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Advances in Material Surface Corrosion and Protection
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Advances in Material Surface Corrosion and Protection

A special issue of Corrosion and Materials Degradation (ISSN 2624-5558).

Deadline for manuscript submissions: 31 August 2026 | Viewed by 10074

Special Issue Editor

Dr. Wei Jiang

E-Mail Website
Guest Editor
School of Mechanical Engineering, Hefei University of Technology, Hefei 230009, China
Interests: electrochemical machining; energy field control machining; electrochemical additive manufacturing theory and equipment for metal matrix composites; surface corrosion and protection of materials; construction of catalytic electrodes for water electrolysis; integration of micro-nanostructure functions

Special Issue Information

Dear Colleagues,

Corrosion remains one of the most critical challenges in materials science, affecting the durability, safety, and performance of components across various industries, ranging from aerospace and automotive to infrastructure and biomedical engineering sectors. This Special Issue aims to cover recent advances in the understanding, characterization, and mitigation of surface corrosion in metals, alloys, and novel materials. We welcome the submission of papers that focus on innovative surface engineering techniques, smart coatings, nanomaterials, and environmentally friendly inhibitors that extend service life and reduce maintenance costs. We also seek contributions that explore the fundamental mechanisms of corrosion at micro- and nanoscale levels, supported by emerging characterization tools and simulation methods. By integrating experimental, theoretical, and industrial perspectives, this Special Issue aims to inspire new directions in corrosion science and surface protection strategies.

Dr. Wei Jiang
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 250 words) can be sent to the Editorial Office for assessment.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Corrosion and Materials Degradation is an international peer-reviewed open access quarterly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 1200 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • surface corrosion
  • smart coatings
  • nanomaterials
  • surface engineering techniques
  • corrosion mechanisms and modeling

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Further information on MDPI's Special Issue policies can be found here.

Published Papers (6 papers)

