1. Introduction
Water availability and security are major concerns for many countries around the world. Both developed and developing countries are experiencing water shortages due to rapid urbanization. The increase in population and economic development in developed nations have increased water demand, while its quality supply remains under threat due to pollution and global warming [
1]. However, due to the continuous advancement in water treatment technologies, opportunities for the use of different source waters increased to meet the rising water demand. Alternative water sources such as treated wastewater, desalinated seawater, and imported water are being used to supplement the existing water supply [
2]. Wastewater reuse can eliminate the necessity of safe wastewater disposal and can be considered essential for sustainable water resource management.
The biggest challenge for sustainable wastewater reuse is the general perception of toxic exposure to human health and the ecosystem. For this reason, water quality assessments are critical in the evaluation of reusability [
3]. Water-borne diseases can be kept at bay if efficient water treatment methods are carried out before reuse [
4]. Unfortunately, emerging pollutants are being discovered in water sources due to pollution. Thus, efficient water treatment has become a challenge since pollution presents numerous obstacles to obtaining high water quality for reuse. Additionally, there is not a universally adopted water treatment method for water reuse, even though sand filtration is common for tertiary treatment of wastewater [
5]. It all depends on the particular source of water, its characteristics, and the water quality standard of that particular area [
6]. Moreover, the scarcity of water will be a major threat in the future, and this will necessitate increased water reuse. For this reason, tertiary treatment will be essential and sand-filtration-based tertiary treatment may not ensure the necessary quality. In the Middle East, there is a heavy reliance on groundwater, particularly for agricultural use [
7]. However, due to over-extraction and lack of natural and/or artificial recharge, groundwater sources are becoming unsustainable. In the UAE, specifically, it is predicted that in 55 years all groundwater will run out [
8]. On the contrary, water consumption per capita in UAE is among the highest in the world, even though available good quality water sources are running out. The culture of this region is such that people do not readily accept the reuse of treated wastewater. However, countries like Singapore have implemented the ‘toilet to tap’ concept since their reliable water sources ran out [
9]. High water consumption and scarcity are making it essential to find an alternative and sustainable source of water. The culture in this region needs to adapt to the reuse of wastewater for purposes like irrigation and toilet flushing by addressing the challenge of quality [
10].
As more wastewater is being disposed of from households and industries, the research communities are working hard to find new ways of treating wastewater to limit the environmental and health aspects and increase the potential for reuse [
11]. The continuous addition of different pollutants exists in wastewater and limits the reusability. Firstly, heavy metals like mercury, copper, and chromium can be found in wastewater, but they are not easy to remove [
12]. These metals are vital for living beings; however, high concentrations can be dangerous to the environment and humans. For example, chromium, which is widely used in various industries like ceramics, textiles, and alloying, is carcinogenic and can cause serious diseases [
13,
14]. Secondly, domestic wastewater can contain an excessive amount of nutrients like phosphorus [
15]. These nutrients cause eutrophication and algal bloom, which can reduce the dissolved oxygen levels in the water. Thirdly, organic materials can pose threats to human life, aquatic life, wildlife, etc. [
16]. These pollutants must be targeted to increase the reusability of the wastewater.
Typical advanced wastewater treatment plants use sand filtration as a tertiary process option. In recent times, membrane technologies have drawn a lot of interest for the treatment of wastewater [
17]. Membrane technology can be defined as a process that removes contaminants of varied sizes from gas and liquid mixtures based on their pore size and permeability. The water that passes through the membrane is called permeate whereas the water that stays behind with all the pollutants in it is called the concentrate [
18]. With membrane technology, the removal of various pollutants without the use of chemicals can be achieved [
19]. For this reason, they are often preferred to chemical processes. The two most efficient membrane technologies in terms of pollutants removal are Nano-filtration (NF) and Reverse Osmosis (RO) [
20]. The specifications of each membrane enable them to remove a wide range of pollutants. Both membranes are efficient in the removal of phosphorus and nitrogen contaminants [
21]. However, they are not very common for wastewater treatment due to high energy consumption and maintenance requirements. Other advanced membrane filtration methods include microfiltration and ultrafiltration. These methods are known to be effective in treating both greywater and wastewater [
22]. However, they are not as efficient for reuse as RO and NF. Even though RO and NF are not as common in wastewater as they are for drinking water, the added value of reuse can make the use of these membranes cost-effective. For this reason, the effectiveness of RO and NF against traditional sand filtration needs investigation.
