Superhydrophobic Surfaces: Wetting Phenomena and Preparation Methods

A special issue of Surfaces (ISSN 2571-9637).

Deadline for manuscript submissions: 31 May 2026 | Viewed by 6885

Special Issue Editor

School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081, China
Interests: biomimic; superhydrophobic surface; wetting; preparation

Special Issue Information

Dear Colleagues,

Superhydrophobic surfaces, which exhibit extreme water repellency, have captivated human curiosity for centuries; one of the earliest natural examples can be traced back to the observation of lotus leaves, whose self-cleaning ability—driven by their unique micro- and nanostructured surface combined with a low-surface-energy wax layer—has long inspired interest. Though ancient civilizations may not have understood the underlying science, the practical benefits of such water-repellent properties, from keeping surfaces dry to reducing contamination, were intuitively recognized. Today, the study of superhydrophobic surfaces has evolved into a sophisticated field, deeply rooted in the understanding of wetting phenomena. Wetting behavior, characterized by contact angles exceeding 150° and sliding angles below 10°, is governed by a complex interplay of surface chemistry (e.g., low-surface-energy functional groups) and topography (e.g., hierarchical micro-/nanostructures, porous architectures, or re-entrant geometries).

The preparation of superhydrophobic surfaces has seen remarkable diversification, encompassing a wide range of techniques tailored to specific materials and applications. These include chemical etching to create microscale roughness on metallic substrates, sol-gel synthesis for depositing ceramic-based coatings with controlled nanostructures, electrospinning to fabricate polymeric nanofiber mats with inherent hydrophobicity, and vapor deposition methods (such as chemical vapor deposition or physical vapor deposition) for precise control over surface chemistry and morphology. Additionally, bioinspired approaches, mimicking lotus leaves or water strider legs, have led to innovative fabrication strategies that combine roughness and low surface energy in novel ways.

In this Special Issue, we will showcase the latest advancements in the understanding of wetting phenomena on superhydrophobic surfaces and the development of cutting-edge preparation techniques. We welcome original research articles that explore fundamental aspects of wetting mechanics, surface characterization, and durability, as well as short critical reviews that synthesize current trends, challenges, and future directions in the field—from environmental applications such as anti-icing and corrosion protection to industrial uses in self-cleaning materials and microfluidics.

Dr. Bo Zhang
Guest Editor

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Keywords

  • superhydrophobic surface
  • wetting
  • fabrication

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Published Papers (3 papers)

