Search Results (39)

Developing advanced antimicrobial agents is critically imperative to address antibiotic-resistant infection crises. MXenes have emerged as a potential nanomedicine for antibacterial applications, but they suffer from suboptimal photothermal conversion efficiency and inherent cytotoxicity. Herein, we report the synthesis of MXene (Ti₃C₂)-based nanohybrids and hybrid membranes through firstly interfacial conjugation of self-assembled β-lactoglobulin nanofibers (β-LGNFs)-inspired copper sulfide nanoparticles (CuS NPs) onto MXene nanosheets, and subsequent vacuum filtration of the created β-LGNF-CuS/MXene nanohybrids. The constructed β-LGNF-CuS/MXene nanohybrids exhibit excellent photothermal conversion performances and satisfactory biocompatibility and minimal cytotoxicity toward mammalian cells, ascribing to the introduction of highly biocompatible β-LGNFs into the hybrid system. In addition, the fabricated β-LGNF-CuS/MXene hybrid membranes demonstrate high efficiency in antibacterial application through the synergistic photothermal and material-related antibacterial effects of both MXene and CuS NPs. Therefore, the ideas and findings shown in this study are useful for inspiring researchers to design and fabricate functional and biocompatible 2D material-based hybrid membranes for antimicrobial applications. Full article

Highly efficient photocatalysts for solar energy conversion require effective charge carrier separation and rapid interfacial transport kinetics to maximize electron availability. Two-dimensional Ti₃CNT_x, a novel conductive material in the MXene family with exceptional electrical conductivity, has emerged as an ideal electron transfer mediator due to its large specific surface area and abundant active terminal groups. In this work, we strategically integrated the 2D multi-metal sulfide Cu-Zn-In-S (CZIS) with 2D Ti₃CNT_x nanosheets through physical mixture, constructing a heterostructured 2D/2D CZIS/Ti₃CNT_x composite photocatalyst for the hydrogen evolution reaction. The unique architecture significantly accelerates electron migration from CZIS to Ti₃CNT_x, while synergistically promoting the spatial separation and directional transfer of photogenerated electron–hole pairs (e⁻/h⁺). When the hydrogen evolution reaction is carried out under identical conditions, the hydrogen yield rate is 4.3 mmol g⁻¹ h⁻¹ with pristine CZIS but is improved dramatically to 14.3 mmol g⁻¹ h⁻¹ when the composite containing an adequate amount of 2D Ti₃CNT_x is used. This study offers new insight into the rational design and controllable synthesis of Ti₃CNT_x-based composite photocatalytic systems for efficient photocatalytic hydrogen production. Full article

Electrochemical glucose sensors are vital for clinical diagnostics and the food industry, where accurate detection is essential. However, the limitations of glucose oxidase (GOx)-based sensors, such as complex preparation, high cost, and environmental sensitivity, highlight the need for non-enzymatic sensors that directly oxidize glucose at the electrode surface. In this study, a self-supporting hierarchical Cu/Fe₃O₄ nanosheet electrode was successfully fabricated by in situ growth on Ni Foam using a hydrothermal method, followed by annealing treatment. The Cu/Fe₃O₄ hierarchical nanosheet structure, with its large surface area, provides abundant active sites for electrocatalysis, while the strong interactions between Cu/Fe₃O₄ and Ni Foam enhance electron transfer efficiency. This novel electrode structure demonstrates exceptional electrochemical performance for non-enzymatic glucose sensing, with an ultrahigh sensitivity of 12.85 μA·μM⁻¹·cm⁻², a low detection limit of 0.71 μM, and a linear range extending up to 1 mM. Moreover, the Cu/Fe₃O₄/NF electrode exhibits excellent stability, a rapid response (~3 s), and good selectivity against interfering substances such as uric acid, ascorbic acid, H₂O₂, urea, and KCl. It also shows strong reliability in analyzing human serum samples. Therefore, Cu/Fe₃O₄/NF holds great promise as a non-enzymatic glucose sensor, and this work offers a valuable strategy for the design of advanced electrochemical electrodes. Full article