Membrane technologies have some constraints of their own. It is recommended to pretreat the water to a level where the membrane is prevented from addressing problems like fouling. The clean feed would ensure that fouling and blocking of filters only occur after a long span of usage and not early on. Backwashes can be planned by constantly monitoring the water quality parameters. As soon as the parameters do not meet the standard qualities, backwash and cleanup of filters should be completed. In addition, the high energy consumption required for membrane technologies such as RO is one of its constraints. However, research is ongoing on using renewable or hybrid energy sources such as solar energy [
23].
Designing wastewater treatment plants should be executed in a way that satisfies a standard water quality level. Cost and efficiency are very intricate parameters when it comes to a water treatment plant design [
24]. Therefore, numerous studies have been conducted on these membrane technologies that investigate their efficiency of pollutants removal. Tertiary treatment of secondary effluent (from biological treatment) has the potential to ensure high quality of treated water reuse. It can justify the additional cost of replacing the existing sand filtration units with the membrane filtration units. Among the different technologies investigated for reuse, there are coagulation [
25], anaerobic baffled reactor [
26], chitosan modified membrane [
27], adsorption [
28,
29,
30,
31,
32], and activated sludge [
33]. Other than treatment technologies, the integration of energy and water systems are also explored for suitable reuse options [
34]. However, application of membrane technology is becoming popular as it does not generate as much waste residual as other chemical processes.
It is important to compare and understand the removal efficiencies of pollutants from synthetic wastewater using different technologies. This is because sometimes it is difficult and not practical to obtain a large amount of real wastewater to collect, preserve, and test, and synthetic wastewater can have less inherent variability in characteristics than real wastewater, which can make experiments on a specific pollutant more complicated. Moreover, there are already studies about using RO, NF, and sand filtration to treat wastewater individually, but no studies are comparing all different filtration technologies at the same time to demonstrate the effective treatability of the membrane technologies.
The objectives of this paper were to compare the treatability of secondary synthetic effluent using RO, NF, and conventional sand filtration. The study also explored comparative treatability between synthetic and real wastewater using RO to ensure the reliability of the experiments conducted using synthetic wastewater. The study also explored the role of pressure and time on the treatability of synthetic wastewater by NF and RO. Finally, ANOVA analysis was conducted on the role of pressure and time. Pilot experimental setups were used to achieve the objectives. The study is novel as it examined improvement in water quality using membrane technologies against sand filtration under controlled experimental condition. The study is also novel with examination of water quality parameters essential for wastewater reuse by replacing sand filtration with membrane technologies during tertiary treatment of secondary effluent.
4. Conclusions and Recommendations
After comparing all three filtrations, RO was the best at removing pollutants as it had the highest percent removal for all pollutants with more than 90% removal. The removal efficiency of pollutants from synthetic water was compared to real water using RO. Synthetic wastewater showed similar behavior to real wastewater with regards to the removal efficiency of the pollutants for different experimental timings. Thus, further controlled analysis on the role of time and pressure on synthetic water treatment was undertaken.
The different timings ensured the reliability of the project, but time did not seem to have an impact on the quality of filtration. However, as pressure increased there was a slight increase in the efficiency. This trend was observed in most of the pollutants. On the other hand, the pressure did not affect UV-254. Some fluctuations in pressure and time results could be attributed to instrumental error, the limited number of tests carried out, and scaling. These fluctuations might have impacted ANOVA analysis. Hence, ANOVA showed different results of the effect of pressure on the removal efficiency in both RO and NF and time in NF. The pH was always monitored to keep in check the alkalinity/acidity of the treated samples.
Choosing the right filter is important to consume the best water quality. As technology is thriving, membrane filtrations have overcome conventional filtrations, as they were more efficient in treating water. The plant management benefits from the data of such experiments because choosing the optimum pressure level results in a reduction in energy consumption eventually and saves a lot of money. This in turn ensures that the quality of treated water can be good for reuse purposes. There is substantial rationale behind replacing existing sand filtration unit with RO units for wastewater reuse purposes.