Next Article in Journal
Surface Aware Triboinformatics Framework for Wear Prediction of MWCNT Reinforced Epoxy Composites Using Run-Wise AFM Descriptors and Machine Learning
Previous Article in Journal
Use of Steel Industry Waste in Mortars for Application in Buildings: A Sustainable Alternative Analyzed by Microstructural, Chemical, and Mechanical Characterization
Previous Article in Special Issue
Impact of Recycled Rubber Mesh Size and Volume Fraction on Dynamic Mechanical and Fracture Characteristics of Polyester/Fiberglass Composites
 
 
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Increased Interlaminar Fracture Toughening Through Distinct Fiber Bridging Effect of rCF Staple Fiber Yarn Composite

by
Christian Becker
*,
Joachim Hausmann
* and
Nicole Motsch-Eichmann
Leibniz-Institut für Verbundwerkstoffe GmbH, 67663 Kaiserslautern, Germany
*
Authors to whom correspondence should be addressed.
J. Compos. Sci. 2026, 10(2), 112; https://doi.org/10.3390/jcs10020112
Submission received: 8 January 2026 / Revised: 16 February 2026 / Accepted: 19 February 2026 / Published: 21 February 2026
(This article belongs to the Special Issue Research on Recycling Methods or Reuse of Composite Materials)

Abstract

This study investigates the influence of fiber bridging on the interlaminar strength of carbon fiber-reinforced polymer (CFRP) made from recycled carbon staple fiber yarn (rCF), compared to CFRP made from new fibers (vCF). Double-cantilever beam (DCB) tests measure the resistance of both materials against crack formation and the corresponding energy release rate (ERR). Several microscopic tools (SEM, CT) were then used to analyze the fracture surfaces and characterize the underlying failure mechanisms of the fiber bridges. The resulting ERR of rCFRP is four times (2140 J/m2 compared to 587 J/m2) higher than that of vCFRP. SEM images of the fracture surface reveal that the fracture mechanism is fiber debonding followed by fiber pull-out with constant friction. This finding is confirmed by calculating the fiber bridging stress using the mathematical formulation of this effect resulting in a fiber bridge tension of approximately 70 N/mm2. The main reason for the increased ERR of rCFRP compared to vCFRP is the extensive occurrence of fiber bridges in rCFRP due to the inhomogeneity of the rCF roving. This results in a pronounced nesting effect between adjacent rCF layers. The influence of the nesting effect on the ERR was investigated by testing samples with an increased layer orientation difference of 3° and 5°. This results in an ERR decrease of 26% in rCF and 30% in vCF. The nesting effect can be eliminated in vCFRP, but in rCFRP higher layer orientation, nesting is still visible. This finding suggests that the coarse, inhomogeneous structure of the rCFRP roving causes nesting regardless of the layer orientation and leads to a pronounced tendency to form fiber bridges.

1. Introduction

Recycling composites plays an increasingly important role in today’s world. In the aviation sector, for example, the growing importance of lightweight construction for reducing operation costs has led to an increased use of composites. With an increasing number of aircrafts reaching the end of their service life, it has become vital to find ways to reuse or recycle components. The main drivers of this necessity are political regulations concerning the recyclability of components and the use of recycled materials in new products. At the same time, there are increasingly better and more efficient recycling methods and technologies. This also results in an ongoing decline in the prices of recycled materials [1,2,3,4]. Nevertheless, the effort to recycle composite materials (rCFRP) and the missing infrastructure and supply chain, or the lack of demand for recycled materials, still remains high. This leads to higher prices compared to new materials. At the same time, recycled fibers (rCF) are only profitable if they are used in load-bearing structures again, to regain their mechanical potential [5,6,7,8,9,10]. Therefore, the question arises as to how recycled fibers can offer benefits when used in technical applications compared to new fibers, despite the high cost and limited availability of recycled fibers. To answer this question, it is important to develop not only recycling methods and new semi-finished products made from rCF, but also manufacturing processes, as well as characterizing the mechanical properties and analyzing the mechanical behavior.
A new manufacturing method for rCF-PA6 tapes from rCF staple fiber yarns is presented in [11]. In addition to the advantages of using continuous tapes due to the highly aligned rCF fibers and the use of established manufacturing processes for further processing, the mechanical characteristics are also investigated. The stiffness of the rCF PA6 tape was up to 85% that of the reference material made from new fibers. In terms of strength, however, it is only 50% of that of new fibers, which is probably due to the poor fiber–matrix interface (mainly fiber pullout visible).
Similar results are achieved in [12]. The production of plate material with a fiber volume content of 45–50% is achieved through the processing of rCF staple fiber yarns (micro-section in Figure 1a) using a winding process. Mechanical tests (tensile, compressive and flexure) achieve yielded stiffness values of up to 110 GPa and strengths of up to 800 MPa. These values represent up to 75% of those of plates made from new carbon fibers. The only major issue is again the lack of strength at the fiber–matrix interface (fiber pullout at fracture surface visible). Another interesting result of this study is that the inhomogeneity of the rCF staple fiber yarn, caused by undulations, misaligned fibers and roving structure (particularly thickness) leads to increased fiber bridging in the crack zone. This is demonstrated in in situ X-ray microscopy experiments, in which fiber bridging in the crack tip is investigated during transverse tensile testing (see Figure 1b).
Fiber bridging is an intrinsic property of FRP materials caused by delamination due to defects or impact damage, for example [13,14,15]. The occurrence of fiber bridging is influenced by various factors:
  • Geometric specifications (e.g., thickness of part) [16];
  • Load conditions (quasi-static or fatigue);
  • Fiber orientation at delamination interface—fiber orientation can cause nesting of adjacent layers especially in unidirectional (UD) laminates (Figure 2b) [17];
  • Material structure and quality (e.g., weak interfaces, larger fiber volume fraction, toughness of resin) [18,19,20];
  • Processing parameters (e.g., cooling rate, pressure).
To provide a general description of delamination behavior, fiber bridging must be considered as an interlaminar strengthening mechanism [14]. This can be illustrated using the resistance curve (R-curve), which can be obtained from a DCB (double cantilever beam) test [21,22]. An increased number of bridging fibers in the crack zone leads to an increase in the GIC value during crack opening; conversely, a low number of bridging fibers results in a constant GIC value over the crack opening. This effect is illustrated in Figure 2a.
Figure 2. Resistance curve from DCB tests with comparison of high and low fiber bridging effect (a) [22]; “Nesting-Effect” in unidirectional FRP materials (b) [17].
Figure 2. Resistance curve from DCB tests with comparison of high and low fiber bridging effect (a) [22]; “Nesting-Effect” in unidirectional FRP materials (b) [17].
Jcs 10 00112 g002
Taking into account the interlaminar strength of components at increased risk of delamination failure due to impact loading, for example, is a well-known problem in the design of such structures [23,24]. The simplest solutions, such as adjusting layer orientation and increasing thickness, are often not feasible for cost or design reasons (the main fiber orientation must be aligned with the main load direction). Other methods such as stitching the layers together or pinning (piercing and connecting the layers with metal or plastic pins) significantly increase interlaminar strength [25,26]. However, this also disrupts the fiber orientation in the material, creating additional resin-rich areas that can reduce in-plane strength [27]. The interlaminar strength enhancement achieved through fiber bridges, coupled with the comparatively minimal reduction in strength and stiffness of rCFRP made from staple fiber yarn compared to new fiber material, raises the question of whether the pronounced fiber bridging of rCF staple fiber yarn also increases the interlaminar strength of rCF sheet material.
This study investigates the interlaminar strength of rCFRP made from recycled staple fiber yarn in comparison to reference samples made from newly produced fibers (vCF). The focus of this work is on the formation of fiber bridges and the initiation and propagation of the crack front, as well as the failure of the fiber bridges in the crack front. To this end, DCB tests were performed to determine the G1C values, and further microscopic analysis was conducted on the fracture surfaces. Additionally, the influence of the “Nesting-effect” on the formation of fiber bridges is discussed.

