Using Soil Stratigraphy and Tephrochronology to Understand the Origin, Age, and Classification of a Unique Late Quaternary Tephra-Derived Ultisol in Aotearoa New Zealand
Abstract
:1. Introduction
1.1. Ultisols Globally and in New Zealand
1.2. Using Tephrochronology to Facilitate Study of Late Quaternary Ultisols in New Zealand
1.3. Aim and Outline of Paper
1.4. Note on the Definition of ‘Soil,’ Soil Horizon Nomenclature, and Classification
2. Kainui Soil and its Distribution in the Central and Northern Waikato Region
3. Origin of the Kainui Soil
3.1. Soil Stratigraphy (Including Tephra Identification) and Upbuilding Pedogenesis
3.2. Importance of Lithologic Discontinuity
3.3. Clay Mineralogy
- (i)
- The depth to the slowly-permeable (buried) paleosol in the Kainui soil is less than a critical threshold of c. 0.8 m below the land surface (see the approximate boundary line marked in Figure 1): soils with a late Quaternary tephra mantle >c. 0.8 m in thickness are almost invariably allophanic in upper profiles, usually forming Andisols (provided thickness criteria are met), whereas soils with a thinner coverbed ≤c. 0.8 m are usually halloysitic, forming Ultisols.
- (ii)
- Rainfall generally decreases somewhat from south to north across the Hamilton lowlands (c. 1400 mm per year at Kakepuku Road to c. 1200 mm per year at Gordonton Road, dropping to c. 1100 mm or less farther to the north and east) [18,73,150], reducing the potential throughflow of silicon in soil solution through the soil [54]. Winter through-drainage in the Otorohanga soil is likely to be >c. 550 mm; that in the Kainui soil is c. 400 mm, probably considerably less in some years (after [143]). A frequently occurring (c. 70% of years) late summer or early autumn soil moisture deficit, usually lasting several months (typically from c. 30 to 50 median annual days), is generally most pronounced north and northeast of Hamilton [73,150]: the potential summer soil moisture deficit for the Kainui soil is likely to be c. 170 mm; that for the Otorohanga soil is probably <c. 140 mm (after [54,73,151,152]). Generally, rainfall during glacial periods is reduced by up to c. 25% of that of the present, e.g., [153,154], and therefore halloysite formation rather than allophane is promoted in such times because of limited desilication, as evident in the middle to lower profile (below c. 0.9 m depth) of the Otorohanga soil (Figure 8B). From c. 0.9 to 1.5 m depth, both allophane and halloysite have been formed in the Otorohanga soil, very likely during MOIS 3 and 2 when the parent tephras and tephric loess were being deposited and simultaneously weathered and altered by pedogenesis during a mainly (but not wholly) drier and cooler climate [54,102,155,156,157]. That allophane or halloysite, or both, were able to form depends on whether Si concentrations in soil solution were above or below, or, at times, fluctuating around the c. 10–15 ppm threshold of Singleton et al. [141], and if kinetic and thermodynamic conditions were appropriate [44].
- (iii)
- The primary composition of the composite tephras of the upper coverbed comprises a mix of rhyolitic and andesitic tephras [18,36,37]. Although the amounts of rhyolitic glass (with high silica, c. 78 wt%, and moderate alumina, c. 12 wt%) always exceed those of andesitic glass (with moderately high silica, c. 62 wt%, and high alumina, c. 17 wt%) [18,110], the tephras in the southwest parts of the Hamilton lowlands, such as at Kakepuku Road in Waipa District (Figure 1A), have a proportionally higher andesitic component (up to c. 30–35%) than in the northern and north-eastern parts (up to c. 10–15%) as demonstrated by analyses of the lacustrine tephras across the Hamilton lowlands (Figure 1A) [18,36,37] because the southern locations are a bit closer to the main source volcanoes of andesitic tephras, Tongariro and Egmont (Taranaki) (Figure 1B). This general ‘compositional gradient’ thus enhances the formation of Al-rich allophane in southern/southwestern areas and halloysite in northern/north-eastern areas [59].
