Advanced Application of Planar Chiral Heterocyclic Ferrocenes
Abstract
:1. Introduction
2. Application of Planar Chiral Heterocyclic Ferrocenes
2.1. Tsuji–Trost Reaction
2.2. Asymmetric Hydrogenation
2.3. The Rearrangement
2.4. Asymmetric Addition
2.5. Annulation and Cycloaddition
2.6. Cross-Coupling Reactions Catalyzed by Metals
2.7. Resolution of Enantiomers
3. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
Abbreviations
Ada | adamantly; |
Ar | aryl; |
Bn | benzoyl; |
Boc | tert-butyloxycarbonyl; |
(Bpin)2 | bis(pinacolato)diborane; |
BSA | bis(trimethylsilyl)acetamide; |
t-Bu | t-butyl; |
CHP | cumene hydroperoxide; |
o-DCB | 1,2-dichlorobenzene; |
DIPEA | N,N-diisopropylethylamine; |
DME | dimethoxyethane; |
DMF | dimethylformamide; |
ee | enantiomeric enriched; |
eq. | equivalent; |
er | enantiomeric ratio; |
Et | ethyl; |
HCA | L-homocysteic acid; |
[Ir(cod)Cl2] | bis(1,5-cyclooctadiene)diiridium(I) dichloride; |
LiHMDS | lithium bis(trimethylsilyl)amide; |
Me | methyl; |
Mes | mesityl; |
MPEG | methoxy polyethylene glycol; |
NHCs | N-heterocyclic carbenes; |
[Ni(cod)2] | bis(cyclooctadiene)nickel(0); |
Pd2(dba)3 | tris(dibenzylideneacetone)dipalladium(0); |
Ph | phenyl; |
PMHS | polymethylhydrosiloxane; |
i-Pr | i-propyl; |
PS | proton sponge, N,N,N′,N′-tetramethyl-1,8-diaminonaphthalene; |
[Rh(cod)2]BF4 | bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; |
[Rh(nbd)2]BF4 | bis(norbornadiene)rhodium(I) tetrafluoroborate; |
[Ru(p-cymene)2] | dichloro(p-cymene)ruthenium(II) dimer; |
TBAF | tetra-n-butylammonium fluoride; |
TBD | triazabicyclodecene; |
TBHP | tert-butyl hydroperoxide; |
THF | tetrahydrofuran; |
TMS | trimethylsilyl; |
Tol | tolyl. |
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Musikhina, A.A.; Serebrennikova, P.O.; Zabelina, O.N.; Utepova, I.A.; Chupakhin, O.N. Advanced Application of Planar Chiral Heterocyclic Ferrocenes. Inorganics 2022, 10, 152. https://doi.org/10.3390/inorganics10100152
Musikhina AA, Serebrennikova PO, Zabelina ON, Utepova IA, Chupakhin ON. Advanced Application of Planar Chiral Heterocyclic Ferrocenes. Inorganics. 2022; 10(10):152. https://doi.org/10.3390/inorganics10100152
Chicago/Turabian StyleMusikhina, Alexandra A., Polina O. Serebrennikova, Olga N. Zabelina, Irina A. Utepova, and Oleg N. Chupakhin. 2022. "Advanced Application of Planar Chiral Heterocyclic Ferrocenes" Inorganics 10, no. 10: 152. https://doi.org/10.3390/inorganics10100152