2. Materials and Methods

The test specimens were produced by processing various materials into sheet material using a winding process (Figure 3). The rCF staple fiber yarn (Wagenfelder Spinnereien GmbH, Wagenfeld, Germany) used consists of 60–80 mm long rCF single fibers, which were mixed with PA6 filaments of the same length in a ratio of 90 to 10 (rCF to PA6). In addition, the yarn was wrapped with a PA6 wrapping yarn to give the yarn additional stability. The exact combinations, information on the manufacturing process, and the resulting sample labeling are illustrated in Table 1. In all variants, a PTFE film was inserted between half of the layers (Figure 3). This film later served to separate the layers and initiate cracking (25 mm pre-crack length). The target plate thickness is 3 mm in each case. Plates with different layer orientations (LO) were produced to characterize the effect of nesting. The panels were then packed in a vacuum bag and cured in an autoclave at 140 °C with 4 bar pressure for 8 h.
Table 1. Material combinations, processing route and sample lay-up used in this work.
Table 1. Material combinations, processing route and sample lay-up used in this work.
Sample NameFiber
Material
Matrix MaterialProcessingFiber Volume ContentLayer orientation (LO)
rCF-EP-“LO”rCF staple fiber roving (Wagenfelder Spinnereien GmbH, Wagenfeld, Germany) [28]Huntsman Epoxy (100:90:2)
Araldite LY 1135-1
Araldur 917
Fastener 960-1
(Huntsman Corporation, The Woodlands, TX 77380, USA)
Wet winding
Autoclave
45%[0 °]6
[+3°/−3°]3
[+5°/−5°]3
vCF-EP-“LO”TenaxTM Filament Yarn ITS55
(Teijin Carbon Europe GmbH, Wuppertal, Germany)
Huntsman Epoxy (100:90:2)
Araldite LY 1135-1
Araldur 917
Fastener 960-1
Wet winding
Autoclave
46%[0 °]6
[+3°/−3°]3
[+5°/−5°]3
Test specimens measuring 250 × 25 mm (length l × width b) are cut from the manufactured plates in accordance with DIN EN 6033 [29]. The specimens are tested on an electro-mechanical testing machine (Zwick 1485 from ZwickRoell GmbH & Co. KG, Wuppertal, Germany with a 10 kN load cell) at a speed of 5 mm/min until the crack propagates to a length of 100 mm. Crack propagation was observed using a marking on the edge surface (see Figure 6) and additionally tracked by an optical measuring system (GOM Aramis 4M, Carl Zeiss IQS Deutschland GmbH, Oberkochen, Germany). The camera system can also be used to record fiber bridging effects during measurement. By recording the force-time diagram and correlating it with the crack progression, a force-displacement diagram can be created. This diagram can then be used to calculate the energy release rate (ERR) by defining the area below the measurement curve. The setup, sample geometry and calculation method are visualized in Figure 4.
The work focuses on describing the formation of the fiber bridges and analyzing their mechanical behavior at the crack front and the underlying failure behavior, such as fiber breakage and pull-out. Therefore the tested samples are examined in detail with microscopy techniques. First, the fracture surfaces were examined using scanning electron microscopy (SEM) (ZEISS SUPRA 40VP, Carl Zeiss IQS Deutschland GmbH, Oberkochen, Germany) to determine possible failure mechanisms. Additionally, X-ray microscopy analyses (μCT) were performed using a ZEISS Xradia 520 Versa (Carl Zeiss IQS Deutschland GmbH, Oberkochen, Germany) to determine fiber orientation, crack fronts, and layer structures. This method can also be used to visualize fiber bridging.

