Search Results (88)

With the rise of carbon capture and storage, liquefied carbon dioxide (LCO₂) has emerged as a promising medium for large-scale marine transport. This study evaluates the structural integrity of an IMO Type C cargo tank for a medium-range LCO₂ carrier under four conditions: ultimate limit state, accidental limit state, hydrostatic pressure test, and fatigue limit state, based on IGC Code and classification rules. Seventeen load cases were analyzed using finite element methods with multi-step loading to ensure stability. The highest stress occurred at the pump dome–shell junction due to geometric discontinuities, but all stress and buckling criteria were satisfied. The fatigue damage from wave-induced loads was negligible, with low-cycle fatigue from loading/unloading operations governing the fatigue life, which exceeded 31,000 years. The findings confirm the tank’s structural robustness and its suitability for safe, efficient medium-pressure LCO₂ transport. Full article

Clouds modulate the net radiative flux that interacts with both shortwave (SW) and longwave (LW) radiation, but the uncertainties regarding their effect in polar regions are especially high because ground observations are lacking and evaluation through satellites is made difficult by high surface reflectance. In this work, sky conditions for six different polar stations, two in the Arctic (Ny-Ålesund and Utqiagvik [formerly Barrow]) and four in Antarctica (Neumayer, Syowa, South Pole, and Dome C) will be presented, considering the decade between 2010 and 2020. Measurements of broadband SW and LW radiation components (both downwelling and upwelling) are collected within the frame of the Baseline Surface Radiation Network (BSRN). Sky conditions—categorized as clear sky, cloudy, or overcast—were determined using cloud fraction estimates obtained through the RADFLUX method, which integrates shortwave (SW) and longwave (LW) radiative fluxes. RADFLUX was applied with daily fitting for all BSRN stations, producing two cloud fraction values: one derived from shortwave downward (SWD) measurements and the other from longwave downward (LWD) measurements. The variation in cloud fraction used to classify conditions from clear sky to overcast appeared consistent and reasonable when compared to seasonal changes in shortwave downward (SWD) and diffuse radiation (DIF), as well as longwave downward (LWD) and longwave upward (LWU) fluxes. These classifications served as labels for a machine learning-based classification task. Three algorithms were evaluated: Random Forest, K-Nearest Neighbors (KNN), and XGBoost. Input features include downward LW radiation, solar zenith angle, surface air temperature ($T_a$), relative humidity, and the ratio of water vapor pressure to $T_a$. Among these models, XGBoost achieved the highest balanced accuracy, with the best scores of 0.78 at Ny-Ålesund (Arctic) and 0.78 at Syowa (Antarctica). The evaluation employed a leave-one-year-out approach to ensure robust temporal validation. Finally, the results from cross-station models highlighted the need for deeper investigation, particularly through clustering stations with similar environmental and climatic characteristics to improve generalization and transferability across locations. Additionally, the use of feature normalization strategies proved effective in reducing inter-station variability and promoting more stable model performance across diverse settings. Full article

Tropical peatlands store approximately 105 gigatons of carbon (GtC), serving as vital long-term carbon sinks, yet remain critically underrepresented in climate policy. Indonesia peatlands contain 57GtC—the largest tropical peatland carbon stock in the Asia–Pacific. However, decades of drainage, fires, and lax enforcement practices have degraded vast peatland areas, turning them from carbon sinks into emission sources—as evidenced by the 1997 and 2015 peatland fires which emitted 2.57 Gt CO₂eq and 1.75 Gt CO₂eq, respectively. Using system theory validated against historical data (1997–2023), we develop a causal loop model revealing three interconnected feedback loops driving irreversible collapse: (1) drainage–desiccation–oxidation, where water table below −40 cm triggers peat oxidation (2–5 cm subsistence) and fires; (2) fire–climate–permafrost, wherein emissions intensify radiative forcing, destabilizing monsoons and accelerating Arctic permafrost thaw (+15% since 2000); and (2) economy–governance failure, perpetuated by palm oil’s economic dominance and slack regulatory oversight. To break these vicious cycles, we propose a precautionary framework featuring IoT-enforced water table (≤40 cm), reducing emissions by 34%, legally protected “Global Climate Stabilization Zones” for peat domes (>3 m depth), safeguarding 57 GtC, and ASEAN transboundary enforcement funded by a 1–3% palm oil levy. Without intervention, annual emissions may reach 2.869 GtCO₂e by 2030 (Nationally Determined Contribution’s business-as-usual scenario). Conversely, rewetting 590 km²/year aligns with Indonesia’s FOLU Net Sink 2030 target (−140 Mt CO₂e) and mitigates 1.4–1.6 MtCO₂ annually. We conclude that integrating peatlands as irreplaceable climate infrastructure into global policy is essential for achieving Paris Agreement goals and SDGs 13–15. Full article

