Search Results (19)

The use of perovskite manganite nanoparticles in magnetic hyperthermia has attracted significant attention due to their tunable magnetic properties and high specific absorption rate (SAR). In this work, we present a combined experimental and theoretical investigation of the frequency- and amplitude-dependent magnetic heating behavior of La_0.51Sr_0.49MnO₃ (LSMO) and Dy-doped La_0.51Dy_0.045Sr_0.445MnO₃ (DLSMO) nanoparticles. The nanoparticles were synthesized via the sol–gel method and characterized by XRD and SEM, while SAR values were experimentally evaluated under varying magnetic field strengths (60–120 Oe) and frequencies (150–300 kHz). In parallel, theoretical modeling based on Néel and Brownian relaxation mechanisms was employed to predict SAR behavior as a function of particle size, magnetic anisotropy, and fluid viscosity. The results reveal that Dy doping enhances magnetic anisotropy, which modifies the relaxation dynamics and leads to a reduction in SAR. The model identifies the optimal nanoparticle size (~18–20 nm) and ferrofluid viscosity to maximize heating efficiency. This combined approach provides a comprehensive framework for designing and optimizing perovskite-based nanoparticles for magnetic hyperthermia applications. Full article

In order to reduce the sintering temperature, MnO₂ was used as a sintering aid to prepare [(Ba_0.85Ca_0.15)_0.999(Dy_0.5Tb_0.5)_0.001](Zr_0.1Ti_0.9)O₃-x mol% MnO₂ (BCDTZT-x mol% MnO₂, x = 0.05, 0.2, 0.4, 0.6, 0.8, 1, 1.5, 3) lead-free piezoelectric ceramics in which the effects of the MnO₂ doping amount and sintering temperature on the phase structure, sintering behavior, and electrical properties of the BCDTZT-x mol% MnO₂ ceramics were systematically analyzed. All ceramics have a single perovskite structure and coexist in multiple phases. The optimal sintering temperature was reduced from 1515 °C to 1425 °C, and the density of all ceramics was increased as compared with the undoped ceramic, reaching a maximum of 5.38 g/cm³ at x = 0.8 mol%. An appropriate MnO₂ doping amount of 0.4 mol% could effectively suppress oxygen vacancies and improve electrical properties, resulting in the best comprehensive performance of the ceramics, with a dielectric constant maximum of 12,817, a high piezoelectric constant of 330 pC/N, and good strain value (S_max = 0.118%) and low strain hysteresis (Hys = 2.66%). The calculation of activation energy indicated that the high-temperature conductivity was dominated by oxygen vacancies in all ceramics. The results showed that the appropriate introduction of MnO₂ as a sintering aid could improve the performance of BCZT-based ceramics while reducing the sintering temperature, presenting high practical application value in the fields of low electric field sensors and actuators. Full article

In order to break through the limitations of the application of traditional temperature measurement technology, non-contact optical temperature sensing material with good sensitivity is one of the current research hotspots. Herein, a series of Dy³⁺ and Mn⁴⁺ co-doping Mg₃Ga₂SnO₈ fluorescent materials were prepared successfully, and the crystal structure, phase purity, and morphology of the synthesized phosphors were comprehensively investigated, as well as their photoluminescence properties, energy transfer, and high-temperature thermal stability. The two pairs of independent thermally coupled energy levels of Dy³⁺ ions and Mn⁴⁺ ions in Mg₃Ga₂SnO₈ are utilized to realize the dual-mode optical temperature detection with excellent performance. On the one hand, based on the different ionic energy level transitions of ⁴F_9/2→⁶H_13/2 and ²E_g→⁴A_2g responding differently to temperature, two emission bands of 577 nm and 668 nm were chosen to construct the fluorescence intensity ratio thermometry, and the maximum sensitivity of 1.82 %K⁻¹ was achieved at 473 K. On the other hand, based on the strong temperature dependence of the lifetime of Mn⁴⁺ in Mg₃Ga₂SnO₈:0.06Dy³⁺,0.009Mn⁴⁺, fluorescence lifetime thermometry was constructed and a maximum sensitivity of 2.75 %K⁻¹ was achieved at 473 K. Finally, the Mg₃Ga₂SnO₈: 0.06Dy³⁺,0.009Mn⁴⁺ sample realizes dual-mode optical temperature measurement with high sensitivity and a wide temperature detection range, indicating that the sample has promising applications in optical temperature measurement. Full article