3. Results and Discussion

First, the DCB rCF-EP-0° and vCF-EP-0° samples were tested. Figure 5 shows the resulting load–displacement curves. The energy release rate (ERR) can be calculated using Equation (1). To do this, the area A below the measurement curve is determined using the trapezoidal rule. The sample width w was measured in advance. The crack propagation length a can be determined by optical measurement of the test.
E R R = A a × w × 10 6
For the tests of the 0° samples, the ERR of the rCF-EP-0° at 2519 J/m2 is four times greater than that of the vCF-EP-0° at 587 J/m2. Examining Figure 6 and the force-displacement diagram (Figure 5) reveals several factors that account for the differences in ERR:
  • Crack-bridging fibers can be seen in both vCF-EP-0° and rCF-EP-0°. However, in rCF-EP-0°, entire roving bundles and PA6 filaments can be seen bridging the crack surfaces.
  • The crack opening angle between the two materials differs greatly. Figure 6 shows that the opening angles are 15° for rCF and 10° for vCF at a crack length of 60 mm. With rCF-EP-0°, significantly higher bending/cracking forces are required to open the crack. This may indicate a pronounced effect of greater fiber bridging stress/numbers.
  • To achieve a crack propagation of 100 mm, the cross head displacement must be approximately 100% longer for rCF.
Figure 5. Force–displacement diagram from DCB test of rCF-EP-0° (a) and vCF-EP-0° (b).
Figure 5. Force–displacement diagram from DCB test of rCF-EP-0° (a) and vCF-EP-0° (b).
Jcs 10 00112 g005
Figure 6. Images of the crack propagation captured during DCB tests showing fiber bridging effects of (a) single fibers, PA6 filaments and roving bundles in rCF-EP-0° and (b) fiber bridging in vCF-EP-0°.
Figure 6. Images of the crack propagation captured during DCB tests showing fiber bridging effects of (a) single fibers, PA6 filaments and roving bundles in rCF-EP-0° and (b) fiber bridging in vCF-EP-0°.
Jcs 10 00112 g006
As can be seen from Figure 7a, the nesting effect described above is particularly noticeable in the rCF-EP-0° samples when the fracture surfaces of the two materials are examined. To measure the real fracture surface, CT scans were carried out (Figure 7b). With a length of 29.43 mm measured over the width of the fracture surface, the rCF-EP-0° samples are approximately 18% larger than that of the vCF-EP-0° samples. When the ERR is recalculated based on this higher surface area, the value is reduced to 2139 J/m2 (minus 379 J/m2). The value remains approximately 3.5 times higher than that of vCF. This may indicate that fiber bridging has a higher influence on the interlaminar strength of rCF than the nesting effect.
To assess this, SEM images of the fracture surface are taken. To this end, a gold-palladium layer was sputter-coated (Sputter coater; Brand: Balzer) onto the surfaces of the test specimen halves. Figure 8 shows that a large number of fiber tunnels are visible on the fracture surfaces, which are caused by individual fibers of the rCF and PA6 filaments being pulled out. However, free ends of complete rCF roving structures can also be seen on the right-hand side of Figure 8. The SEM image and the optical images during the test confirms the assumption that fiber bridges form both through the rCF fiber and through PA6 filaments and entire rCF roving. This extensive fiber bridging increases interlaminar strength and thus improves the ERR.
The SEM images also illustrate the underlying failure mechanism in the Mode 1 test. Examining the exposed fibers reveals no visible matrix residues. This is consistent with the findings in the previous work [12] that there are no binding forces between the fiber and the matrix (i.e., poor fiber-matrix adhesion), which is due to insufficient or inactive sizing on the rCF fiber. This means that the dominant failure mechanism during crack propagation is fiber pull-out and debonding with friction between the fibers and the matrix. Poor fiber-matrix interphase was also detected in the vCF-EP samples (see Appendix A and Figure A1). The main effect here was the detachment of fibers within the interface. Fiber tunnels were also detected in isolated cases. This also confirms the visible occurrence of fiber bridges. Since both materials are subject to the same failure mechanisms, the DCB test results are comparable.
The force–displacement curves of the DCB tests of the rCF-EP-0° exhibit the classic step-shaped progression. By comparing this curve with the findings from the SEM images, we can conclude that the drop in force is related to overcoming friction forces between the fiber and the matrix due to poor fiber-matrix adhesion. Therefore, the drop in force can be correlated with failure pattern (fiber debonding followed by fiber pull-out).
In [30], various mathematical approaches have been proposed to describe fiber bridging and the resulting fiber bridge stress during delamination of layered structures. These approaches include the mathematical description of deboning with coulomb friction, which is the main effect in this work. The fiber bridge stress σ f can be calculated using Equations (2) and (3).
σ f = 1 ρ ρ × 1 c 1 c 3 × E M φ c R f σ r b 1 × 1 e
= 2 μ b 1 z R f
Based on the test results and microscopic images obtained, it can be concluded that debonding with constant friction in the fiber-matrix interface occurs in the rCF-EP samples. This is confirmed by the SEM images, which show no fiber-matrix bond and fiber pull-out channels with no visible fiber breaks, as well as by the force-displacement diagrams. After reaching the maximum force required to initiate crack growth, step formation with the development of constant force plateaus can be observed here. This indicates that, once a defined force threshold (i.e., the friction force between the fiber and the matrix) is exceeded, pure fiber pull-out (i.e., an increase in crack propagation length) initially occurs at a constant force with no friction effects between the fiber and the matrix.
Calculating the fiber bridging stress using Equations (2) and (3) (see the Appendix B for derivation and characteristic values) gives a stress of approx. 70.63 N/mm2. This gives a fiber bridging force of approximately 41 N (the fiber bridge stress projected onto the theoretical fracture surface, where the fracture surface corresponds to the fiber diameter multiplied by the fiber pull-out length). Subtracting this value from the force values measured in the Mode 1 test provides an approximation of the curve from the VCF-EP-0° tests (Figure 9). It should be noted, however, that changes in the path length required to achieve 100 mm crack propagation cannot be taken into account. Therefore, it is not possible to calculate the ERR backwards without fiber bridging stress. Nevertheless, this theoretical calculation of fiber bridging stress shows that the deviations in the force-displacement diagram and in the ERR between rCF and vCF are caused by fiber bridging.
To assess the effect of nesting on ERR, samples with layer differences of 3° and 5° were tested. In [17], the impact of nesting on fiber bridging is investigated, with a particular focus on the influence of fiber intermingling due to nesting. It was also demonstrated that an orientation difference of more than 1.5° or 3° between adjacent layers reduces the effect of nesting. Figure 10a,b shows the reduction in crack width at 3° and 5°, compared to 29.42 mm at 0° (based on a CT scan and measurement of the crack width). Between 0° and 3°, the reduction in crack width is 1.5 mm. Between 3° and 5°, however, the reduction is only approximately 0.05 mm. Due to the coarse structure and inhomogeneity of the rCF roving, it can be assumed that the nesting effect cannot be completely eliminated, as the difference in fiber angles between adjacent layers increases. The coarse roving structure always allows nesting of the layers among themselves. Micrographs of a 0/90 fabric made of rCF roving confirm this assumption (see Appendix C: Figure A2 and Figure A3).
Figure 11 and Table 2 show the influence of nesting on the ERR compared to the 0° samples. As can be seen, there is a sharp drop in the ERR of 450 J/m2 to approx. 1700 J/m2 with rCF between 0° and 3°. Between 3° and 5°, there is only a drop of 120 J/m2 to 1570 J/m2. This is primarily due to the sharp decrease in crack surface width at a fiber orientation difference of 0° to 3° between the layers.
As the difference between the layer orientations increases, the rCF roving can no longer press as strongly into the “valleys” of the layer below. Consequently, fewer fiber bridges are formed within these “valleys”; instead, fiber bridge formation is mainly reduced to the boundary between the layers (see Figure 10c).
In vCF samples with increased fiber orientation differences between layers, a 160 J/m2 decrease in ERR is noticeable between 0° and 3°. The nesting effect is not visible microscopically at 0° in the vCF samples because only individual fibers can nest, unlike the entire roving structure seen in rCF. However, this effect is significantly minimized at a layer difference of 3°. The increase in ERR in the vCF-EP-5° samples is due to an increased plate thickness of 3.3 mm, which is greater than the 3 mm thickness of the vCF samples. The resulting increase in bending stiffness leads to a higher force required to initiate crack growth. This is supported by Farmand-Ashtiani [31], who demonstrated the effect that sample thickness has on ERR. As can be seen, greater sample thickness leads to higher ERR. Therefore, uniform sample thickness is crucial for comparability. Therefore, the vCF-EP-5° test is only of limited significance.
In the vCF samples, when we compare the ERR of rCF and vCF at 0°, 3°, and 5° with each other, it is evident that approximately four times more energy is required to achieve layer separation in the rCF material, regardless of nesting. This suggests that the coarse, inhomogeneous structure of the rCF roving promotes fiber bridging within and between layers of the laminate, thereby increasing interlaminar strength. However, in this context, it should be noted that the energy distribution across the increased crack surface is not uniform. Nesting increases surface roughness, resulting in higher ERR in localized areas compared to “flat” areas. At the same time, as described above, there is greater formation of fiber bridges in the area of the interlocked fiber bundles (see Figure 10c). Since these local effects are difficult to measure experimentally, the energy distribution is simplified and assumed to be uniform across the entire crack surface. Locally, the ERR is therefore overestimated or underestimated relative to the determined value.