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Research

15 pages, 6557 KB  
Article
Corrosion of Extruded WE43, Mg10Gd, and ZX10: Correlation of Morphology and Stress Mapping to Residual Strength Using µCT and DIC
by Agathi Dimakopoulou, Markus Brand, Jan Bohlen and Petra Maier
Corros. Mater. Degrad. 2026, 7(2), 24; https://doi.org/10.3390/cmd7020024 - 10 Apr 2026
Viewed by 632
Abstract
For the corrosion behavior of three extruded Mg alloys (WE43, Mg10Gd, ZX10), the corrosion morphology and the resulting local stress distribution are correlated with the residual strength using µCT, Digital Image Correlation and tensile tests. Samples are corroded in HBSS at 37 °C [...] Read more.
For the corrosion behavior of three extruded Mg alloys (WE43, Mg10Gd, ZX10), the corrosion morphology and the resulting local stress distribution are correlated with the residual strength using µCT, Digital Image Correlation and tensile tests. Samples are corroded in HBSS at 37 °C for various exposure times to increase the extent of corrosion. They are then examined by using the gravimetric method to determine the corrosion rate. Corroded tensile samples are subjected to µCT analysis before and after tensile testing. The crack formation originating from pitting corrosion is discussed on the basis of the stress distribution around local corrosion—its extent is clearly influenced on the morphology. µCT analyses reveals that fractures occur in different ways, either at the smallest cross section, at isolated deep pitting sites, or in other critical areas with critical pitting quantity or size. Mg10Gd has a slightly higher strength compared to WE43 and ZX10. ZX10 maintains superior residual strength over time. Pitting corrosion is mainly observed in Mg10Gd and WE43, with different degrees of residual strength. This study allows for a better understanding and prediction of critical areas of non-uniform corroded Mg alloys and provides information on the bearable stress concentration. Full article
(This article belongs to the Special Issue Advances in Material Surface Corrosion and Protection)
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17 pages, 8451 KB  
Article
Atomic Layer Deposition of Oxide-Based Nanocoatings for Regulation of AZ31 Alloy Biocorrosion in Ringer’s Solution
by Denis Nazarov, Lada Kozlova, Vladislava Vartiajnen, Sergey Kirichenko, Maria Rytova, Anton P. Godun, Maxim Maximov, Arina Ilina, Stephanie E. Combs, Mark Pitkin and Maxim Shevtsov
Corros. Mater. Degrad. 2026, 7(1), 3; https://doi.org/10.3390/cmd7010003 - 26 Dec 2025
Viewed by 1215
Abstract
Research into methods for regulating the biocorrosion rate of biodegradable magnesium implants is one of the most urgent tasks in the field of biomedical materials science. Atomic layer deposition (ALD) is a highly effective method for the preparation of nanocoatings, which can be [...] Read more.
Research into methods for regulating the biocorrosion rate of biodegradable magnesium implants is one of the most urgent tasks in the field of biomedical materials science. Atomic layer deposition (ALD) is a highly effective method for the preparation of nanocoatings, which can be used to regulate the biodegradation rate. The present paper presents the findings of a research study in which the most commonly used simple oxide ALD coatings (Al2O3, TiO2, and ZnO) were examined, in addition to mixed coatings obtained by alternating ALD cycles of the application of ZnO-TiO2 (ZTO) and Al2O3-TiO2 (ATO). The coating thicknesses exhibited a variation within the most typical range for ALD coatings, measuring between 20 and 80 nanometres. The biocorrosion testing was conducted in Ringer’s physiological solution through the measurement of potentiodynamic polarisation curves and impedance spectroscopy. The findings demonstrated that, for Al2O3 coatings, the protective properties exhibited an increase with increasing thickness, while for TiO2, the trend was found to be dependent on the type of precursor utilised. The protective properties of titanium tetraisopropoxide (TTIP) have been observed to increase with increasing thickness. Conversely, the protective properties of titanium tetrachloride (TiCl4) have been observed to decrease. The application of mixed ZTO oxides with a thickness of 40 nm has been demonstrated to reduce the corrosion current by 1.7 and 3.4 times, depending on the use of TiCl4 or TTIP. Furthermore, the effectiveness of ATO coatings of similar thicknesses has been shown to be higher, with a reduction in corrosion currents of 54 and 24 times for samples obtained using TiCl4 and TTIP, respectively. A thorough analysis of the collected data unequivocally demonstrates the superior efficacy of mixed oxides in comparison to their pure oxide counterparts. Full article
(This article belongs to the Special Issue Advances in Material Surface Corrosion and Protection)
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19 pages, 1875 KB  
Article
Natural Orange Peel Extract as a Corrosion Inhibitor and Cleaning Agent for Surgical Instruments
by Willian Aperador, Giovany Orozco-Hernández and Jonnathan Aperador
Corros. Mater. Degrad. 2025, 6(4), 67; https://doi.org/10.3390/cmd6040067 - 17 Dec 2025
Viewed by 2438
Abstract
This study evaluated the efficacy of an environmentally friendly degreasing agent formulated from orange peel extract as both a cleaning agent and corrosion inhibitor for surgical instruments manufactured from 316LVM stainless steel. The extract was obtained via microwave-assisted hydrodistillation and subsequently blended with [...] Read more.
This study evaluated the efficacy of an environmentally friendly degreasing agent formulated from orange peel extract as both a cleaning agent and corrosion inhibitor for surgical instruments manufactured from 316LVM stainless steel. The extract was obtained via microwave-assisted hydrodistillation and subsequently blended with biodegradable surfactants. Its performance was compared against a benchmark commercial cleaner (West Oxyclean®) through Tafel polarization, Electrochemical Impedance Spectroscopy (EIS), Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), and X-Ray Diffraction (XRD). FTIR analysis confirmed the presence of terpenic compounds, predominantly limonene, alongside ethers, alcohols, and unsaturated structure characteristics of citrus essential oils. Polarization and EIS results showed that the formulation containing 0.12% extract exhibited the highest charge-transfer resistance and the lowest corrosion current density (0.093 μA/cm2), achieving an inhibition efficiency of 81.29%, whereas the 0.08% formulation showed greater corrosive response than the commercial cleaner. SEM imaging demonstrated a progressive decline in both the severity and density of localized corrosion attacks with increasing extract concentration, while XRD diffractograms indicated a marked reduction in corrosion-product formation—completely absent at the optimal concentration. These findings demonstrate that orange peel extract functions as an effective and environmentally sustainable corrosion inhibitor, capable of preserving the structural and surface integrity of surgical-grade steel. Its technical performance, combined with its biodegradable profile, positions it as a promising alternative to conventional industrial cleaners within medical and hospital applications. Full article
(This article belongs to the Special Issue Advances in Material Surface Corrosion and Protection)
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23 pages, 2240 KB  