ABO₃ perovskite materials with small cations at the A site, especially with ordered cation arrangements, have attracted a lot of interest because they show unusual physical properties and deviations from general perovskite tendencies. In this work, A-site-ordered quadruple perovskites, RMn₃Ni₂Mn₂O₁₂ with R = Nd, Sm, Gd, and Dy, were synthesized by a high-pressure, high-temperature method at about 6 GPa. Annealing at about 1500 K produced samples with additional (partial) B-site ordering of Ni²⁺ and Mn⁴⁺ cations, crystallizing in space group Pn–3. Annealing at about 1700 K produced samples with disordering of Ni²⁺ and Mn⁴⁺ cations, crystallizing in space group Im–3. However, magnetic properties were nearly identical for the Pn–3 and Im–3 modifications in comparison with ferromagnetic double perovskites R₂NiMnO₆, where the degree of Ni²⁺ and Mn⁴⁺ ordering has significant effects on magnetic properties. In RMn₃Ni₂Mn₂O₁₂, one magnetic transition was found at 26 K (for R = Nd), 23 K (for R = Sm), and 22 K (for R = Gd), and two transitions were found at 10 K and 36 K for R = Dy. Curie–Weiss temperatures were close to zero in all compounds, suggesting that antiferromagnetic and ferromagnetic interactions are of the same magnitude. Full article

A Dy(III) coordination polymer (CP), [Dy(spasds)(H₂O)₂]_n (1) (Na₂Hspasds = 5-(4-sulfophenylazo)salicylic disodium salt), has been synthesized using a hydrothermal method and characterized. 1 features a 2D layered structure, where the spasda³⁻ anions act as pentadentate ligands, adopting carboxylate, sulfonate and phenolate groups to bridge with four Dy centers in η₃-μ¹: μ², η₂-μ¹: μ¹, and monodentate coordination modes, respectively. It possesses a unique (4,4)-connected net with a Schläfli symbol of {4⁴·6²}{4}₂. The luminescence study revealed that 1 exhibited a broad fluorescent emission band at 392 nm. Moreover, the visual blue color has been confirmed by the CIE plot. 1 can serve as a dual-functional luminescent sensor toward Fe³⁺ and MnO₄⁻ through the luminescence quenching effect, with limits of detection (LODs) of 9.30 × 10⁻⁷ and 1.19 × 10⁻⁶ M, respectively. The LODs are relatively low in comparison with those of the reported CP-based sensors for Fe³⁺ and MnO₄⁻. In addition, 1 also has high selectivity and remarkable anti-interference ability, as well as good recyclability for at least five cycles. Furthermore, the potential application of the sensor for the detection of Fe³⁺ and MnO₄⁻ was studied through simulated wastewater samples with different concentrations. The possible sensing mechanisms were investigated using Ultraviolet-Visible (UV-Vis) absorption spectroscopy and density functional theory (DFT) calculations. The results revealed that the luminescence turn-off effects toward Fe³⁺ and MnO₄⁻ were caused by competitive absorption and photoinduced electron transfer (PET), and competitive absorption and inner filter effect (IFE), respectively. Full article

A novel Mn/TiO₂ catalyst, prepared through modification with the rare-earth metal Dy, has been employed for low-temperature selective catalytic reduction (SCR) denitrification. Anatase TiO₂, with its large specific surface area, serves as the carrier. The active component MnO_x on the TiO₂ carrier is modified using Dy. Dy_xMn/TiO₂, prepared via the impregnation method, exhibited remarkable catalytic performance in the SCR of NO with NH₃ as the reducing agent at low temperatures. Experiments and characterization revealed that the introduction of a suitable amount of the rare-earth metal Dy can effectively enhance the catalyst’s specific surface area and the gas–solid contact area in catalytic reactions. It also significantly increases the concentration of Mn⁴⁺, chemisorbed oxygen, and weak acid sites on the catalyst surface. This leads to a notable improvement in the reduction performance of the DyMn/TiO₂ catalyst, ultimately contributing to the improvement of the NH₃-SCR denitrification performance at low temperatures. At 100 °C and a space velocity of 24,000 h⁻¹, the Dy_0.1Mn/TiO₂ catalyst can achieve a 98% conversion rate of NO_x. Furthermore, its active temperature point decreases by 60 °C after the modification, highlighting exceptional catalytic efficacy at low temperatures. By doubling the space velocity, the NO_x conversion rate of the catalyst can still reach 96% at 130 °C, indicating significant operational flexibility. The selectivity of N₂ remained stable at over 95% before reaching 240 °C. Full article