4. Conclusions

This study examined the interlaminar failure behavior of rCFRP made from staple fiber yarn, comparing it to new and continuous fibers with an identical matrix system. The study focused on the significant impact of fiber bridging in rCFRP due to the roving’s coarse and inhomogeneous structure. To this end, unidirectional plates were produced using the wet winding process with rCF staple fiber roving (quasi-continuous reinforcement) and new fiber roving (continuous reinforcement). The energy release rate of the materials was determined through G1C testing according to DIN 6033. The rCF material (2519 J/m2) has an ERR that is more than four times higher than that of the vCF material (587 J/m2) due to the higher amount of fiber bridging. This was also demonstrated by Russo [22], who investigated the impact of a high or low fiber bridging on the ERR using both experimental and analytical methods on an epoxy resin/carbon fiber composite. He also observed a factor of three between the ERR values of low and high fiber bridging. A notable feature of the rCF material is the nesting effect between the layers, which increases the effective fracture area. Taking the increased fracture area into account the ERR reduces for rCFRP to 2139 J/m2. The increase in ERR is due to the formation of fiber bridges between the layers. Not only individual fibers, but also entire roving bundles bridge the cracks. SEM images show that, locally, PA6 filaments (components of the rCF roving), as well as entire roving bundles, bridge the cracks. This significantly increases the interlaminar strength of the rCFRP.
The SEM images also allow us to draw conclusions about the underlying failure behavior at the crack front and at the fiber bridges. As previously determined, the bond between the fibers and the matrix in both rCFRP and vCFRP is minimal or absent due to inadequate or deactivated fiber sizing. This is evidenced by exposed fiber ends with no visible matrix adhesion. SEM images clearly show fiber channels (detached fibers), fiber tunnels (fibers pulled out of the matrix), and gaps between the matrix and embedded fibers. These results, coupled with the lack of visible fiber fractures in the images, lead to the conclusion that the main failure mechanism at the crack front is fiber debonding, followed by fiber pull-out, with constant friction between the fiber and the matrix. Analytical calculations of fiber bridge stress confirm this.
Not only does the nesting of the roving bundles in rCFRP lead to a larger fracture surface, but it also ensures the formation of fiber bridges between the layers (interlaminar) and between the branched roving bundles (intralaminar). Therefore, this significantly increases ERR compared to new fiber material, where fiber bridging only occurs interlaminar and is limited to specific areas.
To investigate the effect of nesting on ERR, additional DCB tests were performed on samples with different layer orientations (3° and 5° differences in layer orientation). As can be seen here, there is a decrease in ERR for both rCF and vCF. Notably, there is a significant decrease in ERR between the 0° and 3° orientations to 1640 J/m2 for rCF. Nevertheless, the ERR of rCFRP is significantly higher than that of vCFRP due to rCFRP’s coarse roving structure. Because of this structure, the fibers can nest into each other even with larger layer orientations (nesting continues to occur), resulting in pronounced fiber bridging. This effect decreases in vCFRP as the difference in layer orientation increases. The results for the rCF and vCF samples are similar to those reported by Johnson [17]. He also demonstrated that changing the position from 0° to 3° significantly decreases the ERR (from 1000 J/m2 to 650 J/m2). It also became apparent here that nesting is no longer evident.
In summary, rCFRP made from staple fiber roving exhibits significantly higher interlaminar strength than comparable materials made from new fibers. However, previous studies have shown that the in-plane properties (stiffness and strength) are only about 70% of those of virgin fiber materials despite the insufficient fiber-matrix interphase [11,12]. This could be a potential application area for rCF roving in structural components. Using an intermediate layer of rCFRP could increase a component’s interlaminar properties without requiring targeted interlaminar reinforcement through stitching or Z-pins during manufacturing. However, stitching or pinning can reduce the in-plane properties of a component by interrupting fiber orientation due to deflection or interruptions of the fibers. This effect could potentially be mitigated with an rCFRP intermediate layer because the formation of fiber bridges at the roving ends does not influence the main orientation of the fibers. Experiments on this topic are currently being conducted to expand the range of applications for rCF and integrate the material into load-bearing components in a mechanically and cost-efficient manner.

Author Contributions

Conceptualization, C.B.; methodology, C.B.; formal analysis, C.B.; investigation, C.B.; writing—original draft preparation, C.B.; writing—review and editing, J.H. and N.M.-E.; visualization, C.B.; supervision, J.H. and N.M.-E.; All authors have read and agreed to the published version of the manuscript.

Funding

This study has been conducted within the framework of the research project “LuFo-Hestia: Sustainable thermoplastic window frame concept made from overmoulded rCF tape inserts—construction method and structure optimization, material and process development” funded by the Federal Ministry for Economic Affairs and Climate Action on the basis of a decision by the German Bundestag. The project is being carried out in cooperation with Airbus Operations GmbH, Deutsches Zentrum für Luft-und Raumfahrt e.V., Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung, Airbus Aerostructures GmbH and Albany International. Funding reference: 20W2203E.

Informed Consent Statement

Not applicable.

Data Availability Statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

The author would like to thank Torsten Weick for his assistance in sample preparation and Marc Hein for his assistance with SEM analyses. During the preparation of this manuscript, the author used DeepL Write for the purposes of improving the writing style. The authors have reviewed and edited the output and take full responsibility for the content of this publication.