The Sierra de las Navajas is a Late Pliocene volcanic complex with a rhyolitic composition and peralkaline affinity. It is located on the northeastern edge of the Trans-Mexican Volcanic Belt in the state of Hidalgo. Within this rocky massif lies Cerro de las Navajas, the site of the most intensively exploited archaeological obsidian deposit in Mesoamerica. Obsidian extraction in this area has been carried out through open-pit mining and unique underground mining. The geological identity of the deposit encompasses the origin, distribution, and petrological characteristics of the obsidian from Cerro de las Navajas, determined through detailed geological mapping, petrographic study, and geochemical analysis. The results reveal the obsidian deposit’s style as well as its temporal and spatial position within the eruptive evolution of the region. The deposit originated from a local explosive eruptive mechanism associated with the partial collapse of a lava dome, forming a Block and Ash Flow Deposit (BAFD). The obsidian blocks, exploited by different cultures, correspond to the pyroclastic blocks within this deposit, which can reach up to 1 m in diameter and are embedded in a weakly consolidated ash matrix. The BAFD was later buried by (a) subsequent volcanic events, (b) structural adjustments of the volcanic edifice, and (c) soils derived from the erosion of other volcanic units. This obsidian deposit was mined underground from the Early Formative period to the Colonial era by the cultures of the Central Highlands and colonized societies. Interest in the vitreous quality and exotic nature of obsidian lithics from the BAFD led to the development of a complex exploitation system, which was generationally refined by the Teotihuacan, Toltec, and Aztec states. Full article

Ginger (Zingiber officinale), a globally grown and economically valuable plant, has inadequate research on germplasm cryopreservation, and droplet-vitrification is yet to be applied. The present study established an efficient droplet-vitrification protocol for Z. officinale ‘Yunnan Xiaohuangjiang’. The droplet-vitrification procedure was as follows: excise 1.5–2.0 mm shoot tips with 3–4 leaf primordia from five-week-old cultures, preculture on MS medium with 0.25 M sucrose for 1 d, treat with MS liquid medium with 2 M glycerol and 0.4 M sucrose for 20 min, dehydrate with PVS2 plus 0.1 M ascorbic acid at 0 °C for 20 min, plunge into LN for 1 h, thaw in MS liquid medium with 1.2 M sucrose for 20 min, post-culture on shoot recovery medium (MS with 0.1 g/L GA₃) in the dark for 3 d. Histological and ultrastructural analyses revealed that PVS + ascorbic acid-treated shoot tips exhibited numerous living cells with small vacuoles in the apical dome, leaf primordia, and basal parts. Genetic stability results showed that the plantlets regenerated from cryopreserved shoot tips had no genetic variation. This is the first report on ginger cryopreservation via droplet-vitrification, providing technical support for ginger germplasm cryopreservation and virus elimination cryotherapy in ginger. Full article

Clinostomum is a genus of parasitic trematodes found worldwide, infecting a wide range of hosts, including freshwater fishes, snails, birds and occasionally humans. In this study, clinostomid metacercariae were collected from Nile tilapia raised in fish farms in the Upper Tana River region, Kenya. The prevalence of infection was 17.2%, with metacercariae infecting the skin, gills and buccal cavity of the fish. Using light microscopy, scanning electron microscopy (SEM) and molecular methods targeting both nuclear ribosomal (ITS1, 5.8S, ITS2) and mitochondrial (COI) regions, the metacercariae were identified as C. cutaneum, C. phalacrocoracis, C. tilapiae and Euclinostomum heterostomum. The three species of Clinostomum have previously been reported to infect fish or piscivorous birds in Kenya, while this is the first report of E. heterostomum in this country. SEM analysis revealed new ultrastructural features of C. cutaneum, including an excretory pore surrounded by minute spiny papillae, an everted cirrus and dome-shaped papillae on the tegumental area around the genital pore. The cirrus lacked basal papillae, showing morphological variation between the adult and metacercarial stages. Our study, therefore, provides new insights into the phenotypic identification of flukes that may be pathogenic to fishes and humans and, therefore, of scientific and practical importance. Full article

