Synthesis of Bis(benzotriazol-1-yl)methane Derivatives by Cobalt-Catalyzed Formation of C-C Bonds

Valentina Ferraro; Marco Bortoluzzi; Jesús Castro

doi:10.3390/ecsoc-23-06469

,

and

¹

Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia, Via Torino 155, 30170 Mestre (VE), Italy

²

Departamento de Química Inorgánica, Universidade de Vigo, Facultade de Química, Edificio de Ciencias Experimentais, 36310 Vigo, Galicia, Spain

^*

Author to whom correspondence should be addressed.

^†

Presented at the 23rd International Electronic Conference on Synthetic Organic Chemistry, 15 November– 15 December 2019; Available online: https://ecsoc-23.sciforum.net/.

Proceedings2019, 41(1), 29;https://doi.org/10.3390/ecsoc-23-06469

This article belongs to the Proceedings The 23rd International Electronic Conference on Synthetic Organic Chemistry

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Abstract

The compounds bis(benzotriazol-1-yl)phenylmethane and bis(benzotriazol-1-yl)pyridin-2-ylmethane were prepared by reacting (benzotriazol-1-yl)methanone and benzaldehyde or pyridine-2-carboxaldehyde using CoCl₂ as catalyst under neat conditions. The products were characterized spectroscopically and the solid-state structures were ascertained by single-crystal X-ray diffraction.

Keywords:

1H-benzotriazole; (benzotriazol-1-yl)methanone; cobalt catalysis; C-C bond formation

Synthesis of Bis(benzotriazol-1-yl)methane Derivatives by Cobalt-Catalyzed Formation of C-C Bonds^†

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Synthesis of Bis(benzotriazol-1-yl)methane Derivatives by Cobalt-Catalyzed Formation of C-C Bonds †

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Article Access Statistics

Synthesis of Bis(benzotriazol-1-yl)methane Derivatives by Cobalt-Catalyzed Formation of C-C Bonds^†