- (iv)
- As the tephras accumulate on stable sites, they, being mainly siliceous to very siliceous, provide an ever-thickening ‘overburden’ (thickening coverbed and concomitantly rising land surface) and hence effectively contribute a more-or-less persistent supply of silica and alumina, e.g., [18,158]. This situation may be compared with the dissolution kinetic-fluid flow coupling model developed by Shikazono et al. [159] to explain the ongoing generation and downward migration of monosilicic acid from the weathering of multiple middle- to late-Holocene basaltic tephra layers that had accumulated layer by layer in central Japan. The coupling model was also invoked to help explain abundant halloysite formation at depth in thick accumulating Quaternary-aged siliceous tephras and derivatives in eastern North Island [131]. In the coupling model, rainwater migrates downwards through a glass-dominated tephra layer (in effect a ‘silica reservoir’) and reacts with the volcanic glass, which dissolves through hydrolysis, the dissolution products [Si] and [Al] then crystallizing together as halloysite. A new layer/reservoir of freshly-deposited glass (along with felsic and mafic minerals) at the land surface provides a new source of silica (and alumina, to a lesser degree) as the soil water moves down through it [159].
4. Classification
5. Caught in the Act: Seasonal Perched Gleying (Reduction) in the Kainui Soil
6. The Buried Soil on the Upper Hamilton Ash Beds
Micromorphology
7. Summary and Conclusions
- (1)
- Ultisols comprise a group of important soils with illuvial clay-enriched and moderately to strongly acid subsoils and generally low fertility on old land surfaces that have, nevertheless, been widely used globally and in northern New Zealand for productive agriculture and horticulture. The Kainui soil in the northern Hamilton lowlands and adjacent regions (in northern North Island) occurs on flattish summits, shoulders and backslopes on gently-rolling hills or terraces of an old, Mid-Quaternary paleo-landscape. It comprises a two-storeyed, tephra-derived Ultisol of Late Quaternary age with the upper part, a silt-rich coverbed c. 0.6 m in thickness on average, formed from multiple, thin, intermixed, mainly rhyolitic tephras ≤c. 50 ka, and a lower part comprising a buried clay-rich paleosol formed from much older, strongly weathered tephra (Hamilton Ash). Because the Kainui’s soil’s accumulating (composite) parent materials are diachronous, the age of the soil cannot be enunciated as a single number; rather, an age range is required.
- (2)
- Although much intermixing has occurred through developmental upbuilding pedogenesis (including via bioturbation), the upper part of the coverbed is inferred to comprise mainly post-20-ka tephras, numerous in number (c. 40 macroscopic beds) but relatively thin (mostly in the millimetre to centimetre range) as identified in sediments in lakes adjacent to the hills; the lower part consists chiefly of pre-20-ka tephras (in the centimetre to decimetre thickness range) including Okareka (c. 21.8 ka), Kawakawa (c. 25.4 ka), Okaia (c. 28.6 ka) (newly identified in this study), Tāhuna (c. 39.3 ka) and Rotoehu (c. 50 ka), the last easily the thickest (c. 25 cm thick) in the coverbed deposits (Figure 5). The age of the basal part of the coverbed (c. 50 ka) was derived using tephrochronology by characterising and identifying Rotoehu Ash largely via its diagnostic cummingtonite-rich ferromagnesian mineral assemblage.
- (3)
- The coverbed unconformably overlies the lower part, a buried clay-rich paleosol formed on strongly weathered clay-rich tephras (upper Hamilton Ash) containing relict argillans (clay skins) that probably formed in the Last Interglacial. The lower buried paleosol, >c. 50 ka in age, is otherwise not dated directly. An age of c. 125 ka (MOIS 5e) is inferred using climatostratigraphy from the physical and clay mineralogical properties of welded paleosols in the underlying c. 3-m-thick Hamilton Ash sequence together with the presence of the c. 0.5-m-thick, 340-ka Rangitawa Tephra, deposited late in MOIS 10, at the base of the sequence. The wavy to irregular surface on top of the buried paleosol represents a tree-overturn paleo-surface with an approximate minimum age estimated at c. 74 ka (the MOIS 5/4 boundary).
