Hydrogen and Combustion Emissions: Atmospheric Pathways, NOₓ Impacts, and Clean Energy Futures

A special issue of Atmosphere (ISSN 2073-4433). This special issue belongs to the section "Air Quality".

Deadline for manuscript submissions: 31 March 2026 | Viewed by 972

Special Issue Editors


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Guest Editor
1. Petroleum Engineering Department, College of Engineering, University of Kirkuk, Kirkuk 52001, Iraq
2. Mechanical and Electrical Engineering College, Hainan University, Haikou 570228, China
Interests: combustion; hydrogen; renewable energy; engine emissions; alternative fuel
Special Issues, Collections and Topics in MDPI journals
School of Vehicle and Mobility, Tsinghua University, Beijing 100190, China
Interests: hydrogen; renewable energy; fuel cells; carbon free engines; laser diagnostics; combustion and emission control
Special Issues, Collections and Topics in MDPI journals

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Guest Editor

Special Issue Information

Dear Colleagues,

Hydrogen is increasingly recognized as a cornerstone in the transition to clean and low-carbon energy systems. However, its expanded production, distribution, and utilization—particularly through combustion applications—introduce significant environmental challenges that must be addressed. This Special Issue seeks to bring together interdisciplinary research exploring hydrogen’s role in atmospheric chemistry, with a focus on sustainable hydrogen technology, hydrogen emissions, combustion emissions, NOₓ formation, hydrogen leakage, and interactions with trace atmospheric species.

We invite contributions examining hydrogen-related emissions across production technologies (green, blue, or gray), their impacts on ozone and radical species, and the implications for air quality and climate. Both experimental and modeling are welcome, especially those that integrate life cycle assessments, emission monitoring, and environmental policy frameworks. Special attention will be given to studies addressing NOₓ emissions from hydrogen combustion and the broader climate alongside the ecosystem consequences of large-scale hydrogen deployment.

Aim and Scope

This Special Issue aims to explore the atmospheric implications of hydrogen production and combustion, particularly within the context of emerging clean energy technologies. As hydrogen becomes more widely adopted in transportation, industry, and power generation, it is essential to understand its full atmospheric impact—from NOₓ and trace gas emissions to long-term effects on air quality and climate forcing.

We seek to compile research that addresses the following:

  • Hydrogen leakage and its atmospheric lifetime;
  • Life cycle assessments of hydrogen production pathways with atmospheric considerations;
  • Tropospheric and stratospheric chemistry are affected by hydrogen and its derivatives;
  • Impacts of hydrogen infrastructure on local and regional air quality;
  • Atmospheric modeling of hydrogen emission scenarios;
  • The formation and environmental behavior of NOₓ and other combustion by-products from hydrogen and hydrogen-blended fuels;
  • Radiative forcing implications and hydrogen’s global warming potential;
  • Monitoring technologies for hydrogen and related emissions;
  • Policy and regulatory strategies for managing hydrogen’s environmental footprint.

Importantly, this Special Issue is not limited to atmospheric or combustion emissions. We also welcome contributions that explore broader hydrogen fuel applications—such as dual-fuel systems, hydrogen blending with ammonia, methane, or biofuels, and engine performance and emission characteristics—with or without a specific atmospheric focus. Studies involving fuel design, emissions reduction strategies, renewable hydrogen integration, and combustion optimization are also encouraged.

By bringing together interdisciplinary research from combustion science, atmospheric chemistry, environmental policy, and clean fuel technology, this Special Issue aims to support the sustainable expansion of hydrogen energy systems in the pursuit of global decarbonization goals.

Dr. Omar I. Awad
Dr. Xiao Ma
Prof. Dr. Kumaran Kadirgama
Guest Editors

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Keywords

  • atmospheric hydrogen
  • combustion emissions
  • NOx emission
  • hydrogen leakage
  • green hydrogen emissions
  • air quality impacts
  • atmospheric chemistry
  • hydrogen and climate interactions
  • hydrogen capture
  • sustainable hydrogen technology

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Published Papers (1 paper)

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Research

23 pages, 4946 KB  
Article
Combustion and Emission Analysis of NH3-Diesel Dual-Fuel Engines Using Multi-Objective Response Surface Optimization
by Omar I. Awad, Mohammed Kamil, Ahmed Burhan, Kumaran Kadirgama, Zhenbin Chen, Omar Khalaf Mohammed and Ahmed Alobaid
Atmosphere 2025, 16(9), 1032; https://doi.org/10.3390/atmos16091032 - 30 Aug 2025
Viewed by 708
Abstract
As internal combustion engines (ICEs) remain dominant in maritime transport, reducing their greenhouse gas (GHG) emissions is critical to meeting IMO’s decarbonization targets. Ammonia (NH3) has gained attention as a carbon-free fuel due to its zero CO2 emissions and high [...] Read more.
As internal combustion engines (ICEs) remain dominant in maritime transport, reducing their greenhouse gas (GHG) emissions is critical to meeting IMO’s decarbonization targets. Ammonia (NH3) has gained attention as a carbon-free fuel due to its zero CO2 emissions and high hydrogen density. However, its low flame speed and high ignition temperature pose combustion challenges. This study investigates the combustion and emission performance of NH3-diesel dual-fuel engines, applying Response Surface Methodology (RSM) for multi-objective optimization of key operating parameters: ammonia fraction (AF: 0–30%), engine speed (1200–1600 rpm), and altitude (0–2000 m). Experimental results reveal that increasing AF led to a reduction in Brake Thermal Efficiency (BTE) from 39.2% to 37.4%, while significantly decreasing NOx emissions by 82%, Total hydrocarbon emissions (THC) by 61%, and CO2 emissions by 36%. However, the ignition delay increased from 8.2 to 10.8 crank angle degrees (CAD) and unburned NH3 exceeded 6500 ppm, indicating higher incomplete combustion risks at high AF. Analysis of variance (ANOVA) confirmed AF as the most influential factor, contributing up to 82.3% of the variability in unburned NH3 and 53.6% in NOx. The optimal operating point, identified via desirability analysis, was 20% AF at 1200 rpm and sea level altitude, achieving a BTE of 37.4%, NOx of 457 ppm, and unburned NH3 of 6386 ppm with a desirability index of 0.614. These findings suggest that controlled NH3 addition, combined with proper speed tuning, can significantly reduce emissions while maintaining engine efficiency in dual-fuel configurations. Full article
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