In this study, MoS₂ nanosheets have been prepared and treated ultrasonically with silver ammonia solutions. The MoS₂/Ag precursor was reduced using dopamine (DA) as reducing and linking agent at room temperature, and it was subjected to a hydrothermal treatment to produce MoS₂/Ag nanocomposites (denoted as MoAg). The MoAg samples were functionalized with N-oleoylethanolamine to improve dispersion in the base oil component of additives. Use of the functionalized MoAg (denoted as Fc-MoAg) as a lubricant additive for steel balls resulted in effective friction reduction and anti-wear. This work avoids ion exchange during exfoliation, and the Ag⁺ has been reduced to nano-silver particles by dopamine to enlarge the layer spaces of MoS₂. Taking the case of lubrication with base oil containing Fc-Mo_0.6Ag₁₅, the wear scar diameters and coefficients of friction of the steel balls were 0.428 and 0.098 mm, respectively, which were about three-fifths base oil. In addition, MoS₂/Cu and MoS₂/Ni nanocomposites were synthesized and the tribological properties associated with steel/steel balls assessed. The results demonstrate that all MoS₂/metal composites exhibit enhanced tribological behavior in the steel/steel pair tests. Both nanocomposite synergy and the tribofilm containing sulfide, oxide, carbide, and other compounds play important roles in achieving reduced friction and improved anti-wear. The friction and wear properties of base oil containing Fc-MoAg and commercial additives were evaluated using a four-ball wear tester with steel/steel, steel/zirconia and zirconia/zirconia pairs. The base oil containing Fc-MoAg delivered smaller coefficients of friction (COFs) and/or scarring groove depths than those observed with the use of pure base oil and base oil containing commercial additives. Full article

In recent years, the electrocatalytic reduction of nitrate to ammonia (NRA) has garnered significant research attention. However, the complex multi-step proton–electron transfer process often results in various by-products, limiting NH₃ production. Therefore, designing and developing highly active and selective electrocatalysts for efficient NRA is crucial. This study proposes a method to construct Cu/Cu₂O nanosheet arrays with heterogeneous interfaces and oxygen vacancies on copper foam surfaces through electrochemical reduction. The interface coupling between Cu and Cu₂O significantly optimizes the catalyst’s surface electronic structure, providing sufficient active sites. In addition, the presence of oxygen vacancies in Cu/Cu₂O can optimize the adsorption kinetics of intermediates in the NRA process and effectively inhibit the formation of by-products. The results show that Cu/CuO₂ nanosheet arrays are superior NRA catalysts, achieving a Faradaic efficiency of up to 91.1%, a nitrate conversion of 96.25%, and an NH₃ yield rate of 6.11 mg h⁻¹ cm⁻². Full article

In the realm of electrochemical nitrite detection, the potent oxidizing nature of nitrite typically necessitates operation at high detection potentials. However, this study introduces a novel approach to address this challenge by developing a highly sensitive electrochemical sensor with a low reduction detection potential. Specifically, a copper metal nanosheet/carbon paper sensitive electrode (Cu/CP) was fabricated using a one-step electrodeposition method, leveraging the catalytic reduction properties of copper’s high occupancy d-orbital. The Cu/CP sensor exhibited remarkable performance in nitrite detection, featuring a low detection potential of −0.05 V vs. Hg/HgO, a wide linear range of 10~1000 μM, an impressive detection limit of 0.079 μM (S/N = 3), and a high sensitivity of 2140 μA mM⁻¹cm⁻². These findings underscore the efficacy of electrochemical nitrite detection through catalytic reduction as a means to reduce the operational voltage of the sensor. By showcasing the successful implementation of this strategy, this work sets a valuable precedent for the advancement of electrochemical low-potential nitrite detection methodologies. Full article

In this study, an electrode slurry composed of molybdenum disulfide (MoS₂) and vapor-grown carbon fiber (VGCF) prepared through a solid-phase synthesis method was blade-coated onto copper foil to form a thick film as the anode for lithium-ion batteries. In previously reported work, MoS₂-based lithium-ion batteries have experienced gradual deformation, fracture, and pulverization of electrode materials during the charge and discharge cycling process. This leads to an unstable electrode structure and rapid decline in battery capacity. Furthermore, MoS₂ nanosheets tend to aggregate over charge and discharge cycles, which diminishes the surface activity of the material and results in poor electrochemical performance. In this study, we altered the density of the MoS₂–carbon fiber/Cu foil anode electrode by rolling. Three different densities of electrode sheets were obtained through varying rolling repetitions. Our study shows the best electrochemical performance was achieved at a material density of 2.2 g/cm³, maintaining a capacity of 427 mAh/g even after 80 cycles. Full article

