandstone, dolomitic, and shale) as well as detailed chemical and mineral analyses of feeds and flotation products were carried out. Based on the obtained results, enrichment selectivity indicators were determined and used in modeling. Among the methods of statistical dimensional analysis, multivariate correlation was used for modeling. The result of modeling was the equation that allowed the prediction of the results of the copper ore enrichment process from the contents of the main rock-forming minerals (clays/micas and carbonates) and copper in the feed. The equation is highly precise and can be used to predict the results of copper ore enrichment on the basis of the mineral and chemical compositions of the feed (correlation coefficient of 0.78). The proposed equations may be employed in an industrial process to determine its metallurgical result in the case of variable ore lithology. Full article

This paper addresses the problem of the geothermal energy generation process in a depleted gas reservoir with a specific enhanced geothermal system, applying CO₂ as an energy transporting medium. Constructed models of the system components are used to perform coupled and dynamic simulation forecasts, taking into account the interdependence of the individual system elements operating in a cyclical fluid flow and the continuous changes in temperature, pressure, and the composition of circulating fluids. The simulation procedure of the geothermal energy generation process is applied to the realistic example of a depleted gas reservoir located in Foresudetic Monocline, Poland. The simulation results are presented in detail and discussed with several conclusions of both case-specific and general characters. Three phases of the energy recovery process can be distinguished, varying in the produced fluid composition and the evolution of the fluid temperature. These phases result in the corresponding behavior of the produced stream power: increasing, stable, and decreasing for the three phases, respectively. Other significant results of the simulation forecasts are also discussed and concluded. In general, the complexity of the obtained results proves the necessity to apply the system’s detailed modeling and simulations to reliably plan and realize a geothermal energy generation project. Full article

The discovery of the Northern Copper Belt in SW Poland is a result of an extensive exploration project with a key role played by various science-related methods. The project relied on mapping the distribution of mineral zones in the entire Fore-Sudetic Monocline, a unit known for its occurrences of Cu-Ag orebodies. This approach involved the examination of historical drill cores from over 400 oil and gas holes in this area, with the collection of samples for laboratory analyses. A close relationship was confirmed between the distribution of orebodies and the transformation of organic matter. Rock-Eval pyrolysis was also performed on selected samples. The tests of rock specimens were accompanied by the reprocessing of historical gravimetric and seismic surveying results. Field magnetotelluric surveying was also performed in certain areas. This phase resulted in the identification of areas with a high probability of finding the best ore, allowing for the initiation of the drilling stage. So far, 37 exploratory boreholes have been drilled in those locations, nearly all of them with highly positive results. The Northern Copper Belt consists of three deposits, Nowa Sól, Mozów, and Sulmierzyce North, along with numerous prognostic areas distributed therebetween. The future production of copper, silver, and the accompanying valuable elements presents a chance to provide the whole of Europe with a new plentiful supply of those critical raw materials. Full article

The study evaluates the geothermal energy potential of two depleted oil and gas reservoirs representing two different lithostratigraphic formations—the carbonate formation of the Visean age from the basement of the Carpathian Flysch and the Rotliegend sandstone formation from the Eastern part of the Foresudetic Monocline, Poland. Advanced modeling techniques were employed to analyze the studied formations’ heat, storage, and transport properties. The obtained results were then used to calculate the heat in place (HIP) and evaluate the recoverable heat (Hrec) for both water and CO₂ as working fluids, considering a geothermal system lifetime of 50 years. The petrophysical parameters and Hrec were subsequently utilized in the generalized c-means (GFCM) clustering analysis, which helped to identify plays with the greatest geothermal potential within the studied formations. The central block emerged as the most promising area for the studied carbonate formation with Hrec values of ~1.12 and 0.26 MW when H₂O and CO₂ were used as working fluids, respectively. The central block has three wells that can be easily adapted for geothermal production. The area, however, may require permeability enhancement techniques to increase reservoir permeability. Two prospective zones were determined for the analyzed Rotliegend sandstone formation: one in the NW region and the other in the SE region. In the NW region, the estimated Hrec was 23.16 MW and 4.36 MW, while in the SE region, it was 19.76 MW and 3.51 MW, using H₂O and CO₂ as working fluids, respectively. Both areas have high porosity and permeability, providing good storage and transport properties for the working fluid, and abundant wells that can be configured for multiple injection-production systems. When comparing the efficiency of geothermal systems, the water-driven system in the Visean carbonate formation turned out to be over four times more efficient than the CO₂-driven one. Furthermore, in the case of the Rotliegend sandstone formation, it was possible to access over five times more heat using water-driven system. Full article

The paper aims to give a universal methodology for assessing the storage capacity of a bedded rock salt formation in terms of the operational and strategic storage facilities for liquid fuels. The method assumes the development of a geological model of the analyzed rock salt formation and the determination of the salt caverns’ size and spacing and the impact of convergence on their capacity during operation. Based on this method, the paper presents calculations of the storage capacity using the example of the bedded rock salt formations in Poland and their results in the form of storage capacity maps. The maps show that the analyzed rock salt deposits’ storage capacity in northern Poland amounts to 7.1 B m³ and in the Fore-Sudetic Monocline to 10.5 B m³, in the case of strategic storage facilities. The spatial analysis of the storage capacity rasters, including determining the raster volumes and their unique values, allowed us to quantify the variability of the storage capacity in the analyzed rock salt deposits. Full article

