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Proceeding Paper

La3+-Induced Band-Gap Modifications in Barium Hexaferrite: An Investigation of the Structural, Optical, and Dielectric Properties †

by
Gowravi Subramanyam
,
Nishkala Kadambu Rao
and
Mamatha Durgadas Daivajna
*
Department of Physics, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal 576104, India
*
Author to whom correspondence should be addressed.
Presented at the IEEE 5th Eurasia Conference on Biomedical Engineering, Healthcare and Sustainability, Tainan, Taiwan, 2–4 June 2023.
Eng. Proc. 2023, 55(1), 94; https://doi.org/10.3390/engproc2023055094
Published: 29 January 2024

Abstract

M-type barium hexaferrites, BaFe(12−x)LaxO19 (x = 0.0, 0.05, 0.1, 0.15, and 0.2), were prepared by a low-cost solid-state reaction method. The specimens crystallized in a non-centrosymmetric hexagonal magnetoplumbite structure that belonged to the P63/mmc space group. Morphologically, the samples were dense with hexagonal plate-like grains and size variations of around 1.19–1.70 μm. The optical band gap of the system was reduced in the wide band-gap region from 1.78 to 1.74 eV. The band-gap values would be useful in photocatalysis and photovoltaics. The AC conductivity was enhanced with La3+ substitution, following Jonscher’s power law. Maxwell–Wagner-type polarization was observed in the specimen, and tangent loss decreased with La3+ substitution. The values of the tangent loss were in the appropriate range for electromagnetic shielding applications.
Keywords: M-type hexaferrite; water splitting; dielectric properties; M–W-type relaxation M-type hexaferrite; water splitting; dielectric properties; M–W-type relaxation

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MDPI and ACS Style

Subramanyam, G.; Rao, N.K.; Daivajna, M.D. La3+-Induced Band-Gap Modifications in Barium Hexaferrite: An Investigation of the Structural, Optical, and Dielectric Properties. Eng. Proc. 2023, 55, 94. https://doi.org/10.3390/engproc2023055094

AMA Style

Subramanyam G, Rao NK, Daivajna MD. La3+-Induced Band-Gap Modifications in Barium Hexaferrite: An Investigation of the Structural, Optical, and Dielectric Properties. Engineering Proceedings. 2023; 55(1):94. https://doi.org/10.3390/engproc2023055094

Chicago/Turabian Style

Subramanyam, Gowravi, Nishkala Kadambu Rao, and Mamatha Durgadas Daivajna. 2023. "La3+-Induced Band-Gap Modifications in Barium Hexaferrite: An Investigation of the Structural, Optical, and Dielectric Properties" Engineering Proceedings 55, no. 1: 94. https://doi.org/10.3390/engproc2023055094

APA Style

Subramanyam, G., Rao, N. K., & Daivajna, M. D. (2023). La3+-Induced Band-Gap Modifications in Barium Hexaferrite: An Investigation of the Structural, Optical, and Dielectric Properties. Engineering Proceedings, 55(1), 94. https://doi.org/10.3390/engproc2023055094

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