Search Results (2,017)

This study investigates the effect of high-temperature hydrogen exposure on the structure and properties of Cr₂O₃/Al₂O₃-based detonation coatings deposited on AISI 316L stainless steel. Bilayer and gradient coatings were exposed to hydrogen at 1000 °C for 3, 4, and 5 h and subsequently characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS), surface profilometry, and thermal desorption spectroscopy (TDS). One independent specimen was examined for each combination of coating architecture and hydrogen exposure duration. Therefore, the present study was designed as an exploratory comparative investigation rather than a statistically powered study. The principal α-Al₂O₃ and Cr₂O₃ phases remained detectable after all exposure durations, indicating preservation of the main oxide phases. SEM/EDS analysis revealed microcracks, local defects, and heterogeneous surface regions, with more pronounced localized damage in the bilayer coatings. The Ra values of the bilayer coatings were 1.385, 0.833, and 1.207 μm after 3, 4, and 5 h, respectively, whereas the corresponding values for the gradient coatings were 1.049, 1.337, and 1.049 μm. The minimum Ra of 0.833 μm after 4 h in the bilayer coating coincided with SEM/EDS evidence suggesting local coating damage and possible thinning. TDS showed the most intense hydrogen desorption for the gradient coating after 3 h. Overall, the observed results suggest that coating architecture influences surface evolution and hydrogen-retention behavior under the investigated high-temperature hydrogen exposure conditions. Full article

High-speed steel (HSS) substrates were coated with layers of CrC, NbC, TiC, and VC using thermo-reactive diffusion (TRD) at 900 and 1100 °C for 2 and 4 h. The experimental design was implemented according to the Taguchi L8 orthogonal array. Coating morphology was investigated using scanning electron microscopy (SEM) combined with energy-dispersive spectroscopy (EDS), while phase composition was determined by X-ray diffraction (XRD). The contributions of coating type, temperature, and time to coating thickness, microhardness, coefficient of friction, and specific wear rate were evaluated using analysis of variance (ANOVA). SEM and EDS analyses showed that coatings produced at lower temperatures and shorter times exhibited irregular layer thickness, localized porosity, and irregular carbide formation, while coatings applied at higher temperatures and longer times were associated with smoother layers, more homogeneous element distribution, and improved surface morphology. XRD analyses confirmed that the coatings consisted of dense carbide phases and that the chemical composition of the substrate affected the resulting coating phases. Phase composition analysis revealed the presence of phases such as Cr₇C₃ and Cr₂₃C₆ in the coatings. It was observed that coating thickness and hardness generally increased with increasing temperature and coating time. Variance analysis showed that the highest additive ratios in terms of coating thickness belonged to coating type (45.13%) and temperature (42.34%), while in terms of microhardness, temperature (39.92%) and coating type (37.77%) had higher additive ratios. The highest additive ratio in terms of friction coefficient was obtained with coating type (87.98%), while temperature (34.99%) and coating type (33.37%) were determined as the parameters with the highest additive ratios in terms of specific wear rate. NbC coatings generally showed lower performance values compared to other coating types under the examined experimental conditions. Full article

Fe-Al intermetallic coatings were fabricated on 0Cr21Al6Nb stainless steel by pack cementation to systematically investigate the effects of temperature (650–800 °C) and holding time (2–16 h) on the coating microstructure, phase constitution, and hardness. The coatings primarily consisted of Fe₂Al₅, with a minor amount of FeAl₃ confined to the outermost surface. The coating/substrate interface exhibited a characteristic serrated or tongue-like morphology, which became increasingly pronounced with increasing temperature and holding time, indicating enhanced interdiffusion across the interface. Both increasing temperature and prolonging holding time markedly promoted coating growth and increased the coating thickness, while simultaneously facilitating the enrichment of FeAl₃ in the near-surface region. Despite these microstructural variations, the coating hardness remained relatively stable at approximately 960 HV, which was substantially higher than that of the substrate; meanwhile, the substrate exhibited a slight reduction in hardness after aluminizing. Thermodynamic analysis revealed that Fe₂Al₅ was preferentially formed owing to its relatively lower Gibbs free energy, and its formation remained thermodynamically favored during subsequent coating growth, whereas FeAl₃ was restricted to the coating surface. Kinetic analysis demonstrated that coating growth followed a parabolic law, indicating a diffusion-controlled growth mechanism, with an apparent activation energy of 107.5 kJ·mol⁻¹ for Al diffusion. Furthermore, temperature exerted a more pronounced influence on coating growth than holding time, highlighting temperature as the dominant kinetic parameter governing the formation and thickening of the Fe-Al intermetallic coating. Full article