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Research

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15 pages, 1405 KB  
Article
Surface Functionalization of Poly(ethylene terephthalate) via Surface-Initiated Atom Transfer Radical Polymerization to Achieve Superhydrophobic, Hydrophilic, and Antibacterial Properties
by Jin Motoyanagi, Hao Maekawa, Yuji Aso and Masahiko Minoda
Surfaces 2026, 9(1), 23; https://doi.org/10.3390/surfaces9010023 - 24 Feb 2026
Viewed by 667
Abstract
Poly(ethylene terephthalate) (PET) is a widely used commodity polymer owing to its low cost, excellent mechanical properties, and high processability. Chemical modification of PET surfaces to impart specific functionalities represents an effective strategy for transforming PET into high-value-added materials without altering its bulk [...] Read more.
Poly(ethylene terephthalate) (PET) is a widely used commodity polymer owing to its low cost, excellent mechanical properties, and high processability. Chemical modification of PET surfaces to impart specific functionalities represents an effective strategy for transforming PET into high-value-added materials without altering its bulk properties. In this study, we investigated the surface functionalization of PET substrates using surface-initiated atom transfer radical polymerization (SI-ATRP). ATRP initiation sites were introduced onto PET surfaces through mild surface hydrolysis followed by polyethyleneimine coating. To further enhance the grafting density, an inimer-based strategy was employed, in which a bifunctional monomer containing both a polymerizable group and a latent initiation site was used to form hyperbranched polymer structures on the PET surface, thereby amplifying the number of active initiation sites. Using these modified PET substrates, SI-ATRP of functional methacrylate monomers was successfully carried out. Grafting of poly(2,2,2-trifluoroethyl methacrylate) imparted highly hydrophobic surface properties, yielding water contact angles above 120°, whereas grafting of poly([2-(methacryloyloxy)ethyl]trimethylammonium chloride) produced hydrophilic surfaces with contact angles below 20°. Surface characterization by X-ray photoelectron spectroscopy confirmed successful graft polymerization and effective surface coverage. While the macroscopic wettability was primarily governed by the chemical nature of the grafted polymers, the inimer-based initiation-site amplification significantly enhanced the surface electrostatic properties of the polycationic polymer–grafted surfaces, increasing the ζ-potential from approximately +20 mV to over +100 mV. Antibacterial tests using Escherichia coli K-12 as a model bacterium demonstrated that PET substrates grafted with poly([2-(methacryloyloxy)ethyl]trimethylammonium chloride) exhibited clear contact-active antibacterial activity, achieving up to 2-log reduction in viable bacterial counts after 3 h of contact incubation. These results highlight the importance of molecular-level control of grafting architecture and surface electrostatic properties in the design of functional antibacterial PET surfaces. Full article
(This article belongs to the Special Issue Superhydrophobic Surfaces: Wetting Phenomena and Preparation Methods)
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16 pages, 12162 KB  
Article
Adjustable Capillary Forces Through Wetting State Changes in Liquid Bridges: Regulation via Trapezoidal Microstructures
by Yanlian Liu, Xueli Chen, Yu Wang, Guannan Lei, Junsheng Zhao, Taiyang Li, Liyang Huang and Bo Zhang
Surfaces 2025, 8(4), 73; https://doi.org/10.3390/surfaces8040073 - 12 Oct 2025
Viewed by 3618
Abstract
A detailed understanding of the mechanistic role of solid surface microstructures in modulating capillary forces and liquid transport in liquid bridge systems is crucial, for liquid bridges between rough surfaces are omnipresent in nature and various industries. In this work, Gibbs free energy [...] Read more.
A detailed understanding of the mechanistic role of solid surface microstructures in modulating capillary forces and liquid transport in liquid bridge systems is crucial, for liquid bridges between rough surfaces are omnipresent in nature and various industries. In this work, Gibbs free energy expression was derived for a liquid bridge system confined between a smooth surface and a microstructured surface, based on the principle of minimum thermodynamic potential. Furthermore, by analyzing the energy conversion during spacing variation between the two solid surfaces, an analytical expression for the capillary force of the liquid bridge was derived that incorporates the geometric parameters of the microstructures and the contact angle. Finally, numerical simulations were performed using the Fluent UDFs (User-Defined Functions) to validate the proposed capillary force model. The simulation results validated the analytical expression and revealed the influence of the microstructures on the force distribution on the upper and lower surfaces of the liquid bridge, and on the droplet transport performance. Full article
(This article belongs to the Special Issue Superhydrophobic Surfaces: Wetting Phenomena and Preparation Methods)
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Review

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22 pages, 3104 KB  
Review
Fluorination to Convert the Surface of Lignocellulosic Materials from Hydrophilic to Hydrophobic
by Alexandre Dumontel, Olivier Téraube, Tomy Falcon, Angélique Bousquet, Eric Tomasella, Monica Francesca Pucci, Pierre-Jacques Liotier, Yasser Ahmad, Karine Charlet and Marc Dubois
Surfaces 2026, 9(1), 3; https://doi.org/10.3390/surfaces9010003 - 25 Dec 2025
Viewed by 1965
Abstract
Natural fibers are increasingly used as sustainable, lightweight, and low-cost alternatives to glass fibers in polymer composites. However, their inherent hydrophilicity and surface polarity limit compatibility with non-polar polymer matrices. Both gas/solid and plasma fluorination modify only the surface of lignocellulosic materials. Mild [...] Read more.
Natural fibers are increasingly used as sustainable, lightweight, and low-cost alternatives to glass fibers in polymer composites. However, their inherent hydrophilicity and surface polarity limit compatibility with non-polar polymer matrices. Both gas/solid and plasma fluorination modify only the surface of lignocellulosic materials. Mild conditions are mild, with reactivity governed by fluorine concentration, temperature, and material composition. Surface energy is typically assessed through contact-angle measurements and surface analytical techniques that quantify changes in hydrophobicity and chemical functionalities. In wood, fluorination proceeds preferentially in lignin-rich regions, making lignin a key component controlling reactivity and the spatial distribution of fluorinated groups. Natural fibers follow the same logic as for flax, which is a representative example of lignin content. Applications of fluorinated bio-based materials include improved moisture resistance, enhanced compatibility in composites, and functional surfaces with tailored wetting properties. Scalability depends on safety, cost, and process control, especially for direct fluorination. Durability of the treatment varies with depth of modification, and environmental considerations include the potential release of fluorinated species during use or disposal. Full article
(This article belongs to the Special Issue Superhydrophobic Surfaces: Wetting Phenomena and Preparation Methods)
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