Conflicts of Interest

Christian Becker, Joachim Hausmann, and Nicole Motsch-Eichmann were employed by “Leibniz-Institut für Verbundwerkstoffe GmbH”. The remaining authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

Abbreviations

The following abbreviations are used in this manuscript:
rCFRecycled carbon fiber
rCFRPRecycled carbon fiber reinforced plastic
vCFNewly produced carbon fibers
vCFRPCarbon fiber reinforced plastic from newly produced carbon fibers
SEMScanning electron microscopy
LOLayer orientation
FVFFiber volume fraction
ERREnergy release rate
DCBDouble cantilever beam
PTFEPolytetrafluoroethylene
UDUnidirectional
CTComputer tomography

Appendix A

Figure A1 shows the scanning electron microscope (SEM) characterization of a vCF fracture surface, which supplements the SEM images of the rCF sample. The SEM images of the vCF sample reveal similar failure mechanisms to those observed in the rCF samples. Visible features include fiber pull-outs, fiber detachments, and exposed fiber segments without matrix adhesion. Therefore, the results of the DCB tests for both material combinations can be compared.
Figure A1. SEM images of the fracture zone of vCF-EP-0° sample with visible fiber tunnels of pulled out vCF fibers, fiber channels of debonded vCF fibers and exposed fiber segments.
Figure A1. SEM images of the fracture zone of vCF-EP-0° sample with visible fiber tunnels of pulled out vCF fibers, fiber channels of debonded vCF fibers and exposed fiber segments.
Jcs 10 00112 g0a1

Appendix B

This sections shortly explains the analytical calculation of the fiber bridging stress in the rCF-EP-0° material. As explained in chapter “Results and Discussion” the formulation focus on the fracture mechanism of deboning with coulomb friction, which was mathematically derived in [30]. The derived equation for fiber bridging stress is:
σ f = 1 ρ ρ × 1 c 1 c 3 × E M φ c R f σ r b 1 × 1 e
with   = 2 μ b 1 z R f
and   c 1 = [ 1 ν 2 ( 1 ρ ) ] 1 / 2 2 ρ ; c 3 = 1 ;   b 1 = 1 2 ν
The following table shows the variables and their definitions. The required characteristic values are derived from single fiber pull-out (SFPO) tests of an rCF fiber from a drop of the used matrix system. More detailed information on these tests is available from the author upon request.
Table A1. Variables used for calculating fiber bridging stress with Equation (2).
Table A1. Variables used for calculating fiber bridging stress with Equation (2).
DefinitionVariableValueUnit
Fracture surface of fiberρ0.0000385mm2
Radius of fiber =
1/2 fiber diameter
Rf0.0035000mm
Modulus fiberEf230,000.00N/mm2
Modulus matrixEm2700.00N/mm2
Radial component of stress at interphaseσT0.00000770N/mm2
Frictional shear stressμ5.13N/mm2
Transverse ratio of isotropic fiberξ3.02
Fiber pull-out length;
Fracture surface fiber/matrix
z0.02mm
Poisons ratio (with vf = vm)ν0.23
GICφc2.10N/mm

Appendix C

In this paragraph the effect of nesting in composites with a high orientation difference in adjacent layers is discussed additionally. More specifically, it concerns the effect of nesting in rCF roving in a 0/90° layer structure. In vCFRP the effect of nesting is eliminated by a LO higher than [+3°/−3°]. In rCFRP the effect of nesting is still visible even in 0/90° layer structure because of the coarse, inhomogeneous structure of the rCFRP roving. In the processing, gaps/valleys between rovings in one UD layer were formed. This structure ensures that subsequent layers have the opportunity to press into these valleys during consolidation.
Figure A2. Micro section of rCFRP with [0/90/90/0]s structure from rCF roving.
Figure A2. Micro section of rCFRP with [0/90/90/0]s structure from rCF roving.
Jcs 10 00112 g0a2
Figure A3. Graphical representation of the nesting effect in rCFRP with 0/90° layers.
Figure A3. Graphical representation of the nesting effect in rCFRP with 0/90° layers.
Jcs 10 00112 g0a3