Background: Idiopathic epilepsy (IE) is among the most frequent chronic neurological disorders of cats, but by definition it is associated with an unremarkable conventional brain MRI, leaving its temporal lobe pathophysiology poorly characterised. Objectives: To quantify interictal temporal lobe neurometabolite ratios in cats with IE using bilateral single-voxel ¹H-MRS and to compare them with healthy controls, and to explore relationships with seizure timing and signalment. Methods: In this prospective case–control study, 20 client-owned cats with idiopathic epilepsy and 20 healthy control cats underwent bilateral single-voxel ¹H-MRS (PRESS; TE 135 ms; 10 × 10 × 10 mm voxel centred on the mid-hippocampus and amygdala). N-acetylaspartate (NAA), total choline (tCho), and total creatine (tCr) were quantified and the NAA/tCr, NAA/tCho, tCho/tCr, and tCho/NAA ratios were compared (independent-samples t-tests; one-way ANOVA; Spearman correlation; α = 0.05). Results: Overall, no metabolite ratio differed significantly between groups across both hemispheres, and no ratio correlated with age, sex, breed, coat length, or neutering status. However, the right temporal lobe NAA/tCr ratio was significantly lower in epileptic cats (1.32 ± 0.29) than in controls (1.50 ± 0.20; p < 0.05). Seizure timing modulated the left-hemisphere spectrum: left tCho/tCr correlated negatively with the interval since the last seizure (Spearman r = −0.48; p = 0.035), and cats with ≤3 days between first and last seizures showed lower left NAA/tCho (0.89 ± 0.23 vs. 1.14 ± 0.24; p = 0.032) and higher left tCho/NAA (1.21 ± 0.40 vs. 0.91 ± 0.17; p = 0.039) than cats with a longer interval. Conclusions: Interictal ¹H-MRS detects temporal lobe metabolic disturbances, including a reduced right temporal lobe NAA/tCr ratio suggesting neuronal or metabolic dysfunction and seizure timing-dependent membrane turnover shifts, in cats with normal-appearing MRI. ¹H-MRS is therefore a promising non-invasive adjunct for characterising, monitoring, and potentially assisting in the localisation of metabolic abnormalities in feline IE and warrants validation in larger, longitudinally sampled cohorts. Full article

The surface of nodular cast iron is susceptible to wear failure under high-load conditions. In this study, Fe-Cr-Ni wear-resistant coatings were developed on the surface of nodular cast iron using laser cladding technology. The influence of laser power (P), powder feeding rate (F), scanning speed (V), and overlapping rate (φ) on the microhardness and dilution rate of the coatings was analyzed by response surface methodology, while the model’s accuracy was evaluated through analysis of variance. Subsequently, the multi-objective particle swarm optimization algorithm was utilized to identify the optimal process parameters (P = 1350 W, V = 12.5 mm/s, F = 9 g/min, and φ = 45%) based on non-destructive testing results. The predictive model values closely matched the experimental results. The average microhardness of the Fe-Cr-Ni cladding layer was 620.3 HV, which was 2.8 times that of the nodular cast iron substrate. Importantly, the laser cladding layer demonstrated a significant improvement in wear resistance compared to the substrate. The wear mechanisms for the coating predominantly involved mild abrasive wear and adhesive wear, while the substrate primarily experienced severe adhesive wear. This study offers valuable insights for optimizing laser cladding process parameters for nodular cast iron. Full article