A significant part of organic carbon found on the earth is deposited as fossil organic matter in the lithosphere. The most important reservoir of carbon is shale rocks enriched with organic matter in the form of kerogen created during diagenesis. The purpose of this study was to analyze whether the bacterial communities currently inhabiting the shale rocks have had any impact on the properties and type of kerogen. We used the shale rock located on the Fore-Sudetic Monocline, which is characterized by oil-prone kerogen type II. We were able to show that shale rock inhabited by bacterial communities are characterized by oxidized and dehydrated kerogen type III (gas-prone) and type IV (nonproductive, residual, and hydrogen-free). Bacterial communities inhabiting shale rock were dominated by heterotrophs of the Proteobacteria, Firmicutes, and Actinobacteria phyla. Additionally, we detected a number of protein sequences in the metaproteomes of bacterial communities matched with enzymes involved in the oxidative metabolism of aliphatic and aromatic hydrocarbons, which may potentially contribute to the postdiagenetic oxidation and dehydrogenation of kerogen. The kerogen transformation contributes to the mobilization of fossil carbon in the form of extractable bitumen dominated by oxidized organic compounds. Full article

This study describes for the first time the comprehensive characterization of tetrapyrrole cofactor biosynthetic pathways developed for bacterial community (BC) inhabiting shale rock. Based on the genomic and proteomic metadata, we have detailed the biosynthesis of siroheme, heme, cobalamin, and the major precursor uroporphyrinogen III by a deep BC living on a rock containing sedimentary tetrapyrrole compounds. The obtained results showed the presence of incomplete heme and cobalamin biosynthesis pathways in the studied BC. At the same time, the production of proteins containing these cofactors, such as cytochromes, catalases and sulfite reductase, was observed. The results obtained are crucial for understanding the ecology of bacteria inhabiting shale rock, as well as their metabolism and potential impact on the biogeochemistry of these rocks. Based on the findings, we hypothesize that the bacteria may use primary or modified sedimentary porphyrins and their degradation products as precursors for synthesizing tetrapyrrole cofactors. Experimental testing of this hypothesis is of course necessary, but its evidence would point to an important and unique phenomenon of the tetrapyrrole ring cycle on Earth involving bacteria. Full article

The paper presents the latest state of knowledge on clastic sedimentary rocks from the Carboniferous complex in the SW part of the Polish Lowlands, studied to help determine their potential prospectivity for the occurrence of oil and/or gas deposits. Rocks were analyzed with respect to the petrographic-mineralogical characteristics of the Carboniferous deposits, their diagenesis, determinations of pressure-temperature conditions of mineral formation and the hydrocarbon occurrence. Analyses were carried out on samples from four selected boreholes in the Fore-Sudetic Monocline. After microscopic analysis of rocks and minerals in thin sections, the following techniques were used: luminescence analysis (UV, blue light), microthermometric analysis of fluid inclusions in double-sided polished wafers, cathodoluminescence analysis, electron scanning microscope studies, XRD analyses, stable isotopic analyses (carbon, oxygen) on calcite and dolomite-ankerite and Raman spectra of fluid inclusions. Orthochemical components, such as carbonates and authigenic quartz, that form cements or fill the veins cutting the sample material have been studied. Fluid inclusion data in quartz and carbonates result in homogenization temperatures of 74–233 °C. The Raman analysis gives temperature estimations for the organic matter of about 164 °C and 197 °C, depending on the borehole, which points to a low coalification degree. The post-sedimentary processes of compaction, cementation and diagenetic dissolution under eo- and meso-diagenetic conditions to temperatures of over 160 °C influenced the present character of the deposits. P-T conditions of brines and methane trapping have been estimated to be ~850–920 bars and 185–210 °C (vein calcite) and ~1140 bars and 220 °C (Fe-dolomite/ankerite). Therefore, locally, temperatures might have been higher (>200 °C), which may be a symptom of local regional metamorphism of a very low degree. Full article

The chalcocite group minerals are widely distributed among different hydrothermally affected rocks, the oxidized zone of copper sulfide deposits, or may be even crystalline from supersaturated volcanic gases. Some of the chalcocite group minerals form the main Cu orebodies. Djurleite (Cu₃₁S₁₆) is a rare member of the chalcocite group, with a very complex structure. The physical and chemical similarities between all members of the group make them almost unidentifiable by macroscopic and microscopic methods. In this study, Ag-bearing djurleite from the Kupferschiefer deposits, Lower Silesia, Poland, is characterized by EMPA (Electron Microprobe Analyses), XRD (X-Ray Diffraction), and Raman spectroscopy. Djurleite from the investigated site has the following general, average chemical formula: Cu_30.86Ag_0.1Fe_0.04S₁₆. The Ag content is up to 0.55 wt.%, while Fe is up to 0.19 wt.%. The presence of djurleite confirms a low-temperature (~90 °C), hydrothermal origin of the Cu-Ag deposit in Kupferschiefer, which is consistent with previously studies. Moreover, the authors believe that Ag-rich djurleite may often be mistaken for Ag-rich chalcocite, which used to be one of the main Ag-bearing minerals in the orebody from the Cu-Ag deposit in the Fore-Sudetic Monocline. However, the confirmation of such a statement requires more samples, which should be studied in detail. Full article