- (4)
- Both the upper and lower parts of the Kainui soil were formed by developmental upbuilding pedogenesis, providing an exemplar for this process (which is generally still not well represented in the global literature relating to soil genesis) and the key role of soil stratigraphy. The composite coverbed of tephras accumulated on the land surface at an average rate of just c. 1.2 mm/century, and each part of the ensuing soil has been an ‘A’ horizon (at the soil surface) as the land surface rose slowly. Detailed insight into the origin of the lower paleosol in Hamilton Ash is obscured by its strong alteration but this (now buried) soil is also the result of developmental upbuilding pedogenesis on the basis of micromorphological evidence for the closely related Naike soil on exhumed Hamilton Ash [17].The entire Hamilton Ash sequence below the Kainui soil represents a composite set of clayey, welded paleosols very probably developed by upbuilding pedogenesis from MOIS 10 to 5. The basal Rangitawa Tephra is underlain unconformably by a much older tephra-derived, extremely clay-rich, welded paleosol sequence on Kauroa Ash beds >c. 0.78 Ma in age.
- (5)
- The clay mineral assemblages of both upper and lower parts of the Kainui soil are dominated by halloysite of the kaolin subgroup. The formation of halloysite rather than allophane in the relatively ‘young’ (≤c. 50 ka) coverbed tephras (Figure 8A) is the result of limited desilication (consistent with the Si-leaching model) as a consequence of various factors including the presence of the slowly-permeable paleosol on Hamilton Ash at shallow depths ≤c. 0.8 m (slowing the downward movement of water and hence reducing the loss of Si in soil solution), the dominance of silica-rich rhyolitic tephras in the coverbed, not-infrequent soil moisture deficits extending over several months of the year, and the formation of much of the soil during MOIS 3 and 2 when rainfall was generally lower than today’s. The resultant soils are invariably Ultisols.
- (6)
- At sites in the southern Hamilton lowlands and further south in Waipa District where the greater accumulative thickness of the composite coverbed tephras (≤c. 50 ka) readily exceeds the c. 0.8 m threshold (Figure 1A), such as at Kakepuku Road (Figure 8B), the greater depth to the underlying paleosol on Hamilton Ash (at c. 1.5 m) provides more ‘room’ for sufficient desilication to enable Al-rich allophane, not halloysite, to form in the upper soil above c. 0.9 m depth (Figure 8B). Below 0.9 m or so, marked by the c. 25.4-ka Kawakawa Tephra, mainly halloysite with some allophane was formed during the time of tephra (and minor tephric loess) accretion during MOIS 3–2 [18]. The modern Otorohanga soil is therefore an Andisol (one of the oldest in the world, taking the entire profile, c. 1 to 2 m deep, into account) [110]. The synthesis of allophane in the southern locations is enhanced by a higher average rainfall (increasing throughflow in the soil) and by the greater relative proportion of Al-rich andesitic tephras intermixed with the nonetheless predominantly rhyolitic tephras that make up the composite soil parent materials.
- (7)
- The Kainui soil has been characterized previously as having an eluvial and illuvial couplet, namely a pale E horizon over a (translocated clay-enriched) Bt (argillic/kandic) horizon, forming a sequum. However, the soil stratigraphic evidence shows that the Bt horizon is a buried soil, hence is classed as a 2bBt horizon, with the upper boundary representing a lithologic discontinuity or unconformity. Therefore the sequum is illusory because the E and (2b)Bt horizons are (largely) not connected genetically and are some tens of thousands of years apart in age. Most if not all of the clay skins in the 2bBt horizon are relict. Hence, the designation of an E horizon may be morphologically correct but genetically less so; the compromise designation as an EBw horizon, as suggested by Clayden and Hewitt [46] in situations where a lithologic discontinuity occurs, is appropriate.
- (8)
- The revelation of contemporary perched gleying, forming an EBw(g) horizon in the lower part of the coverbed of the Kainui soil, in early spring after a wet winter at a favourable landscape position (Figure 9A), explains the ubiquitous occurrence of >2% redox segregations (mainly MnO2 concretions and mangans) in this juxtaposition in the Kainui soils. The relative abundance of low chroma colours is not quite sufficient for the gleyed horizon to qualify as having aquic conditions in ST (although such status would be expected to occur where the right conditions prevail).
- (9)
- The Kainui soil at Gordonton Road and similar sites qualifies as a Typic Kandiudult in ST and, uniquely, as a Buried-granular Yellow Ultic Soil in NZSC, being the only soil in this taxonomic category in New Zealand.