CrAlN PVD coatings are frequently used to protect cutting tools because of their superior hardness and wear resistance. However, the influence of carbon addition to such coatings remains largely unexplored. Therefore, Cr-Al-C-N coatings were deposited by HiPIMS using a commercial PVD unit equipped with a segmented sputter target. The target consisted of an upper half of Cr and a lower half of Al. Carbon was added under reactive sputtering conditions with the aim of reducing internal stress and introducing a friction-reducing component. A range of different Al-Cr-C compositions could be efficiently explored by varying the acetylene reactive gas flow. Depending on the positioning of the samples, Cr/Al ratios could be varied between about 4/1 and 1/2 while three different levels of carbon concentration (0, 11, and 25 atomic % of total coating composition) were investigated. It was found that an intermediate carbon concentration effectively increased the hardness of Cr-rich coatings, achieving maximum plastic hardness values over 40 GPa. With increasing Al content, hardness drops to below 30 GPa. The cubic CrN phase with mostly 200-oriented grains was detected for most variants. With increasing Al and C contents, a rapid decrease in crystallite size is observed, accompanied by a reduced intensity of the (200) XRD reflection. A turning test on stainless steel showed decreasing flank wear with higher Al contents. However, no improvement associated with carbon addition could be confirmed within the investigated concentration range. Full article

Microplastics (MPs) and potentially toxic elements (PTEs) increasingly co-occur in agricultural and peri-urban soils, yet their combined effects on adsorption, mobility, bioavailability, and phytotoxicity are highly context-dependent. This review synthesizes plant–soil evidence by focusing on the interacting roles of MP polymer type, particle size and shape, aging/weathering state, soil geochemistry, dissolved organic matter, and rhizosphere processes. Across the reported studies, MP-PTE interactions show several major directions of changes: MPs may reduce PTE lability by promoting adsorption, aggregation, or sequestration within coated surfaces and soil aggregates; conversely, they may increase PTE mobility and plant exposure when reversible binding, dissolved organic ligands, pH shifts, or particle transport deliver labile PTEs to root-active zones. Dose-dependent and biphasic responses are also common, with low MP additions sometimes attenuating stress while higher doses intensify toxicity. Quantitatively, available crop studies show that intensified co-exposure can reduce plant biomass by approximately 10.2–29.3%, depending on crop species, plant organ, MP type, dose, and PTE identity, whereas antagonistic or neutral responses are also reported under other exposure conditions. The strongest evidence currently exists for Cd and As, but this review also considers Pb, Cu, Zn, Ni, Cr, and Hg to represent chemically distinct cationic, metalloid, and redox-sensitive PTEs. Overall, MPs should not be treated only as passive contaminant carriers; they act as dynamic reactivity modifiers that can function as sinks, vectors, or indirect regulators of PTE bioavailability depending on soil and rhizosphere boundary conditions. Full article