In Antarctica, SAR interferometry has largely been used in coastal glacial areas, while in rare cases this method has been used on the Antarctic plateau. In this paper, the authors present a digital elevation and ice flow map based on SAR interferometry for an area encompassing Talos Dome (TD) and the Frontier Mountain (FM) meteorite site in North Victoria Land/Antarctica. A digital elevation model (DEM) was calculated using a double SAR interferometry method. The DEM of the region was calculated by extracting approximately 100 control points from the Reference Elevation Model of Antarctica (REMA). The two DEMs differ slightly in some areas, probably due to the penetration of the SAR-C band signal into the cold firn. The largest differences are found in the western area of TD, where the radar penetration is more pronounced and fits well with the layer structures calculated by the georadar and the snow accumulation observations. By differentiating a 70-day interferogram with the calculated DEM, a displacement interferogram was calculated that represents the ice dynamics. The resulting ice flow pattern clearly shows the catchment areas of the Priestley and Rennick Glaciers as well as the ice flow from the west towards Wilkes Basin. The ice velocity field was analysed in the area of FM. This area has become well known due to the search for meteorites. The velocity field in combination with the calculated DEM confirms the generally accepted theories about the accumulation of meteorites over the Antarctic Plateau. Full article

Background/Objectives: To report the cosmetic, clinical, and visual outcomes of a combined surgical approach for treating a corneal/limbal dermoid using excision and a three-layered amniotic membrane graft with fibrin glue. Methods: An 18-year-old female presented with impaired vision and ocular discomfort caused by a prominent dome-shaped limbal congenital dermoid on the inferotemporal cornea, resulting in a significant aesthetic concern. A full assessment, including refraction, best-corrected visual acuity (BCVA), corneal topography, aberrometry and anterior segment OCT (AS-OCT) was conducted to plan the surgical approach. The dermoid was excised under peribulbar anaesthesia using manual lamellar dissection, followed by the application of 0.02% Mitomycin C and a multilayered amniotic membrane graft with fibrin glue. A bandage contact lens was applied and removed after three weeks, with postoperative treatment including topical antibiotics and steroids. Follow-ups were conducted on day 1, at 1 week, 3 weeks, 2 months, 6 months, 1 year, and 2 years. Results: Histopathological examination confirmed the mesoblastic nature of the lesion. Significant improvements in BCVA and ocular symptoms were observed. Corneal topography showed ocular surface regularization with reduction of high order aberrations and point spread function. AS-OCT showed complete integration of the amniotic membrane, with full epithelial coverage of the defect. The healing process was uneventful and the ocular surface remained stable throughout the entire follow-up, without complications or recurrence. Conclusions: This approach of dermoid excision, multilayered amniotic membrane and fibrin glue restored vision effectively, with notable improvements in ocular surface and cosmetic outcomes, without recurrence over two years. Full article

Bulk n-type SrTiO₃ (STO) has long been known to possess a superconducting ground state at an exceptionally dilute carrier density. This has raised questions about the applicability of the BCS-Eliashberg paradigm with its underlying adiabatic assumption. However, recent experimental reports have set the pairing gap to the critical temperature ($T_c$) ratio at the BCS value for superconductivity in Nb-doped STO, even though the adiabaticity condition the BCS pairing requires is satisfied over the entire superconducting dome only by the lowest branch of optical phonons. In spite of the strong implications these reports have on specifying the pairing glue, they have not proved sufficient in explaining the magnitude of the optimal doping. This motivated us to apply density functional theory to Nb-doped STO to analyze how the phonon band structures and the electron–phonon coupling evolve with doping. To describe the very low doping concentration, we tuned the homogeneous background charge, from which we obtained a first-principles result on the doping-dependent phonon frequency that is in good agreement with experimental data for Nb-doped STO. Using the EPW code, we obtain the doping-dependent phonon dispersion and the electron–phonon coupling strength. Within the framework of our calculation, we found that the electron–phonon coupling forms a dome in a doping range lower than the experimentally observed superconducting dome of the Nb-doped STO. Additionally, we examined the doping dependence of both the orbital angular momentum quenching in the electron–phonon coupling and the phonon displacement correlation length and found the former to have a strong correlation with our electron–phonon coupling in the overdoped region. Full article