DyMnO₃ is a p-type semiconductor oxide with two crystal systems, orthorhombic and hexagonal. This material highlights its ferroelectric and ferromagnetic properties, which have been the subject of numerous studies. Nevertheless, its photocatalytic activity has been less explored. In this work, the photocatalytic activity of DyMnO₃ is evaluated through the photodegradation of MG dye. For the synthesis of this oxide, a novel and effective method was used: polymer-decomposition. The synthesized powders contain an orthorhombic phase, with a range of absorbances from 300 to 500 nm and a band gap energy of 2.4 eV. It is also highlighted that, when using this synthesis method, some of the main diffraction lines related to the orthorhombic phase appear at 100 °C. Regarding its photocatalytic activity, it was evaluated under visible light (λ = 405 nm), reaching a photodegradation of approximately 88% in a period of 30 min. Photocurrent tests reveal a charge carrier separation (${\mathrm{e}}^{-},{\mathrm{h}}^{+}$) at a 405 nm wavelength. The main reactive oxygen species (ROS) involved in the photodegradation process were radicals, ${\mathrm{O}\mathrm{H}}^{•},$ and photo-holes (${\mathrm{h}}^{+}$). These results stand out because it is the first time that the photodegradation capability of this oxide in the visible spectrum has been evaluated. Full article

As one of the main fossil fuels globally, coal can be enriched with a variety of critical metal elements in specific geological conditions. This paper investigates the mineral compositions and concentrations of major and minor element oxides and trace elements in the No. 9 coal from the Xinyuan mine of the northern Qinshui coalfield, China, and discusses the modes of occurrence and enrichment mechanisms of critical metal elements such as Li, Ga, Th and REY. The mineral compositions of the No. 9 coal are primarily represented by clay minerals and quartz, with a small amount of calcite, siderite, anatase, etc. The major element oxides in the No. 9 coal are dominated by SiO₂ and Al₂O₃. Compared with world hard coal, the No. 9 coal of the Xinyuan mine is rich in Li (CC = 8.00) and Th, slightly enriched with Pb, Sc, Ga, Y, La, Ce, Tb, Dy, Er, Yb and Hg, and depleted in Mn, Co, Ni, Rb, Cs and Tl. The critical metal elements such as Li, Ga, Th and REY that enriched No. 9 coal mainly occur in aluminum silicates. The genetic type of the critical metal elements in the No. 9 coal from the Xinyuan mine is source rock-controlled type. The critical metal minerals and solutions from the source area were transported to the study area by the action of water. Due to the change of swamp water conditions, the critical metal elements were combined with clay minerals and enriched the coal. Full article

Dy³⁺ and Mn⁴⁺ codoped SrAl₂O₄ (SrAl₂O₄:Dy³⁺,Mn⁴⁺) phosphors were obtained by diffusing Mn⁴⁺ ions into Dy³⁺-doped SrAl₂O₄ via the constant-source diffusion technique. The influences of diffusion temperature and diffusion time on the emissions of SrAl₂O₄:Dy³⁺,Mn⁴⁺ were investigated. It was found that: (i) efficient red emission peaking at 651 nm can be readily achieved for SrAl₂O₄:Dy³⁺ by simply diffusing Mn⁴⁺ into SrAl₂O₄:Dy³⁺ at 800 °C and above; (ii) the red emission of Mn⁴⁺ becomes dominant over the characteristic emissions of Dy³⁺ when the diffusion temperature is 900 °C or higher; and (iii) the intensity of the red emission of SrAl₂O₄:Dy³⁺,Mn⁴⁺ is far more sensitive to diffusion temperature than to diffusion time. Our results have demonstrated that full-color tunable emissions can be realized for SrAl₂O₄:Dy³⁺, Mn⁴⁺ by tuning the parameters of diffusion temperature and diffusion time, which opens up a space for realizing easy color control of Dy³⁺-doped inorganic materials. Full article