This study investigates the tribological performance of three commercial PTFE-based Xylan^® coatings—Xylan^® 1425, Xylan^® 1052, and Xylan^® 1010—applied to 18CrNiMo7-6 steel under dry sliding conditions. Ball-on-Disk tests were conducted at normal loads of 5, 7.5, and 10 N, wear-track radii of 12, 16, and 20 mm, and corresponding sliding velocities of 0.31–0.52 m·s⁻¹. The tribological evaluation was complemented by measurements of coating thickness, surface roughness, nanoindentation, wear-track profilometry, scanning electron microscopy, EDS mapping, and post-test cross-sectional microscopy. All coatings reduced the coefficient of friction from approximately 0.49–0.64 for the uncoated steel to 0.09–0.13, corresponding to an average reduction of 78–80%. Xylan^® 1425 exhibited the highest nanohardness of 57.02 MPa, the highest reduced elastic modulus of 3.33 GPa, and the most favorable elastoplastic indices. It also achieved the lowest wear, with a volumetric loss of approximately 0.03 mm³ under the most severe conditions, representing a reduction of more than 99% compared with the substrate. Xylan^® 1010 provided the lowest friction but showed pronounced plastic deformation, whereas Xylan^® 1052 exhibited fragmentation and increased wear. Post-test cross-sectional microscopy confirmed local exposure of the steel substrate in both coatings. Overall, Xylan^® 1425 provided the best balance of low friction, mechanical stability, coating continuity, and wear resistance. Full article

The corrosion-protection performance of zinc oxide-hybrid polymeric coatings is traditionally attributed to the individual contributions of their constituent phases. This study reveals that the calcination temperature of zinc oxide (ZnO) filler is a critical, previously overlooked processing parameter that dictates not only filler crystallinity but also the collective synergistic failure mechanism of the entire coating system. Herein, we demonstrate that incorporating ZnO calcined at 500 °C yields a ternary chitosan–graphene oxide–zinc oxide/epoxy (CS–GO–ZnO/EP) composite coating with a highly compact, dense morphology, minimal internal porosity, and exceptional filler dispersion, as validated by FTIR, XRD, and SEM analyses. The optimized CS–GO–ZnO/EP coating applied to carbon steel exhibits outstanding dry and wet pull-off adhesion strengths, the highest surface hydrophobicity (102.2°), and superior electrochemical barrier protection. Notably, after a 120-h immersion period in an aggressive 3.5 wt.% NaCl electrolyte, the CS–GO–ZnO/EP (500 °C) maintains excellent coating resistance (R_coat = 1.06 × 10⁵ Ω) and a minimized corrosion rate (CR = 0.074 mm/y). This thermal threshold is a key processing window that improves chemical bonding and compatibility between the different parts of the hybrid matrix without causing the severe nanoparticle sintering, phase aggregation, and micro-cracking that happen at 650 °C. This work offers a significant advancement in the design of eco-friendly, high-performance hybrid coatings, demonstrating that precise control of the inorganic phase’s thermal history provides a direct pathway toward superior durability, hydrophobicity, and electrochemical stability for carbon steel protection in aggressive marine environments. Full article

Tool steel TD salt-bath vanadizing generally relies on expensive analytical-grade raw materials, yet systematic investigations into low-cost industrial borax-based vanadizing of 9SiCr steel remain insufficient. This work intends to optimize the industrial salt-bath vanadizing process and clarify the growth mechanism of vanadium carbide coatings. TD thermal diffusion vanadizing was performed on 9SiCr steel using a molten borax salt bath containing industrial-grade borax and V₂O₅. Metallurgical microscopy, XRD, SEM-EDS and microhardness testing were adopted to systematically explore the effects of treatment temperature and holding time on coating thickness, microstructure and hardness. Continuous, dense VC coatings with favorable metallurgical bonding were fabricated. Coating thickness increased linearly with temperature and followed a parabolic growth law with respect to holding time. The optimized parameter was identified as 970 °C for 4 h, yielding a 8.3 μm thick coating with an average microhardness of ~2500 HV and an 8 μm thick diffusion transition layer. Comparative chromizing experiments indicated that the chromium carbide coating (16.7 μm) was approximately twice the thickness of the VC coating under identical conditions, demonstrating that VC coating growth is restricted by the diffusion supply of active carbon from the substrate. This research provides experimental data and theoretical guidance for the industrialized optimization of TD salt-bath vanadizing for 9SiCr steel. Full article