Although 2D MoS₂ alone shows excellent gas-sensing performance, it is prone to stacking when used as the sensitive layer, resulting in insufficient contact with the target gas and lower sensitivity. To solve this, a 2D-MoS₂/1D-CuPc heterojunction was prepared with different weight ratios of MoS₂ nanosheets to CuPc micro-nanowires, and its room-temperature gas-sensing properties were studied. The response of the 2D-MoS₂/1D-CuPc heterojunction to a target gas was related to the weight ratio of MoS₂ to CuPc. When the weight ratio of MoS₂ to CuPc was 20:7 (7-CM), the gas sensitivity of MoS₂/CuPc composites was the best. Compared with the pure MoS₂ sensor, the responses of 7-CM to 1000 ppm formaldehyde (CH₂O), acetone (C₃H₆O), ethanol (C₂H₆O), and 98% RH increased by 122.7, 734.6, 1639.8, and 440.5, respectively. The response of the heterojunction toward C₂H₆O was twice that of C₃H₆O and 13 times that of CH₂O. In addition, the response time of all sensors was less than 60 s, and the recovery time was less than 10 s. These results provide an experimental reference for the development of high-performance MoS₂-based gas sensors. Full article

Metal–organic frameworks (MOFs) have broad potential applications in electrochemical glucose detection. Herein, a green ultrasonic synthesis process is presented for preparing two-dimensional (2D) copper–nickel metal–organic framework nanosheets (CuNi-MOFNs) for glucose detection. The synthesized CuNi-MOFNs were characterized using scanning electron microscopy (SEM), scanning transmission electron microscope (STEM), X-ray diffractometer (XRD), and X-ray photoelectron spectrometer (XPS). The CuNi-MOFN nanocomposites were used to cover the glassy carbon electrode (GCE) and the CuNi-MOFNs-modified electrode was studied in alkaline media. Cyclic voltammetry (CV) and amperometric i–t curves indicated that the CuNi-MOFNs-modified electrode revealed great electrochemical performances towards glucose oxidation. Due to the ease of access to active metal sites in large specific surface of nanosheets, the CuNi-MOFNs-modified electrode can effectively improve the electronic transfer rate and enhance electrocatalytic activity of the CuNi-MOFNs-modified electrode. The CuNi-MOFNs-modified electrode showed electrochemical performances for glucose detection with a linear range from 0.01 mM to 4 mM, sensitivity of 702 μAmM⁻¹cm⁻², and detection limit of 3.33 μΜ (S/N = 3). The CuNi-MOFNs-modified electrode exhibited excellent anti-interference ability and high selectivity in glucose measurements. Hence, the CuNi-MOFNs-modified electrode has good, promising prospects in non-enzymatic electrochemical glucose detection. Full article

The pursuit of superhydrophilic materials with hierarchical structures has garnered significant attention across diverse application domains. In this study, we have successfully crafted Ni-Mn LDHs@CuC₂O₄ nanosheet arrays on a copper mesh (CM) through a synergistic process involving chemical oxidation and hydrothermal deposition. Initially, CuC₂O₄ nanosheets were synthesized on the copper mesh, closely followed by the growth of Ni-Mn LDHs nanosheets, culminating in the establishment of a multi-tiered surface architecture with exceptional superhydrophilicity and remarkable underwater superoleophobicity. The resultant Ni-Mn LDHs@CuC₂O₄ CM membrane showcased an unparalleled amalgamation of traits, including superhydrophilicity, underwater superoleophobicity, and the ability to harness photocatalytic forces for self-cleaning actions, making it an advanced oil-water separation membrane. The membrane’s performance was impressive, manifesting in a remarkable water flux range (70 kL·m^−2·h⁻¹) and an efficient oil separation capability for both oil/water mixture and surfactant-stabilized emulsions (below 60 ppm). Moreover, the innate superhydrophilic characteristics of the membrane rendered it a prime candidate for deployment as a supercapacitor cathode material. Evidenced by a capacitance of 5080 mF·cm⁻² at a current density of 6 mA cm⁻² in a 6 M KOH electrolyte, the membrane’s potential extended beyond oil-water separation. This work not only introduces a cutting-edge oil-water separation membrane and supercapacitor electrode but also offers a promising blueprint for the deliberate engineering of hierarchical structure arrays to cater to a spectrum of related applications. Full article

Porous C nanosheet/Cu₂S composites were prepared using a simple self-template method and vulcanization process. The Cu₂S nanoparticles with an average diameter of 140 nm are uniformly distributed on porous carbon nanosheets. When used as the anode of a potassium-ion battery, porous C nanosheet/Cu₂S composites exhibit good rate performance and cycle performance (363 mAh g⁻¹ at 0.1 A g⁻¹ after 100 cycles; 120 mAh g⁻¹ at 5 A g⁻¹ after 1000 cycles). The excellent electrochemical performance of porous C nanosheet/Cu₂S composites can be ascribed to their unique structure, which can restrain the volume change of Cu₂S during the charge/discharge processes, increase the contact area between the electrode and the electrolyte, and improve the electron/ionic conductivity of the electrode material. Full article