Moderate-Resolution Imaging Spectroradiometer (MODIS) sensors onboard the Terra and Aqua spacecraft have been in orbit for over 24 and 22 years, respectively, providing continuous observations of the Earth’s surface. Among the instrument’s 36 bands, 16 of them are thermal emissive bands (TEBs) with wavelengths that range from 3.75 to 14.24 μm. Routine post-launch calibrations are performed using the sensor’s onboard blackbody and space view port, the moon, and vicarious targets that include the ocean, Dome Concordia (Dome C) in Antarctica, and quasi-deep convective clouds (DCC). The calibration consistency between the satellite measurements from the two instruments is essential in generating a multi-year data record for the long-term monitoring of the Earth’s Level 1B (L1B) data. This paper presents the Terra and Aqua MODIS TEB comparison for the upcoming Collection 7 (C7) L1B products using measurements over Dome C and the ocean, as well as the double difference via simultaneous nadir overpasses with the Infrared Atmospheric Sounding Interferometer (IASI) sensor. The mission-long trending of the Terra and Aqua MODIS TEB is presented, and their cross-comparison is also presented and discussed. Results show that the calibration of the two MODIS sensors and their respective Earth measurements are generally consistent and within their design specifications. Due to the electronic crosstalk contamination, the PV LWIR bands show slightly larger drifts for both MODIS instruments across different Earth measurements. These drifts also have an impact on the Terra-to-Aqua calibration consistency. This thorough assessment serves as a robust record containing a summary of the MODIS calibration performance and the consistency between the two MODIS sensors over Earth view retrievals. Full article

The heterobimetallic 15-MC-5 metallacrown of formula [CeCu₅(5mpzHA)₅(NO₃)(H₂O)₇]·2NO₃·7H₂O, designated MC-Ce, was synthesized using 5-methyl-2-pyrazinehydroxamic acid (5mpzHA) as a linker, reacting with Ce^III and Cu^II salts under mild conditions. Single-crystal X-ray diffraction analysis reveals a crown-like [Cu₅Ce(5mpzHA)₅] core, characteristic of a 15-MC-5 system, with five Cu^II atoms at the rim of the crown and the Ce^III ion occupying the dome of the crown, with water molecules, oxygen atoms and one nitrate anion filling the nine-coordination sphere around the Ce^III ion, which exhibits a distorted spherical tricapped trigonal prism geometry. The thermogravimetric analysis evidences successive mass losses due to the removal of water molecules and decomposition of the structure after 217 °C, whereas the PXRD analysis of the thermal decomposition residue reveals the presence of copper and copper/cerium oxide particles. These nanocomposite materials were also synthesized using the metallacrown MC-Ce under a hydrothermal method in the presence of multi-walled carbon nanotubes (MWCNTs), affording insights that this metallacrown can act as a source precursor for the synthesis of these mixed cerium/copper oxide nanomaterials. The experimental χMT value in MC-Ce at room temperature is 3.175 cm³ mol⁻¹ K, which is higher than the calculated one for one magnetically isolated Ce^III plus five Cu^II ions, probably due to the antiferromagnetic interactions among Cu^II ions within the metallacrown hoop plus the thermal depopulation of JZ sublevels of Ce^III ground state (5/2), which exhibit a small splitting under the anisotropic ligand field effects. The χMT decreases continuously until it reaches the value of 0.80 cm³ mol⁻¹ K at 10 K, reinforcing the presence of intramolecular antiferromagnetic interactions. Full article

This research paper explores biogas production in an underground temperature-controlled fixed dome digester and compares it with a similar uncontrolled digester. Two underground fixed-dome digesters, one fitted with a solar heating system and a stirrer and the other one with an identical stirrer only, were batch-fed with cow dung slurry collected from the University of Fort Hare farm and mixed with water in a ratio of 1:1. The solar heating system consisted of a solar geyser, pex-al-pex tubing, an electric ball valve, a water circulation pump, an Arduino aided temperature control system, and a heat exchanger located at the centre of the digester. Both the digesters were intermittently stirred for 10 min every 4 h. The digester without a heating system was used as a control. Biogas production in the two digesters was compared to assess the effect of solar heating on biogas production. The total solids, volatile solids, and the chemical oxygen demand of the cow dung used as substrate were determined before and after digestion. These were compared together with the cumulative biogas produced and the methane content for the controlled and uncontrolled digesters. It was observed that the temperature control system kept the slurry temperature in the controlled digester within the required range for 82.76% of the retention period, showing an efficiency of 82.76%. Some maximum temperature gradients of 7.0 °C were observed in both the controlled and uncontrolled digesters, showing that the stirrer speed of 30 rpm was not fast enough to create the needed vortex for a uniform mix in the slurry. It was further observed that the heat from the solar geyser and the ground insulation were sufficient to keep the digester temperature within the required temperature range without any additional heat source even at night. Biogas yield was observed to depend on the pH with a strong coefficient of determination of 0.788 and 0.755 for the controlled and uncontrolled digesters, respectively. The cumulative biogas was 26.77 m³ and 18.05 m³ for controlled and uncontrolled digesters, respectively, which was an increase of 33%. The methane content increased by 14% while carbon dioxide decreased by 10% from the uncontrolled to the controlled scenario. The percentage removal of the TS, VS, and COD was 66.26%, 76.81%, and 74.69%, respectively, compared to 47.01%, 60.37%, and 57.86% for the uncontrolled situation. Thus, the percentage removal of TS, VS, and COD increased by 19.25%, 16.44%, and 16.89%, respectively. Full article

