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Moisture Absorption of Carbon/Epoxy Nanocomposites

School of Aerospace and Mechanical Engineering, University of Oklahoma, Norman, OK 73019, USA
Author to whom correspondence should be addressed.
J. Compos. Sci. 2020, 4(1), 21;
Received: 12 January 2020 / Revised: 11 February 2020 / Accepted: 18 February 2020 / Published: 20 February 2020
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2019)
Moisture absorption of composites with nanoscale carbon additives such as carbon nanotubes, carbon nanofibers, graphite nanoplatelets, and carbon black is investigated using thermogravimetric data and a non-Fickian hindered diffusion (Langmuir-type) model. The moisture absorption parameters are determined using this model for six different types of carbon/epoxy nanocomposites. The absorption behaviors obtained at different humidity levels and thermal environments are recovered by minimizing the error between the experimental data and model predictions, thus enabling the accurate determination of the moisture equilibrium level. The absorption behavior and the weight gain of all nanocomposites are shown to be accurately represented by this model over the entire absorption period. The presence of carbon nanomaterials is found to induce varying levels of non-Fickian behavior, governed by the nondimensional hindrance coefficient. This behavior is enhanced with the nanomaterial content and separate from the slight non-Fickian behavior of all neat epoxy samples. The molecular bonding during diffusion, as well as the interfacial moisture storage, could be among the reasons for non-Fickian behavior and should be included in the absorption models for accurate characterization of carbon/epoxy nanocomposites. View Full-Text
Keywords: hindered diffusion model; moisture absorption; thermosetting composites; nanocomposites hindered diffusion model; moisture absorption; thermosetting composites; nanocomposites
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MDPI and ACS Style

Guloglu, G.E.; Altan, M.C. Moisture Absorption of Carbon/Epoxy Nanocomposites. J. Compos. Sci. 2020, 4, 21.

AMA Style

Guloglu GE, Altan MC. Moisture Absorption of Carbon/Epoxy Nanocomposites. Journal of Composites Science. 2020; 4(1):21.

Chicago/Turabian Style

Guloglu, Gorkem E., and M. Cengiz Altan. 2020. "Moisture Absorption of Carbon/Epoxy Nanocomposites" Journal of Composites Science 4, no. 1: 21.

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