Search Results (2,296)

The control of cladding layer morphology is crucial in laser cladding technology. However, traditional process parameter-based regulation suffers from parameter coupling issues, and previous nanosecond laser pretreatment is prone to causing uneven substrate morphology due to significant thermal effects. This study proposes a novel substrate pretreatment method using femtosecond laser etching, employing 45 steel as the substrate and Ni45 powder as the cladding material to investigate its regulatory effect on cladding layer morphology. The results show that femtosecond laser etching enables a good linear correlation between substrate roughness and laser power, forming uniform grid-like microgrooves without the spherical remelted structures observed in nanosecond laser treatment, thus achieving superior regulatory stability. With the increase in substrate roughness, the contact angle and dilution rate of the cladding layer decrease, while the cladding height and width increase, with the optimal cladding quality obtained in the roughness range of 4~7 μm. This study reveals the intrinsic mechanism by which femtosecond laser regulates molten pool behavior through mechanical anchoring and groove guiding effects, providing a more stable technical pathway for the preparation of high-quality cladding coatings. Full article

Synthetic microfibres released during textile drying are considered an emerging source of microplastic pollution, yet this waste stream is generally discarded without treatment. This study investigates a valorisation route by incorporating waste dryer-filter microfibres into a potassium-based/metakaolin geopolymeric coating for architectural applications, with the dual objective of preventing environmental release and enhancing material performance. Geopolymer pastes containing 0.1–0.3 wt.% of synthetic microfibres were characterised in terms of physical, mechanical and microstructural behaviour. Microfibre addition produced a marked toughening effect, with flexural strength increasing from about 3 MPa for the unreinforced matrix to 7.5 MPa for the composite containing 0.3 wt.% fibres, while compressive strength decreased moderately due to the presence of a compliant fibrous phase. Microstructural observations confirmed fibre dispersion and fibre–matrix bonding, supporting crack-bridging mechanisms. Density, porosity and water absorption measurements indicated a stable geopolymer gel structure with a connected pore network. Thin-layer applications onto clay brick exhibited satisfactory workability and adhesion, confirmed by pull-off testing (~0.12 MPa) and interfacial microscopy. The results demonstrate that textile-derived microfibres can be effectively immobilised within a potassium geopolymer matrix while improving flexural performance, offering a feasible circular strategy for microfibre waste reuse in mineral coatings. Full article

CoCuNiTi HEACs reinforced by different diamond contents were prepared on the surface of 45 steel substrate by laser cladding. Their phase composition, microstructure, elemental composition, and wear/corrosion resistance were investigated using XRD, OM, SEM, EDS, a friction and wear testing machine, and an electrochemical workstation, respectively. The results show that after adding diamond, the phase composition of the sample transforms from the original dual-phase structure of the FCC main phase and BCC to the dual-phase structure of the BCC main phase and FCC. With an increase in the diamond content, the diffraction peak intensity of the alloy phases first increases and then decreases. This behavior is related to the significant enhancement of the alloy phase crystallinity with low diamond addition and the intensified crystal lattice distortion caused by excessive diamond addition. The CoCuNiTi + x Diamond (C) (x = 0, 0.5, and 1.0 wt.%) high-entropy alloys have a dendritic structure. After the addition of diamond, no hole defects were observed in the microstructure, and the dendritic structure was significantly refined. Ti and C are enriched in the primary phase, Cu is enriched in the interdendrite regions, and Co exhibits the highest concentration in the dendrite regions. The segregation coefficients of Ni in all three alloys are relatively small. As the diamond content increases, the friction coefficient of the samples decreases significantly. The 1 wt.% diamond sample exhibits the best wear resistance, primarily owing to the combined effects of superhard phase strengthening, solid solution strengthening, and fine grain strengthening resulting from diamond addition. The sample with 0.5 wt.% diamond addition has the lowest self-corrosion current density, highest polarization resistance, and lowest annual corrosion rate, indicating the best corrosion resistance. This performance is mainly attributed to the refinement of the microstructure, reduction in defects, and formation of a dense passivation film caused by the addition of a small amount of diamond. Full article