Geochemical baselines are crucial to explore mineral resources and monitor environmental changes. This study presents the first Laos geochemical baseline values of 69 elements. The National-scale Geochemical Mapping Project of Lao People’s Democratic Republic conducted comprehensive stream sediment sampling across Laos, yielding 2079 samples collected at 1 sample/100 km², and 69 elements were analyzed. Based on the results of LGB value, R-mode factor analysis, and scatter plot analysis, this paper analyzes the relationship between the 69 elements and the geological background, mineralization, hypergene processes and human activities in the study area. The median values of element contents related to the average crustal values were: As, B, Br, Cs, Hf, Li, N, Pb, Sb, Zr, and SiO₂, >1.3 times; Ba, Be, Cl, Co, Cr, Cu, F, Ga, Mn, Mo, Ni, S, Sc, Sr, Ti, Tl, V, Zn, Eu, Al₂O₃, Tot.Fe₂O_3, MgO, CaO, and Na₂O, <0.7 times; and Ag, Au, Bi, Cd, Ge, Hg, I, In, Nb, P, Rb, Se, Sn, Ta, Th, U, W, Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and K₂O, 0.7–1.3 times. R-mode factor analysis based on principal component analysis and varimax rotation showed that they fall into 12 factors related to bedrock, (rare earth, ferrum-group, and major Al₂O₃ and K₂O elements; mineralization–Au, Sb, and As) and farming activities–N, Br, S, and C). This study provides basic geochemical data for many fields, including basic geology, mineral exploration, environmental protection and agricultural production in Laos. Full article

The co-occurrence of multiple mycotoxins, including aflatoxin B₁ (AFB₁), zearalenone (ZEN) and deoxynivalenol (DON), widely exists in cereal-based animal feed and food. At present, most reported mycotoxins degrading enzymes target only a certain type of mycotoxins. Therefore, it is of great significance for mining enzymes involved in the simultaneous degradation of different types of mycotoxins. In this study, a dye-decolorizing peroxidase-encoding gene BsDyP from Bacillus subtilis SCK6 was cloned and expressed in Escherichia coli BL21/pG-Tf2. The purified recombinant BsDyP was capable of oxidizing various substrates, including lignin phenolic model compounds 2,6-dimethylphenol and guaiacol, the substrate 2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid), anthraquinone dye reactive blue 19 and azo dye reactive black 5, as well as Mn²⁺. In addition, BsDyP could efficiently degrade different types of mycotoxins, including AFB₁, ZEN and DON, in presence of Mn²⁺. More important, the toxicities of their corresponding enzymatic degradation products AFB₁-diol, 15-OH-ZEN and C₁₅H₁₈O₈ were significantly lower than AFB₁, ZEN and DON. In summary, these results proved that BsDyP was a promising candidate for the simultaneous degradation of multiple mycotoxins in animal feed and food. Full article

In talc-magnesite veins in serpentinite near Muránska Dlhá Lúka (MDL), Slovakia, yellow euhedral to subhedral crystals apatite of a gem quality occur. It has a composition of hydroxylapatite with F⁻ varying between 0.29 and 0.34 apfu, Cl⁻ in range of 0.02–0.05 apfu and calculated OH⁻ content between 0.62–0.68 apfu. Moreover, [CO₃]²⁻ molecules were identified by FTIR and Raman spectroscopy. MDL apatite contains only up to 0.003 apfu As⁵⁺ and Si⁴⁺ substituting for P⁵⁺; Ca is substituted by small amount of Na, Fe²⁺, Mn²⁺ (all up to 0.006 apfu), and Rare Earth Elements (REE—in total up to 0.017 apfu). Compared to trace-element composition of similar apatites from Durango, Mexico, the REE content in MDL apatite is around ten times lower with Nd > Ce >> La, its chondrite-normalized REE pattern has almost a horizontal slope and larger negative Eu anomaly. The MDL apatite is richer in Mn, Pb and Li, but poorer in As, V, Th and U. The concentrations of Sr and Y are similar. In the optical absorption spectra, the most prominent bands are at 585–590 nm (Nd³⁺) and between 600 and 800 nm (Mn²⁺, Ce³⁺-SiO³⁻ photochromic center and Nd³⁺). The photoluminescence spectrum of MDL apatite shows bands between 550 and 620 nm (Dy³⁺, Sm³⁺, Pr³⁺ and also Mn²⁺) which likely enhance its yellow color. MDL hydroxylapatite likely formed from fluids derived from granitic rocks as evidenced by the chondrite-normalized REE patterns, Li, Mn and Y concentrations. The Sr content reflects the host-rock serpentinite composition. Fluids for its crystallization were likely derived from Muráň complex orthogneisses by the Alpine deformation and recrystallization in greenschist to lower amphibolite facies. Full article