To address the problem of the short service life of relay injection molds caused by erosion of high-temperature glass fibers, AlCrN coatings were deposited on the surface of ELMAX mold steel using multi-arc ion plating technology. The surface morphology, cross-sectional morphology, and elemental composition of the coatings were analyzed using scanning electron microscopy (SEM) and the attached energy-dispersive X-ray spectroscopy (EDS). The phase structure was characterized by X-ray diffraction (XRD). The surface hardness, film–substrate adhesion strength, and friction and wear performance were tested using a nanoindenter, a scratch tester, and a friction and wear tester, respectively. The effects of duty cycle, arc current, and negative bias voltage on the coating microstructure, hardness, adhesion strength, and friction and wear performance were systematically investigated. Increasing the duty cycle increases surface particles and pits but improves coating density; increasing the arc current increases coating thickness but coarsens particles; increasing the negative bias voltage refines particles but increases pits. Through a three-factor, three-level orthogonal experiment and a multi-index equal-weight weighting method, with hardness, adhesion strength, and friction coefficient as comprehensive evaluation objectives, the optimal process parameters were determined as a duty cycle of 70%, an arc current of 60 A, and a negative bias voltage of 110 V. The optimized coating achieved a hardness of 36.04 GPa (399% higher than that of the uncoated substrate), an adhesion strength of 143.87 N, and a friction coefficient of 0.422. In production cycle tests, the coated mold exhibited an average service life of 128,070 cycles, which is 277% higher than that of the uncoated mold (33,985 cycles). The surface of the coated mold showed only slight scratches, while the uncoated mold exhibited severe glass-fiber plowing grooves. This study provides a process optimization and verification solution for extending the service life of injection molds. Full article

This study investigated how compositional variation within the AlTiSiCrCo high-entropy alloy (HEA) system affects the microstructure, hardness, and dry sliding wear behaviour of laser-cladded coatings on Ti6Al4V. Three coatings, namely, equiatomic (HEA 1), Cr/Co-enriched (HEA 2), and Al/Ti-enriched (HEA 3), were characterized by SEM, EDS, XRD, and Vickers microhardness and tested for dry sliding wear using a ball-on-disc tribometer at 5 N and 15 N. All coatings comprise a BCC solid solution matrix reinforced by intermetallic precipitates. HEA 2 and HEA 3 gave the highest hardness (755 HV and 754 HV, respectively) against 705 HV for HEA 1 and 345 HV for the Ti6Al4V substrate. All HEA coatings reduced wear rate relative to Ti6Al4V; HEA 2 recorded the lowest rate ($4.570\times {10}^{-5}$ mm³/N.m and $2.744\times {10}^{-4}$ mm³/N.m at 5 N and 15 N, respectively), well below the substrate ($2.257\times {10}^{-4}$ mm³/N.m and $0.0014$ mm³/N.m at 5 N and 15 N, respectively). Worn surface analysis showed abrasive/delamination at 5 N transitioning to more severe abrasive, adhesive, and delamination wear at 15 N. The enhanced wear resistance of HEA 2 stems from the BCC solid solution strengthening, intermetallic reinforcement, and high chromium content, which aids in the formation of the Cr₂O₃ protective oxide film. Overall, enriching the coating with chromium and cobalt proved to be the most effective approach for improving the tribological performance of laser-cladded AlTiSiCrCo HEA coatings on Ti6Al4V. Full article