With the growing demand for high-performance die materials under harsh service conditions, the development of composite coatings with enhanced hardness and wear resistance has attracted significant attention. In this study, homogeneous laser cladding was employed to fabricate H13 alloy coatings reinforced with varying TiC contents (0, 10, 20, and 30 in wt.%) on H13 steel, which minimizes compositional segregation and ensures strong metallurgical bonding. TiC particles acted as heterogeneous nucleation sites during solidification, refining the microstructure and enhancing phase stability. The coatings consisted of initial TiC residues, newly formed primary and eutectic TiC, as well as austenite and martensite phases. With increasing TiC addition, TiC morphology evolved from fine particles to complex fishbone-like and polygonal structures. The coating containing 30% TiC achieved the highest hardness of 1095.9 HV_0.5, approximately five times that of the as-annealed H13 steel substrate while the 20% TiC coating exhibited optimal high-temperature wear resistance. Under the sliding conditions at 600 °C, the friction coefficient decreased from 0.467 for the substrate to 0.367 for the 20% TiC coating, accompanied by a remarkable reduction in wear rate from 27.45 × 10⁻⁴ mm³ N⁻¹ m⁻¹ to 4.32 × 10⁻⁴ mm³ N⁻¹ m⁻¹. The superior performance was attributed to the multiscale TiC reinforcement mechanism: initial TiC promoted grain refinement and strong interfacial bonding, in situ formed primary TiC induced lattice distortion and dislocation strengthening, and eutectic TiC reinforced grain boundaries, jointly enhancing hardness, thermal stability, and wear resistance. Full article

HfC possesses high hardness, high melting point, and excellent thermal stability, and is regarded as an important wear-resistant reinforcing phase material. In this study, the laser cladding technique was employed to fabricate CoCrFeNiTi and CoCrFeNiTi/HfC composite coatings on the surface of Q235 substrate. The influence of HfC addition on the phase structure evolution, microstructure, and wear resistance of the coatings was systematically investigated. The results showed that the addition of HfC did not alter the phase structure of the coating, which remained dominated by an FCC solid solution. However, they induced the formation of an in situ TiC strengthening phase and reduced the brittle Laves phase content, thereby optimizing the coating’s toughness. At the same time, the coating transformed from columnar to equiaxed crystals, with significantly finer grains and further improved structural uniformity. Compared with the CoCrFeNiTi coating, the CoCrFeNiTi/HfC composite coating exhibited a more stable friction coefficient, a significantly lower wear rate, and improved wear resistance by approximately 2.4 times. The performance improvement was mainly attributed to the load-bearing strengthening and crack-pinning effect of the in situ TiC, the inhibitory effect of the reduction in the Laves brittle phase on adhesive wear, and the synergistic effect of Hf, which forms a stable oxidation-protective film during friction. Full article

Multilayer laminated composites consisting of high-chromium cast iron (HCCI) powder clad with low-carbon steel (LCS) were fabricated via multi-pass hot rolling at a deformation of 70% under three different temperatures: 1100 °C, 1150 °C, and 1200 °C. The microstructure, elemental diffusion, and mechanical properties of the samples processed at these temperatures were systematically investigated. The results indicate that effective metallurgical bonding was achieved between the HCCI powder and the LCS matrix, with the HCCI regions accumulating high strain energy and dislocation density. Hardness testing demonstrated that higher rolling temperatures lead to increased hardness. The dominant wear mechanism was identified as dry sliding wear. The relatively low content of retained austenite contributed to a reduction in tensile strength, while this microstructure further promoted abrasive wear through the spalling of carbides. These findings suggest that hot processing offers a feasible pathway for improving the wear resistance of HCCI-based composites. Full article

Laser metal deposition operates on the principle of layer-by-layer material addition, wherein each layer is formed by overlapping individual single tracks. Consequently, clads formed serve as the fundamental building blocks for this technology. Their quality directly affects the overall build quality, particularly the geometric characteristics, which are also critical to process productivity. In the present work, geometric characteristics of TiC/Ti6Al4V single tracks fabricated via laser metal deposition are optimised. An artificial neural network model was developed to predict the clad width, height, and dilution using processing parameters, laser power, scan speed, and powder feed rate, as model inputs. The Particle Swarm Optimisation algorithm was employed for hyperparameter selection. The hyperparameter-optimised model achieved a mean squared error of 0.00183 and an R² score of 0.979 during training, and a mean squared error of 0.00709 and an R² score of 0.887 during testing. Although the small discrepancy between training and testing metrics suggests slight overfitting, likely due to the size of the dataset, the model achieved a mean absolute percentage error of less than 10% during testing. Subsequently, process plots generated by the model predictions were used to identify suitable parameters, and a processing map was developed to highlight the window that achieves suitable dilution (14–24%), defect-free sound bonding, and thick and dense clads. Full article