Article
Aging Investigation of Polyethylene-Coated Underground Steel Pipelines
by Gregory R. Neizvestny, Samuel Kenig and Konstantin Kovler
Corros. Mater. Degrad. 2025, 6(4), 62; https://doi.org/10.3390/cmd6040062 - 27 Nov 2025
Viewed by 1490
Abstract
The aging of three-layer polyethylene-coated buried steel pipelines for oil/gas and water transport poses significant challenges for public safety, environmental integrity, and economic sustainability. Over time, these pipelines become increasingly susceptible to corrosion and eventual failures, which can pose environmental hazards, safety risks, [...] Read more.
The aging of three-layer polyethylene-coated buried steel pipelines for oil/gas and water transport poses significant challenges for public safety, environmental integrity, and economic sustainability. Over time, these pipelines become increasingly susceptible to corrosion and eventual failures, which can pose environmental hazards, safety risks, and costly repairs. Consequently, predicting the service life of polyethylene-coated steel pipelines is critical for mitigating corrosion risks, extending operational lifespan, and planning effective maintenance strategies. Current international standards lack clear methodologies and criteria for assessing the aging behavior of polyethylene-coated underground pipelines. Current studies have examined two techniques—Line Current Attenuation (LCA) and Drainage Test (DT)—to estimate aging rates in polyolefin-coated pipelines following soil exposure during service. The present study introduces an innovative approach for evaluating aging behavior. It includes a comprehensive analysis using an exponential aging model to estimate the coating’s average specific electrical resistance at any service time, as well as quantitative criteria for the failure of oil/gas and water pipelines. Moreover, it is based on the modified LCA as the most suitable aging methodology with some limitations. Finally, the study concludes with a derived correlation between the coating’s initial specific electrical resistance and its aging rates, and the prediction of the residual life of the polyethylene coating. This integrated framework provides a robust foundation for regulatory bodies, design engineers, maintenance planners, quality assurance/control teams, and researchers to ensure the long-term integrity and sustainability of underground polyethylene-coated steel pipelines. Full article
(This article belongs to the Special Issue Advances in Material Surface Corrosion and Protection)
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22 pages, 5849 KB  
Article
A Semi-Automated Image-Based Method for Interfacial Roughness Measurement Applied to Metal/Oxide Interfaces
by João Gabriel da Cruz Passos, Luis Fernando Pedrosa Rabelo, Carlos Alberto Della Rovere and Artur Mariano de Sousa Malafaia
Corros. Mater. Degrad. 2025, 6(3), 31; https://doi.org/10.3390/cmd6030031 - 14 Jul 2025
Viewed by 1269
Abstract
Measuring interfacial roughness is essential in evaluating the adhesion of coatings and thermally grown oxides. Conventional contact methods are often impractical for such analyses, especially when the interface lies beneath a nonremovable layer. This study proposes a semi-automated method combining an ImageJ macro [...] Read more.
Measuring interfacial roughness is essential in evaluating the adhesion of coatings and thermally grown oxides. Conventional contact methods are often impractical for such analyses, especially when the interface lies beneath a nonremovable layer. This study proposes a semi-automated method combining an ImageJ macro and an R-language script to assess interfacial roughness from images obtained through scanning electron microscopy (SEM), leveraging chemical contrast between substrate and oxide. The approach preserves user input where interpretation is critical while standardizing measurement to reduce variability. Applied to 21 images from seven experimental conditions, the algorithm successfully reproduced the roughness ranking obtained from manual measurement while also significantly reducing measurement dispersion. Though it underestimates absolute roughness values compared with the user measurements (which should also happen with conventional contact methods), it offers a robust, flexible, and reproducible alternative for interface characterization. Full article
(This article belongs to the Special Issue Advances in Material Surface Corrosion and Protection)
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12 pages, 2705 KB  
Article
Electrochemical Behavior of Cobalt–Chromium Alloy Exposed to Effervescent Denture Cleansers
by Glenda Lara Lopes Vasconcelos, Carolina Alves Freiria de Oliveira, Ana Paula Macedo, Viviane de Cássia Oliveira, Patrícia Almeida Curylofo, Carlos Alberto Della Rovere, Rodrigo Galo, Bruna S. H. Tonin and Valéria Oliveira Pagnano
Corros. Mater. Degrad. 2025, 6(2), 23; https://doi.org/10.3390/cmd6020023 - 12 Jun 2025
Viewed by 2283
Abstract
This study demonstrates that effervescent denture cleansers can influence the electrochemical behavior of cobalt–chromium (Co-Cr) alloys, with a particular focus on their corrosion resistance. The findings underscore the importance for dental professionals of selecting cleansers compatible with Co-Cr prostheses to minimize material degradation [...] Read more.
This study demonstrates that effervescent denture cleansers can influence the electrochemical behavior of cobalt–chromium (Co-Cr) alloys, with a particular focus on their corrosion resistance. The findings underscore the importance for dental professionals of selecting cleansers compatible with Co-Cr prostheses to minimize material degradation and enhance clinical durability. Corrosion resistance was evaluated using open-circuit potential (OCP), corrosion current density (icorr), and passivation current density (ipass). Surface morphology and elemental composition were analyzed through scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). Forty specimens (n = 5 per group) were individually immersed in one of ten test solutions: distilled water (DW), artificial saliva (AS), and eight commercial denture cleansers—Polident 3 minutes™ (P3M), Steradent™ (St), Polident for Partials™ (PP), Efferdent™ (Ef), Corega Tabs™ (CT), NitrAdine™ (Ni), Fixodent™ (Fi), and Kukident™ (Ku). Each specimen was exposed a single solution to avoid cross-contamination. Results showed St, Ef, and Ku had higher OCP values than DW and Ni (p < 0.05), indicating better corrosion resistance. AS exhibited lower OCP values compared to St (p = 0.034), Ku (p = 0.023), and P3M (p = 0.050). DW had higher icorr than PP (p = 0.030), CT (p = 0.005), and P3M (p = 0.003). For ipass, DW had lower values than Ef (p = 0.025) and Ku (p = 0.016). SEM and EDS revealed no significant surface alterations. Understanding the underlying corrosion mechanisms in different solutions provides valuable insights into optimizing material performance and ensuring durability in clinical applications. The corrosion resistance of Co-Cr depends on the stability of the passive oxide layer, which can be degraded by chloride ions, reinforced by sulfate ions, and influenced by active ingredients in denture cleansers. Overall, the Co-Cr alloy demonstrated acceptable corrosion resistance, underscoring the importance of selecting suitable cleansers for prosthesis longevity. Full article
(This article belongs to the Special Issue Advances in Material Surface Corrosion and Protection)
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