Two-dimensional Cu₂FeSnS₄ (CFTS) nanosheets with exposed high-energy facets (111) have been synthesized by a facile, scalable, and cost-effective one-pot heating process. The CFTS phase formation is confirmed by both X-ray diffraction and Raman spectroscopy. The formation mechanism of exposed high-energy facet CFTS growth is proposed and its electrochemical and photoelectrochemical properties are investigated in detail to reveal the origin of the anisotropic effect of the high-energy facets. Dye-sensitized solar cells (DSSC) achieve a favorable power conversion efficiency of 5.92% when employing CFTS thin film as a counter electrode, suggesting its potential as a cost-effective substitute for Pt in DSSCs. Full article

In this work, the S@g-C₃N₄ and CuS@g-C₃N₄ catalysts were prepared via the polycondensation process. The structural properties of these samples were completed on XRD, FTIR and ESEM techniques. The XRD pattern of S@g-C₃N₄ presents a sharp peak at 27.2° and a weak peak at 13.01° and the reflections of CuS belong to the hexagonal phase. The interplanar distance decreased from 0.328 to 0.319 nm that facilitate charge carrier separation and promoting H₂ generation. FTIR data revealed the structural change according to absorption bands of g-C₃N₄. ESEM images of S@g-C₃N₄ exhibited the described layered sheet structure for g-C₃N₄ materials and CuS@g-C₃N₄ demonstrated that the sheet materials were fragmented throughout the growth process. The data of BET revealed a higher surface area (55 m²/g) for the CuS-g-C₃N₄ nanosheet. The UV–vis absorption spectrum of S@g-C₃N₄ showed a strong peak at 322 nm, which weakened after the growth of CuS at g-C₃N₄. The PL emission data showed a peak at 441 nm, which correlated with electron–hole pair recombination. The data of hydrogen evolution showed improved performance for the CuS@g-C₃N₄ catalyst (5227 mL/g·min). Moreover, the activation energy was determined for S@g-C₃N₄ and CuS@g-C₃N₄, which showed a lowering from 47.33 ± 0.02 to 41.15 ± 0.02 KJ/mol. Full article

Developing an efficient multi-functional electrocatalyst with high efficiency and low cost to replace noble metals is significantly crucial for the industrial water electrolysis process and for producing sustainable green hydrogen (H₂) fuel. Herein, ultrathin CuCo₂S₄ nanosheets assembled into highly open three-dimensional (3D) nanospheres of CuCo₂S₄ (Cu/Co = 33:67) were prepared by a facile one-pot solvothermal approach and utilized as a bifunctional electrocatalyst for efficient overall water splitting. The as-prepared CuCo₂S₄ is characterized structurally and morphologically; the BET surface area of the CuCo₂S₄ (Cu/Co = 33:67) catalyst was found to have a larger specific surface area (21.783 m²g⁻¹) than that of other catalysts with a Cu/Co ratio of 67:33, 50:50, and 20:80. Benefiting from a highly open structure and ultrathin nanosheets with excellent exposure to catalytically active sites, CuCo₂S₄ (Cu/Co = 33:67) is identified as an efficient catalyst for the proton reduction and oxygen evolution reactions in 1 M KOH with an overpotential of 182 and 274 mV at 10 mA cm⁻², respectively. As expected, a low cell voltage of 1.68 V delivers a current density of 10 mA cm⁻². Stability and durability are also greatly enhanced under harsh alkaline conditions. Therefore, this work provides a simple strategy for the rational design of spinel-based transition metal sulfide catalysts for electrocatalysis. Full article

Herein, well-defined hollow CuS microspheres assembled from nanosheets were successfully synthesized through a facile solvothermal method. Hollow CuS microspheres have an average diameter of 1.5 μm; moreover, the primary CuS nanosheets have an ultrathin thickness of about 10 nm and are bound by {0001} polar facets. When used as anodes for lithium-ion batteries (LIBs), hollow CuS microspheres exhibit excellent electrochemical properties, including a large discharge capacity (610.1 mAh g⁻¹ at 0.5 C), an excellent rate capability (207.6 and 143.4 mAh g⁻¹ at 1 and 5 C), and a superior cyclic stability (196.3 mAh g⁻¹ at 1 C after 500 cycles). When used as photocatalysts for Rhodamine B (RhB), hollow CuS microspheres can degrade more than 99% of the initial RhB within 21 min. These excellent Li-ion storage properties and photocatalytical performances are attributed to their unique hierarchical hollow structure. Full article