High-strength quenched and tempered steels such as EN 42CrMo4, widely used for marine shaft applications due to their high strength, toughness, and fatigue resistance, are nevertheless susceptible to surface degradation under severe dry sliding conditions. To enhance surface integrity and tribological performance, this study investigates laser-cladded AISI 410L and mixed AISI 410L/AISI 4140 (50/50 wt.%) coatings deposited on EN 42CrMo4 steel using a high-power diode laser (HPDL). Two-layer coatings were produced, and selected specimens underwent post-cladding stress-relief heat treatment to mitigate residual stresses and temper as-solidified microstructures. Microstructural characterization revealed refined dendritic and martensitic morphologies, while the mixed-alloy coatings showed increased carbide formation and improved hardness homogeneity. The mixed AISI 410L/AISI 4140 coatings achieved significantly higher microhardness values (≈530–555 HV) compared to single-alloy 410L coatings (≈310–420 HV). Tribological testing under dry sliding conditions (Al₂O₃ counterbody, 5 N load, 0.5 m/s sliding speed) demonstrated that the mixed-alloy coatings exhibited substantially lower steady-state friction coefficients (μ ≈ 0.65–0.69) and markedly reduced specific wear rates (≈11–17 × 10⁻¹⁴ m³/Nm) compared to the 410L coatings (≈150–175 × 10⁻¹⁴ m³/Nm). Post-cladding heat treatment further stabilized friction behaviour and reduced wear in the mixed-alloy system by tempering martensite and alleviating localized stress concentrations. Wear mechanism analysis revealed a transition from severe abrasive wear with fatigue-induced delamination in the 410L coatings to predominantly mild abrasive wear in the mixed-alloy coatings, accompanied by localized plastic deformation. Overall, the results establish clear correlations between microstructure, hardness, and tribological response, demonstrating that mixed-alloy laser cladding is an effective strategy for enhancing the dry sliding performance of EN 42CrMo4 steel in demanding marine applications. Full article

Background/Objectives: Chronic lung allograft dysfunction (CLAD) remains the leading cause of late graft failure after lung transplantation (LuTX). De novo donor-specific anti-HLA antibodies (dnDSA), especially HLA-DQ, have been implicated; we assessed associations between dnDSA (class and specificity) and CLAD after LuTX. Methods: We retrospectively analyzed all LuTX recipients transplanted from 2005–2018 at a single center (n = 585). dnDSA were measured by Luminex single-antigen bead assays (MFI > 1000) at 1, 3, 6, and 12 months and at least annually thereafter. CLAD was defined by ISHLT criteria; time-to-event comparisons used log-rank testing. Results: dnDSA developed in 151/585 recipients (25.8%), predominantly class II (129/585; 22.1%); class I dnDSA occurred in 52/585 (8.9%). CLAD occurred more frequently in dnDSA-positive than dnDSA-negative recipients (64/151; 42.4% vs. 109/434; 25.1%; p < 0.0001). Rejection-attributed death was higher in dnDSA-positive recipients (19/151; 11.3% vs. 25/434; 5.3%; p = 0.01). Both class I and class II dnDSA were associated with higher CLAD rates (log-rank p < 0.001 each). Locus-specific analyses identified HLA-DQ dnDSA as strongly associated with CLAD (p < 0.0001); DQ7 was the most frequent specificity (n = 44) and showed the strongest association (p < 0.0001). Conclusions: dnDSA after LuTX were associated with increased CLAD incidence and rejection-attributed mortality, with a prominent association for HLA-DQ—particularly DQ7. Full article

Lung transplantation provides a curative option for patients living with end-stage lung disease, with a goal of improving survival and quality of life. Chronic lung allograft dysfunction, or CLAD, represents a major cause of morbidity and mortality, particularly after the first year of transplant. Background/Objectives: The goal of this review is to outline the diagnosis and management of CLAD within the lung transplant population, as well as discuss future areas of potential research interest. Methods: A PubMed literature review of relevant publications regarding CLAD epidemiology, diagnosis, and management was performed to assess current understandings. Results: CLAD is the leading cause of death in lung transplant patients following the first year of transplant, and is common, with approximately 50% of patients exhibiting some degree of CLAD within five years of surgery. Well-established guidelines on diagnosis were recently published to aid clinicians in diagnosing and characterizing CLAD. Several medical and surgical interventions exist, although no therapy consistently and reliably stabilizes or reverses CLAD. Conclusions: CLAD management remains a priority within the lung transplant field as a leading cause of morbidity and mortality. Full article