References

  1. Kaufmann, M.; Zenkert, D.; Wennhage, P. Integrated cost/weight optimization of aircraft structures. Struct. Multidiscip. Optim. 2010, 41, 325–334. [Google Scholar] [CrossRef]
  2. Scheelhaase, J.; Müller, L.; Ennen, D.; Grimme, W. Economic and Environmental Aspects of Aircraft Recycling. Transp. Res. Procedia 2022, 65, 3–12. [Google Scholar] [CrossRef]
  3. Wong, K.; Rudd, C.; Pickering, S.; Liu, X. Composites recycling solutions for the aviation industry. Sci. China Technol. Sci. 2017, 60, 1291–1300. [Google Scholar] [CrossRef]
  4. Asmatulu, E.; Twomey, J.; Overcash, M. Recycling of fiber-reinforced composites and direct structural composite recycling concept. J. Compos. Mater. 2014, 48, 593–608. [Google Scholar] [CrossRef]
  5. Hengstermann, M.; Hasan, M.M.B.; Scheffler, C.; Abdkader, A.; Cherif, C. Development of a new hybrid yarn construction from recycled carbon fibres for high-performance composites. Part III: Influence of sizing on textile processing and composite properties. J. Thermoplast. Compos. Mater. 2021, 34, 409–430. [Google Scholar] [CrossRef]
  6. Goergen, C.; Schommer, D.; Duhovic, M.; Mitschang, P. Deep drawing of organic sheets made of hybrid recycled carbon and thermoplastic polyamide 6 staple fiber yarns. J. Thermoplast. Compos. Mater. 2020, 33, 754–778. [Google Scholar] [CrossRef]
  7. Goergen, C. Quasiplastisches Verformungsverhalten Von Organoblechen Aus Recycelten Kohlenstoff-Stapelfasergarnen; Institut für Verbundwerkstoffe GmbH: Kaiserslautern, Germany, 2020. [Google Scholar]
  8. Barnett, P.R.; Ghossein, H.K. A Review of Recent Developments in Composites Made of Recycled Carbon Fiber Textiles. Textiles 2021, 1, 433–465. [Google Scholar] [CrossRef]
  9. Isa, A.; Nosbi, N.; Ismail, M.C.; Akil, H.M.; Ali, W.F.F.W.; Omar, M.F. A Review on Recycling of Carbon Fibres: Methods to Reinforce and Expected Fibre Composite Degradations. Materials 2022, 15, 4991. [Google Scholar] [CrossRef]
  10. May, D.; Goergen, C.; Friedrich, K. Multifunctionality of polymer composites based on recycled carbon fibers: A review. Adv. Ind. Eng. Polym. Res. 2021, 4, 70–81. [Google Scholar] [CrossRef]
  11. Detzel, M.; Mitschang, P.; Breuer, U. New Approach for Processing Recycled Carbon Staple Fiber Yarns into Unidirectionally Reinforced Recycled Carbon Staple Fiber Tape. Polymers 2023, 15, 4575. [Google Scholar] [CrossRef]
  12. Becker, C.; Motsch-Eichmann, N.; Hausmann, J. Analysis of the mechanical and fracture behaviour of recycled carbon ataple fiber yarn under static load. In Proceedings of the 20th European Conference on Composite Materials—Composites Meet Sustainability, Lausanne, Switzerland, 26–30 June 2022; Volume 1–6, pp. 245–252. [Google Scholar]
  13. Manshadi, B.D.; Farmand-Ashtiani, E.; Botsis, J.; Vassilopoulos, A.P. An iterative analytical/experimental study of bridging in delamination of the double cantilever beam specimen. Compos. Part A Appl. Sci. Manuf. 2014, 61, 43–50. [Google Scholar] [CrossRef]
  14. Khan, R. Fiber bridging in composite laminates: A literature review. Compos. Struct. 2019, 229, 111418. [Google Scholar] [CrossRef]
  15. Gur, H.B.; Banks-Sills, L. Evaluation of the effect of fiber bridging on mode I quasi-static testing. Fatigue Fract. Eng. Mat. Struct. 2023, 46, 1357–1374. [Google Scholar] [CrossRef]
  16. Frossard, G.; Cugnoni, J.; Gmür, T.; Botsis, J. Mode I interlaminar fracture of carbon epoxy laminates: Effects of ply thickness. Compos. Part A Appl. Sci. Manuf. 2016, 91, 1–8. [Google Scholar] [CrossRef]
  17. Johnson, W.S.; Mangalgiri, P.D. Investigation of Fiber Bridging in Double Cantilever Beam Specimens. J. Compos. Technol. Res. 1987, 9, 10. [Google Scholar] [CrossRef]
  18. Sakai, M.; Miyajima, T.; Inagaki, M. Fracture toughness and fiber bridging of carbon fiber reinforced carbon composites. Compos. Sci. Technol. 1991, 40, 231–250. [Google Scholar] [CrossRef]
  19. Bradley, W.L.; Cohen, R.N. Matrix Deformation and Fracture in Graphite-Reinforced Epoxies. In Delamination and Debonding of Materials; Johnson, W.S., Ed.; ASTM International: West Conshohocken, PA, USA, 1985; pp. 389–410. [Google Scholar]
  20. Khan, R. Delamination Growth in Composites under Fatigue Loading; Delft University of Technology: Delft, Netherlands, 2013. [Google Scholar]
  21. Shokrieh, M.M.; Heidari-Rarani, M.; Ayatollahi, M.R. Delamination R-curve as a material property of unidirectional glass/epoxy composites. Mater. Des. 2012, 34, 211–218. [Google Scholar] [CrossRef]
  22. Russo, A.; Zarrelli, M.; Sellitto, A.; Riccio, A. Fiber Bridging Induced Toughening Effects on the Delamination Behavior of Composite Stiffened Panels under Bending Loading: A Numerical/Experimental Study. Materials 2019, 12, 2407. [Google Scholar] [CrossRef]