- (10)
- These conclusions above have arisen primarily through a multipronged approach based on synthesising tephrostratigraphy (of both subaerial/dryland and lacustrine deposits), tephrochronology (as a correlational and dating tool), pedology (including soil morphology, genesis and classification), paleopedology and soil stratigraphy, together with primary and secondary (clay) mineralogy. These tools have been essential in helping to elucidate the origin, age and classification of the special Kainui soil, as I hope has been demonstrated.
Funding
Acknowledgements
Conflicts of Interest
References
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Okaia Tephra | Tāhuna Tephra | ||||||
---|---|---|---|---|---|---|---|
Oxide or Element | L. Maratoto (Sample LM3, Figure 5) b | Scott Rd Reference Site No. 588 e | Reference Site f | L. Maratoto (Sample LM2, Figure 5) b | Reference Sites (Compilation) g | Scott Rd Reference Site No. 587 h | |
SiO2 | 77.87 | 77.57 | 77.50 | 78.38 | 77.60 | 77.56 | |
(0.99) | (0.21) | (0.34) | (0.24) | (0.21) | (0.18) | ||
Al2O3 | 12.26 | 12.55 | 12.42 | 12.36 | 12.29 | 12.57 | |
(0.26) | (0.11) | (0.21) | (0.11) | (0.13) | (0.10) | ||
TiO2 | 0.18 | 0.18 | 0.18 | 0.15 | 0.18 | 0.16 | |
(0.05) | (0.07) | (0.06) | (0.03) | (0.07) | (0.05) | ||
FeOt c | 1.25 | 1.31 | 1.29 | 1.09 | 1.10 | 1.04 | |
(0.28) | (0.08) | (0.10) | (0.08) | (0.09) | (0.09) | ||
MnO | na | 0.06 (0.03) | 0.04 (0.04) | na | 0.07 (0.04) | 0.07 (0.04) | |
MgO | 0.13 | 0.08 | 0.10 | 0.14 | 0.07 | 0.08 | |
(0.04) | (0.04) | (0.06) | (0.02) | (0.05) | (0.06) | ||
CaO | 1.09 | 1.17 | 1.20 | 1.12 | 0.99 | 0.97 | |
(0.13 | (0.06) | (0.09) | (0.10) | (0.07) | (0.05) | ||
Na2O | 3.54 | 3.81 | 3.90 | 3.35 | 3.48 | 3.56 | |
(0.29) | (0.13) | (0.14) | (0.21) | (0.16) | (0.11) | ||
K2O | 3.56 | 3.29 | 3.28 | 3.29 | 4.09 | 4.01 | |
(0.74) | (0.11) | (0.10) | (0.29) | (0.10) | (0.05) | ||
Cl | 0.12 | 0.20 | 0.19 | 0.12 | 0.14 | 0.19 | |
(0.05) | (0.02) | (0.02) | (0.02) | (0.03) | (0.02) | ||
H2O d | 3.07 | 7.70 | 5.99 | 2.37 | 5.36 | 4.02 | |
(2.10) | (1.89) | (2.36) | (1.98) | (1.61) | (1.79) | ||
n | 18 | 10 | 10 | 12 | 41 | 11 |
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Lowe, D.J. Using Soil Stratigraphy and Tephrochronology to Understand the Origin, Age, and Classification of a Unique Late Quaternary Tephra-Derived Ultisol in Aotearoa New Zealand. Quaternary 2019, 2, 9. https://doi.org/10.3390/quat2010009
Lowe DJ. Using Soil Stratigraphy and Tephrochronology to Understand the Origin, Age, and Classification of a Unique Late Quaternary Tephra-Derived Ultisol in Aotearoa New Zealand. Quaternary. 2019; 2(1):9. https://doi.org/10.3390/quat2010009
Chicago/Turabian StyleLowe, David J. 2019. "Using Soil Stratigraphy and Tephrochronology to Understand the Origin, Age, and Classification of a Unique Late Quaternary Tephra-Derived Ultisol in Aotearoa New Zealand" Quaternary 2, no. 1: 9. https://doi.org/10.3390/quat2010009
APA StyleLowe, D. J. (2019). Using Soil Stratigraphy and Tephrochronology to Understand the Origin, Age, and Classification of a Unique Late Quaternary Tephra-Derived Ultisol in Aotearoa New Zealand. Quaternary, 2(1), 9. https://doi.org/10.3390/quat2010009