Bio-inspired and bio-based materials are increasingly recognized as powerful enablers of climate-responsive and low-carbon architecture. By learning from natural systems, such as adaptability, self-regulation, and resource efficiency, these materials offer promising solutions to the escalating environmental pressures faced by the built environment. However, their systematic integration into building design remains limited, particularly in tropical monsoon climates. To address this gap, this study applies the Decision-Making Trial and Evaluation Laboratory (DEMATEL) method to identify, prioritize, and map the interdependencies among ten bio-based and bio-inspired strategies for sustainable building design. The results highlight five dominant solutions: living building systems, bio-composite exterior cladding for weather resistance, mycelium-based insulation for humidity control, bio-based natural ventilation and passive cooling, and bio-inspired self-shading systems. The causal analysis reveals three key characteristics: (1) living building systems function as a central integrative nexus, (2) bio-composite cladding acts as a primary driver of durability and climate resilience, and (3) bio-based water filtration and local timber exhibit lower systemic leverage despite their environmental benefits. Theoretically, this study advances biomimetic design research by introducing a causal, system-level framework for understanding interactions among nature-inspired strategies. Practically, it provides architects, engineers, and policymakers with an evidence-based decision-support tool to prioritize climate-adapted, bio-inspired solutions, contributing to the development of resilient and regenerative architecture in rapidly changing climates. Full article

This study utilized oscillating laser cladding technology to fabricate nickel-based composite coatings, systematically investigating the influence of varying laser powers on their morphology, microstructure, and properties. The results indicate that as laser power increases from 800 W to 1400 W, the dilution rate of the coating exhibits a non-monotonic change, reaching a maximum at an intermediate laser power due to the competing effects of enhanced substrate melting and melt-pool instability. The microstructure of the coatings is primarily composed of dendritic and equiaxed crystals. Elemental analysis revealed that Ni is predominantly enriched within the dendritic regions, whereas Cr segregates toward the grain boundary areas. Furthermore, the microhardness of the coating, as well as its anti-wear and anti-corrosion properties, are positively correlated with the laser power. When the power reaches the maximum value of 1400 W studied, the performance of the coating significantly improves. The average hardness is 482 HV, and the relative wear resistance is approximately 1.8 times that of the coating when the power is 800 W. The corrosion current density is 9.04 × 10⁻⁷ A/cm². Full article

This study investigates the tribological and electrochemical corrosion behavior of laser-clad nickel–aluminum bronze (NAB) coatings reinforced with WC particles (0, 8, 16 wt.%). Through microstructural characterization and phase analysis, it was found that in the NAB coating containing 16% WC, the WC particles and carbides were uniformly distributed, serving as a reinforcing scaffold. During the friction and wear process, they effectively reduced the contact area between the counter ball and the NAB matrix to a certain extent, smoothing the wear process and resulting in a more stable friction coefficient. Electrochemical testing demonstrates that WC addition significantly enhances corrosion resistance: NAB + 8%WC exhibits a low corrosion current density (i_corr), the highest polarization resistance, and the densest protective film. The dual mechanisms—grain boundary blocking and ion channel obstruction—reduce selective Al/Fe leaching and minimize Cl⁻ penetration. The 8% WC formulation optimizes the electrochemical performance, providing excellent corrosion resistance in a simulated marine environment. Full article

The present study investigates the effect of welding heat input on the corrosion resistance of duplex stainless steel (DSS) overlays, with particular focus on applications in pressure vessels and clad plates. ER2209 filler metal was deposited onto SA-516 Gr. 70 carbon steel using GMAW, both manually and mechanized, with varying heat inputs. Microstructural characterization included ferrite-content measurement, macrographic analysis, and pitting-corrosion testing according to ASTM G48 Method A. The results indicate that increasing the heat input from 548 J mm⁻¹ to 2319 J mm⁻¹ significantly reduced the ferrite content from 49% to 25%, leading to a corresponding increase in weight loss from 0.55% to 2.5%. Mechanized welding exhibited better arc stability and more consistent phase distribution compared to the manual process. Although we did not detect brittle phases or intermetallic precipitates due to strict interpass temperature control, the microstructural imbalance induced by high-heat-input directly compromised the corrosion resistance. These findings advance understanding of the optimized welding parameters required to ensure the integrity of DSS coatings in aggressive environments. Full article

Laser-cladding directed energy deposition enables both the repair and fabrication of complex metallic components with curved surfaces. However, during multi-axis deposition on curved substrates, sharp transient feed-rate fluctuations at corner segments—together with an approximately constant powder feed rate—readily cause local over-deposition and geometric defects (e.g., nodules and humps). These defects compromise surface-profile fidelity, thereby creating a major barrier to practical deployment. To overcome this limitation, we propose a corner-oriented path-optimization strategy based on geometric code parsing. By operating directly on the toolpath without modifying the Computer-Aided Design model or slicing workflow, the proposed method suppresses corner overbuild and associated morphological distortion in curved-surface directed energy deposition, substantially improving dimensional consistency and surface quality. Overall, this strategy provides a scalable and broadly applicable route toward high-precision, high-reliability, industrial-scale curved-surface additive manufacturing. Full article