  23. Ashcroft, I.A.; Hughes, D.J.; Shaw, S.J. Mode I fracture of epoxy bonded composite joints: 1. Quasi-static loading. Int. J. Adhes. Adhes. 2001, 21, 87–99. [Google Scholar] [CrossRef]
  24. Brunner, A.J.; Blackman, B.R.K.; Davies, P. A status report on delamination resistance testing of polymer–matrix composites. Eng. Fract. Mech. 2008, 75, 2779–2794. [Google Scholar] [CrossRef]
  25. Dransfield, K.A.; Jain, L.K.; Mai, Y.-W. On the effects of stitching in CFRPs—I. mode I delamination toughness. Compos. Sci. Technol. 1998, 58, 815–827. [Google Scholar] [CrossRef]
  26. Tsai, G.-C.; Chen, J.-W. Effect of stitching on Mode I strain energy release rate. Compos. Struct. 2005, 69, 1–9. [Google Scholar] [CrossRef]
  27. Heß, H.; Himmel, N. Structurally stitched NCF CFRP laminates. Part 1: Experimental characterization of in-plane and out-of-plane properties. Compos. Sci. Technol. 2011, 71, 549–568. [Google Scholar] [CrossRef]
  28. Wagenfelder-Spinnereien GmbH. Available online: https://rcf-yarn.com/de/ (accessed on 18 February 2026).
  29. DIN EN 6033:2016-02; Luft- und Raumfahrt-Kohlenstofffaserverstärkte Kunststoffe–Prüfverfahren-Bestimmung der in-terlaminaren Energiefreisetzungsrate–Mode I-GIC. Deutsche und Englische Fassung EN_6033:2015; German Institute for Standardization: Berlin, Germany.
  30. Hutchinson, J.W.; Jensen, H.M. Models of fiber debonding and pullout in brittle composites with friction. Mech. Mater. 1990, 9, 139–163. [Google Scholar] [CrossRef]
  31. Farmand-Ashtiani, E.; Cugnoni, J.; Botsis, J. Specimen thickness dependence of large scale fiber bridging in mode I interlaminar fracture of carbon epoxy composite. Int. J. Solids Struct. 2015, 55, 58–65. [Google Scholar] [CrossRef]
Figure 1. Micro-section of rCFRP made from staple fiber yarn (a); X-ray image (3D rendering) of bridging fibers in crack zone (b).
Figure 1. Micro-section of rCFRP made from staple fiber yarn (a); X-ray image (3D rendering) of bridging fibers in crack zone (b).
Jcs 10 00112 g001
Figure 3. Plate winding process with integrated PTFE film for plates with rCF staple fiber roving and newly produced carbon fiber (vCF) roving.
Figure 3. Plate winding process with integrated PTFE film for plates with rCF staple fiber roving and newly produced carbon fiber (vCF) roving.
Jcs 10 00112 g003
Figure 4. DCB test setup with optical measurement Aramis (a); DIN 6033 sample geometry and load–displacement diagram with determined energy used for calculation of ERR (b).
Figure 4. DCB test setup with optical measurement Aramis (a); DIN 6033 sample geometry and load–displacement diagram with determined energy used for calculation of ERR (b).
Jcs 10 00112 g004
Figure 7. (a) Comparison of nesting effect in the rCF-EP-0° and vCF-EP-0° samples [17]; (b) measurement of the effective fracture width in CT images of rCF-EP-0° and vCF-EP-0° sample half.
Figure 7. (a) Comparison of nesting effect in the rCF-EP-0° and vCF-EP-0° samples [17]; (b) measurement of the effective fracture width in CT images of rCF-EP-0° and vCF-EP-0° sample half.
Jcs 10 00112 g007
Figure 8. SEM images of the fracture zone of rCF-EP-0° sample with visible fiber tunnels of rCF fibers and PA6 filaments and ends of pulled out rCF roving bundles.
Figure 8. SEM images of the fracture zone of rCF-EP-0° sample with visible fiber tunnels of rCF fibers and PA6 filaments and ends of pulled out rCF roving bundles.
Jcs 10 00112 g008
Figure 9. Force–displacement diagram of rCF-EP-0° and vCF-EP-0° and adapted rCF-EP-0° with calculated fiber bridging stress (red line).
Figure 9. Force–displacement diagram of rCF-EP-0° and vCF-EP-0° and adapted rCF-EP-0° with calculated fiber bridging stress (red line).
Jcs 10 00112 g009
Figure 10. Measurement of the fracture width of rCF-EP-3° (a) and rCF-EP-5° (b) via CT scan of fracture surface; inter- (red lines) and intra-laminar (green lines) fiber bridging between rCF roving (c).
Figure 10. Measurement of the fracture width of rCF-EP-3° (a) and rCF-EP-5° (b) via CT scan of fracture surface; inter- (red lines) and intra-laminar (green lines) fiber bridging between rCF roving (c).
Jcs 10 00112 g010
Figure 11. Comparison of the energy release rate (ERR) over crack length of rCF (0°, 3°, 5°) and vCF (0°, 3°, 5°).
Figure 11. Comparison of the energy release rate (ERR) over crack length of rCF (0°, 3°, 5°) and vCF (0°, 3°, 5°).
Jcs 10 00112 g011
Table 2. Energy release rate from DCB tests for all material combinations.
Table 2. Energy release rate from DCB tests for all material combinations.
Material
Combination
Energy Release Rate (J/m2)Standard
Deviation
rCF_G1C-0°2518.93132.98
rCF_G1C-3°1697.52144.99
rCF_G1C-5°1571.15226.68
vCF_G1C-0°587.3875.04
vCF_G1C-3°425.9341.84
vCF_G1C-5°652.6532.93
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.