Chromium coatings with excellent corrosion resistance and strong Zr interfacial bonding are economical candidates for accident-tolerant fuel claddings. Irradiation-triggered elemental interdiffusion and interfacial voids severely degrade their service reliability. Ni alloying was introduced into the Cr matrix to obtain composite coatings with improved mechanical properties and irradiation resistance. CrNi coatings with different Ni contents were deposited using magnetron sputtering, whose microstructural features, phase composition, mechanical properties and irradiation behavior were comprehensively characterized by XRD, SEM, TEM and mechanical measurements. The pristine CrNi coatings display compact and uniform microstructural morphologies. Increasing Ni concentration significantly refines the columnar grain architecture and diminishes grain dimensions. Post-irradiation microstructural characterization reveals distinct structural evolution features of CrNi coatings with different Ni contents. Pure Cr and low-Ni coatings present enhanced XRD diffraction intensities and contain high-density irradiation-induced dislocation loops. The 27 at.% Ni coating after irradiation is indicative of irradiation-triggered local recrystallization and defect annihilation. Mechanical tests confirm that moderate Ni alloying (~17 at.%) achieves improved resistance to irradiation-induced hardening through solute–defect interaction effects, whereas excessive Ni (~27 at.%) degrades mechanical properties owing to aggravated lattice disorder, increased free volume, and soft Ni-phase dilution effects. Full article

This study investigates the influence of detonation spraying parameters on the microstructure, mechanical properties and tribological performance of self-fluxing Ni–Cr–Fe–Si–B–C coatings deposited on AISI 321 stainless steel substrates. The effects of the barrel filling ratio (48–68%), the oxygen-to-fuel molar ratio (O/C = 1.026–1.856), and the delay time between detonation shots (0–1 s) were systematically evaluated. The coatings were characterized using scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), microhardness measurements, instrumented indentation, and ball-on-disk tribological testing. Microstructural investigations revealed that the spraying parameters significantly influence coating thickness, porosity and defect formation. The lowest porosity (0.306 per cent) and the most homogeneous microstructure were obtained at a barrel filling ratio of 48 per cent, an O/C ratio of 1.026 and a shot delay of 1 s. XRD analysis identified a multiphase structure consisting of a Ni₃Fe matrix reinforced by Cr₇C₃ carbides, Ni₃B and CrB borides, and Ni₃₁Si₁₂ silicides. Tribological tests demonstrated that increasing the delay between shots significantly improved wear resistance, reducing the wear rate to 1.89 × 10⁻⁴ mm³/(N × m). The optimised coating exhibited an average coefficient of friction of 0.578 ± 0.093 and a wear rate of 1.03 × 10⁻⁴ mm³/(N × m). Instrumented indentation revealed a hardness of 1049.1 ± 43.4 HV and a Young’s modulus of 215.9 ± 8.5 GPa. The wear mechanism was predominantly abrasive–adhesive, whilst the wear rate of the 100Cr6 counter-body remained low at 1.20 × 10⁻⁵ mm³/(N × m). The results obtained demonstrate that appropriate optimisation of detonation spraying parameters enables the formation of dense Ni–Cr–Fe–B–Si–C coatings with superior mechanical and tribological properties, making them promising candidates for wear-resistant engineering applications. Full article

Surface-dominated failures such as micropitting, scuffing, and rolling contact fatigue remain critical challenges for 20CrMnTi gear steel under high-stress and poor lubrication conditions. Inspired by the composite bionic “checkerboard + dot-matrix dimple” architecture found in natural surfaces, this study aims to develop an optimized biomimetic texture combined with a graphene solid lubricant coating to enhance the tribological performance of 20CrMnTi alloy. Laser surface texturing was employed to fabricate the bionic pattern on 20CrMnTi substrates, followed by deposition of an oxysilane-graphene coating. Reciprocating ball-on-disc tribological tests were conducted under both dry friction and oil-lubricated conditions. The results showed that under dry friction, the optimized textured and coated specimen achieved an average friction coefficient of ~0.18, representing a ~62% reduction compared to the untextured surface (~0.47). Under oil lubrication, the friction coefficient was further reduced to ~0.10–0.11, demonstrating a synergistic effect among the texture, graphene coating, and lubricant. Wear volume decreased by over 70% under dry conditions. The dominant wear mechanism shifted from severe adhesive–abrasive–oxidative wear to mild adhesive and abrasive wear. These findings suggest that the proposed composite bionic texture combined with a graphene coating offers an effective strategy for improving the tribological durability of 20CrMnTi gear. Full article