Environmental stress, reactive oxygen species (ROS), or ionizing radiation (IR) can induce adverse effects in organisms and their cells, including mutations and premature aging. DNA damage and its faulty repair can lead to cell death or promote cancer through the accumulation of mutations. Misrepair in germ cells is particularly dangerous as it may lead to alterations in developmental programs and genetic disease in the offspring. DNA damage pathways and radical defense mechanisms mediate resistance to genotoxic stresses. Here, we investigated, in the fission yeast Schizosaccharomyces pombe, the role of the H₂O₂-detoxifying enzyme cytosolic catalase T (Ctt1) and the Fe²⁺/Mn²⁺ symporter Pcl1 in protecting meiotic chromosome dynamics and gamete formation from radicals generated by ROS and IR. We found that wild-type and pcl1-deficient cells respond similarly to X ray doses of up to 300 Gy, while ctt1∆ meiocytes showed a moderate sensitivity to IR but a hypersensitivity to hydrogen peroxide with cells dying at >0.4 mM H₂O₂. Meiocytes deficient for pcl1, on the other hand, showed a resistance to hydrogen peroxide similar to that of the wild type, surviving doses >40 mM. In all, it appears that in the absence of the main H₂O₂-detoxifying pathway S. pombe meiocytes are able to survive significant doses of IR-induced radicals. Full article

This work shows the influence of admixture on the basic properties of the multicomponent PbZr_1−xTi_xO₃ (PZT)-type ceramics. It presents the results of four compositions of PZT-type material with the general chemical formula, Pb_0.99M_0.01((Zr_0.49Ti_0.51)_0.95Mn_0.021Sb_0.016W_0.013)_0.9975O₃, where, in the M position, a donor admixture was introduced, i.e., samarium (Sm³⁺), gadolinium (Gd³⁺), dysprosium (Dy³⁺) or lanthanum (La³⁺). The compositions of the PZT-type ceramics were obtained through the classic ceramic method, as a result of the synthesis of simple oxides. The X-ray diffraction (XRD) pattern studies showed that the obtained multicomponent PZT materials have a tetragonal structure with a P4mm point group. The microstructure of the obtained compositions is characterized by a well crystallized grain, with clearly visible grain boundaries. The composition with the admixture of lanthanum has the highest uniformity of fine grain microstructure, which positively affects its final dielectric and piezoelectric properties. In the multicomponent PZT-type ceramic, materials utilize the mixed (acceptor and donor) doping of the main compound. This dopiong method has a positive effect on the set of the electrophysical parameters of ceramic materials. Donor dopants W⁶⁺ (at positions B) and M³⁺ = Sm³⁺, Gd³⁺, Dy³⁺, and La³⁺ (at positions A) increase the dielectric and piezoelectric properties, while the acceptor dopant Sb³⁺ (at positions B) increases the time and temperature stability of the electrophysical parameters. In addition, the suitable selection of the set of admixtures improved the sinterability of the ceramic samples, as well as resulted in obtaining the required material with good piezoelectric parameters for the poling process. This research confirms that all ceramic compositions have a set of parameters suitable for applications in micromechatronics, for example, as actuators, piezoelectric transducers, and precision microswitches. Full article

Alkene cleavage is a possibility to generate aldehydes with olfactory properties for the fragrance and flavor industry. A dye-decolorizing peroxidase (DyP) of the basidiomycete Pleurotus sapidus (PsaPOX) cleaved the aryl alkene trans-anethole. The PsaPOX was semi-purified from the mycelium via FPLC, and the corresponding gene was identified. The amino acid sequence as well as the predicted tertiary structure showed typical characteristics of DyPs as well as a non-canonical Mn²⁺-oxidation site on its surface. The gene was expressed in Komagataella pfaffii GS115 yielding activities up to 142 U/L using 2,2′-azino-bis(3-ethylbenzthiazoline-6-sulphonic acid) as substrate. PsaPOX exhibited optima at pH 3.5 and 40 °C and showed highest peroxidase activity in the presence of 100 µM H₂O₂ and 25 mM Mn²⁺. PsaPOX lacked the typical activity of DyPs towards anthraquinone dyes, but oxidized Mn²⁺ to Mn³⁺. In addition, bleaching of β-carotene and annatto was observed. Biotransformation experiments verified the alkene cleavage activity towards the aryl alkenes (E)-methyl isoeugenol, α-methylstyrene, and trans-anethole, which was increased almost twofold in the presence of Mn²⁺. The resultant aldehydes are olfactants used in the fragrance and flavor industry. PsaPOX is the first described DyP with alkene cleavage activity towards aryl alkenes and showed potential as biocatalyst for flavor production. Full article