Share and Cite

MDPI and ACS Style

Becker, C.; Hausmann, J.; Motsch-Eichmann, N. Increased Interlaminar Fracture Toughening Through Distinct Fiber Bridging Effect of rCF Staple Fiber Yarn Composite. J. Compos. Sci. 2026, 10, 112. https://doi.org/10.3390/jcs10020112

AMA Style

Becker C, Hausmann J, Motsch-Eichmann N. Increased Interlaminar Fracture Toughening Through Distinct Fiber Bridging Effect of rCF Staple Fiber Yarn Composite. Journal of Composites Science. 2026; 10(2):112. https://doi.org/10.3390/jcs10020112

Chicago/Turabian Style

Becker, Christian, Joachim Hausmann, and Nicole Motsch-Eichmann. 2026. "Increased Interlaminar Fracture Toughening Through Distinct Fiber Bridging Effect of rCF Staple Fiber Yarn Composite" Journal of Composites Science 10, no. 2: 112. https://doi.org/10.3390/jcs10020112

APA Style

Becker, C., Hausmann, J., & Motsch-Eichmann, N. (2026). Increased Interlaminar Fracture Toughening Through Distinct Fiber Bridging Effect of rCF Staple Fiber Yarn Composite. Journal of Composites Science, 10(2), 112. https://doi.org/10.3390/jcs10020112

Article Metrics

Back to TopTop