Changes in the stress field in Świebodzice Depression (ŚU) unit area are the reason of complex kinematics of the rock blocks consisting of rotations and horizontal/vertical displacements. The measurement system of the Geodynamic Laboratory in Książ, associated with rock blocks which are separated by faults, is a natural detector of tectonic activity. Installed in laboratory long water-tube gauges allowing to determine the functions of tectonic activity—TAF, and their derivatives. A comparison of the TAF with the seismic activity of the Fore-Sudetic Monocline showed that the strong seismic shocks (magnitude ≥3.6) occur in the Monocline only during defined and repeatable phases of the kinematic activity of the ŚU. Observed concordance proves the thesis of the existence of a large-scale, and largely homogeneous field of tectonic forces which, at the same time, cover the ŚU and the Fore-Sudetic Monocline units. The results of comparison between seismic events temporal distribution and phases of tectonic activity of the ŚU orogen indicate existence of the time relation between function of derivative of the tectonic activity (TAF) and seismic events. Full article

This paper presents a new instrument in geological exploration, which uses historical geophysical data for the indication of potential zones of the occurrence of Cu-Ag ore, based on the example of the newly discovered Nowa Sól deposit in south-western Poland. Basic historical seismic and gravimetric data were applied along with transformed maps. The new method of effective reflection coefficients (ERC) allowed the utilization of archival seismic records for a more precise determination of the most vaguely traced interfaces within the Permian Zechstein unit. Compared to an amplitude-based seismic section, an ERC section is characterized by its highly increased resolution of imaging. The tracing of changes in the facies and the tectonics of Zechstein sediments, particularly in a zone of their contact with Rotliegend rocks, along with the new ERC method, enabled the establishing of precise locations of prospecting boreholes. The combined use of ERC and historical well logs also allowed more precise identification of the shape of oxidized areas and the adjacent orebodies. Full article

Na-Cu carbonates are relatively rare secondary minerals in weathering zones of ore deposits. Hereby we describe mineral composition and crystal chemistry of the most important secondary (Na)Cu minerals and their Na- and Mg-bearing associates forming rich paragenesis in Rudna IX mine. A non-bulky Ca-rich dripstone-like paragenesis from Lubin Główny mine is also characterized, using Powder X-Ray Diffraction, Rietveld, and Electron Microprobe methods. Light blue juangodoyite (3rd occurrence worldwide) and darker chalconatronite are the most important members of the Rudna IX paragenesis, being associated with malachite, aragonite (intergrown with hydromagnesite and northupite), and probably cornwallite. Most of the minerals are chemically close to their ideal composition, with minor Mg substitution in malachite. Cu chlorides are mainly represented by clinoatacamite and probably herbertsmithite. Additional, minor phases include trace Cu minerals langite, wroewolfeite, and a lavendulan-group mineral, and monohydrocalcite. Separate halite-rich encrustations are shown to be filled with eriochalcite, ktenasite, and kröhnkite. The most likely to be confirmed coexisting species include paratacamite, wooldridgeite/nesquehonite, johillerite, melanothallite, and kipushite. The Lubin paragenesis mainly comprises aragonite, gypsum, rapidcreekite, and monohydrocalcite, with trace vaterite. Blue colouration is mainly provided by a yet unspecified Ni-, Co-, Mg-, and Mn-bearing Cu-Zn-Ca arsenate mineral close to parnauite. Full article

Polish sediment-hosted stratiform copper deposits associated with Zechstein sediments are one of the country’s most valuable natural resources and the basis for its copper industry. The paper presents the history of their research and current exploration. Although documented deposits and their identified resources are described and characterized, much attention is paid to areas located outside of them, including those where geological exploration is currently underway. The gradual depletion of shallow Cu–Ag reserves in the Lubin-Sieroszowice district and elsewhere in the world requires exploration for deeper-seated deposits. To expand resources, time span and scale of copper production in Poland, exploration and definition of new prospects is of great importance. Thirty-five prospective areas with hypothetical and speculative resources have been delineated in SW Poland, including the most prospective areas adjacent to the Cu–Ag Lubin-Sieroszowice deposit. The paper also focuses on those parts of the Fore-Sudetic Monocline where new copper deposits were recently identified. Their resources are described along with the methodology of establishing their boundaries, which differs from recommended Polish threshold parameters not taking into account the depths exceeding 1500 m. Intelligent modern mining and ore processing technologies are considered as a prerequisite for future profitable development of deposits at deeper levels. Full article