Grass carp (Ctenopharyngodon idella) is a Cyprinid fish of aquacultural and research importance. The buccal cavity represents the gateway of the digestive tract. The present study investigated the adaptational changes involving various components of the buccal cavity of fingerling (three months posthatching, mph), yearling (12 mph), and adult (48 mph) C. idella using scanning electron microscopy, histology, and morphometry. The upper and lower lips appeared uninterrupted at the three studied stages and were limited caudally by the upper and lower jaws. The jaw epithelium was the thickest part of the buccal epithelium; ultrastructurally, it appeared smooth with ridge-like borders in fingerlings that transformed into microgrooves in yearlings. In adult C. idella, the jaw mucosa was organized into dome-shaped masses separated from each other by tight furrows. Each mass was formed from several keratinocytes with corrugated surfaces that featured numerous microdepressions. Except for the jaws, taste buds, mainly of type I, and acidic and neutral goblet cells were observed throughout the mucosa of the buccal cavity, and their densities were highest along the mucosal folds of the palate and oral floor, suggesting a principal role for these parts in both gustation and food lubrication. This study is the first to report age-associated spatiotemporal changes in the buccal cavity of grass carp and will serve as a fundamental reference during the interpretation of various types of oral pathologies in teleost. Full article

People with schizophrenia have died at disproportionately higher rates during recent extreme heat events (EHEs) in Canada, including the deadly 2021 Heat Dome in British Columbia (B.C.). However, to date, little research has qualitatively focused on how people with schizophrenia experience and respond to EHEs. This study aimed to (i) explore how people with schizophrenia experienced and were impacted by the 2021 Heat Dome physically, cognitively, and emotionally and (ii) understand their level of awareness and health-protective actions taken in response to the EHE. Between October 2023 and February 2024, interviews were conducted with 35 people with schizophrenia who experienced the 2021 Heat Dome in a community setting within B.C., Canada. The semi-structured interviews were guided by pre-defined questions to explore the participant’s background, living situation, social network, awareness and access to heat-mitigation measures. The transcripts were analyzed using a descriptive form of thematic analysis. Participants shared critical insights on how the EHE impacted them, including descriptions of mild to severe physical manifestations of heat stress (e.g., fainting, heat rashes), the triggering of schizophrenia-related symptoms (e.g., paranoia, hallucinations), and the detrimental effects on their energy levels and emotional stability, which further caused disruptions to their everyday life. Participants also illustrated gaps in knowledge and challenges experienced with accessing information, which hindered their ability to manage the heat exposure effectively and, for some, resulted in no actions (or counter-intuitive actions) being taken to mitigate the heat. These findings demonstrate the complex ways that individuals with schizophrenia experienced and responded to the 2021 Heat Dome and revealed various situational and contextual factors that further compounded the challenge of heat mitigation. These findings can support the development of tailored individual and community-level heat response and communication initiatives and strategies for people with schizophrenia. Full article

The VIIRS instrument on the JPSS-2 (renamed NOAA-21 upon reaching orbit) spacecraft was launched in November 2022, making it the third sensor in the VIIRS series, following those onboard the SNPP and NOAA-20 spacecrafts, which are operating nominally. As a multi-disciplinary instrument, the VIIRS provides the worldwide user community with high-quality imagery and radiometric measurements of the land, atmosphere, cryosphere, and oceans. This study provides an early assessment of the calibration stability and radiometric consistency of the NOAA-21 VIIRS RSBs using the latest NASA SIPS C2 L1B products. Vicarious approaches are employed, relying on reflectance data obtained from the Libya-4 desert and Dome C sites, deep convective clouds, and simultaneous nadir overpasses, as well as intercomparison with the first two VIIRS instruments using MODIS as a transfer radiometer. The impact of existing band spectral differences on sensor-to-sensor comparison is corrected using scene-specific a priori hyperspectral observations from the SCIAMACHY sensor onboard the ENVISAT platform. The results indicate that the overall radiometric performance of the newly launched NOAA-21 VIIRS is quantitatively comparable to the NOAA-20 for the VIS and NIR bands. For some SWIR bands, the measured reflectances are lower by more than 2%. An upward adjustment of 6.1% in the gain of band M11 (2.25 µm), based on lunar intercomparison results, generates more consistent results with the NOAA-20 VIIRS. Full article