Author Contributions
Conceptualization, A.R.A.N.M. and M.P.; Methodology, A.R.A.N.M. and M.P.; Software, A.R.A.N.M. and M.P.; Validation, A.R.A.N.M. and M.P.; Formal analysis, A.R.A.N.M. and M.P.; Investigation, A.R.A.N.M. and M.P.; Resources, M.P.; Data curation, A.R.A.N.M. and M.P.; Writing—original draft, A.R.A.N.M. and M.P.; Writing—review & editing, A.R.A.N.M. and M.P.; Visualization, A.R.A.N.M. and M.P.; Supervision, M.P.; Project administration, M.P.; Funding acquisition, M.P. All authors contributed equally. All authors have read and agreed to the published version of the manuscript.
Figure 1.
Generalized geological cross-section throughout Lithuanian territory [
1].
Figure 1.
Generalized geological cross-section throughout Lithuanian territory [
1].
Figure 2.
Conceptual representation of the injection well in the Cambrian complex used for TOUGHREACT simulations.
Figure 2.
Conceptual representation of the injection well in the Cambrian complex used for TOUGHREACT simulations.
Figure 3.
Plots of initial reservoir properties used in TOUGHREACT simulation for the axis–symmetric model 1, porosity, and permeability plots.
Figure 3.
Plots of initial reservoir properties used in TOUGHREACT simulation for the axis–symmetric model 1, porosity, and permeability plots.
Figure 4.
Effect of operation time and injection temperature on reservoir property–porosity of Model 1, changes shown for reservoir porosity at 100 and 1000 m from injection well. Results are shown for 10, 30, and 50 years.
Figure 4.
Effect of operation time and injection temperature on reservoir property–porosity of Model 1, changes shown for reservoir porosity at 100 and 1000 m from injection well. Results are shown for 10, 30, and 50 years.
Figure 5.
Effect of operation time and injection temperature on reservoir properties–permeability of Model 1, changes shown for reservoir porosity at 100 and 1000 m from injection well. Results are shown for 10, 30, and 50 years.
Figure 5.
Effect of operation time and injection temperature on reservoir properties–permeability of Model 1, changes shown for reservoir porosity at 100 and 1000 m from injection well. Results are shown for 10, 30, and 50 years.
Figure 6.
Effect of operation time and injection temperature on reservoir properties–porosity of Model 2, changes shown at 500 m and 1000 m from injection well. Results are shown for 10, 30, and 50 years.
Figure 6.
Effect of operation time and injection temperature on reservoir properties–porosity of Model 2, changes shown at 500 m and 1000 m from injection well. Results are shown for 10, 30, and 50 years.
Figure 7.
Effect of operation time and injection temperature on reservoir properties–permeability of Model 2, changes shown at 500 m and 1000 m from injection well. Results are shown for 10, 30, and 50 years.
Figure 7.
Effect of operation time and injection temperature on reservoir properties–permeability of Model 2, changes shown at 500 m and 1000 m from injection well. Results are shown for 10, 30, and 50 years.
Figure 8.
Mineral dissolution (negative values) and mineral precipitation (positive values) at 40 °C, over a 50-year period for both Model 1 and Model 2.
Figure 8.
Mineral dissolution (negative values) and mineral precipitation (positive values) at 40 °C, over a 50-year period for both Model 1 and Model 2.
Figure 9.
Horizontal Well Placement (Injector (blue) and Producer (red) at same depth) (green box represent aquifer zone).
Figure 9.
Horizontal Well Placement (Injector (blue) and Producer (red) at same depth) (green box represent aquifer zone).
Figure 10.
Average water production and injection rate of screened sites (Mid-case model).
Figure 10.
Average water production and injection rate of screened sites (Mid-case model).
Figure 11.
Vertical segregation of horizontal Well (Injector (blue) at bottom and Producer (red) at top)–Scenario 2 (green box represent the aquifer zone).
Figure 11.
Vertical segregation of horizontal Well (Injector (blue) at bottom and Producer (red) at top)–Scenario 2 (green box represent the aquifer zone).
Figure 12.
Effect of horizontal length on water production and injection rates (without fracturing–Mid case).
Figure 12.
Effect of horizontal length on water production and injection rates (without fracturing–Mid case).
Figure 13.
Effect of fracturing on water production and injection rates (Mid-case model).
Figure 13.
Effect of fracturing on water production and injection rates (Mid-case model).
Figure 14.
Effect of fracture intensity on water production and injection rates (Mid-case model).
Figure 14.
Effect of fracture intensity on water production and injection rates (Mid-case model).
Figure 15.
Comparison of low, mid, and high case without fracturing for screened sites.
Figure 15.
Comparison of low, mid, and high case without fracturing for screened sites.
Figure 16.
Comparison of low, mid, and high case with fracturing (500 m intensity) for screened sites.
Figure 16.
Comparison of low, mid, and high case with fracturing (500 m intensity) for screened sites.
Figure 17.
Fracture Intensity comparison of low, mid, and high cases for screened Sites.
Figure 17.
Fracture Intensity comparison of low, mid, and high cases for screened Sites.
Figure 18.
Thermal breakthrough profile of screened sites (High-case model–125 m fracture intensity–50 years).
Figure 18.
Thermal breakthrough profile of screened sites (High-case model–125 m fracture intensity–50 years).
Table 1.
Water production history from all oil reservoirs [
1].
Table 1.
Water production history from all oil reservoirs [
1].
| Oil Reservoir | Water Extracted from the Field Since the Start of Production, m3 | Water Produced in 2022, m3/y | No. of Wells | Temperature at the Top of Cambrian, °C |
|---|
| Genciai | 5,651,869.915 | 86,236.001 | 10 | 74 |
| Vilkyciai | 4,129,050.971 | 64,714.905 | 15 | 85.5 |
| South Siupariai | 2,955,872.771 | 0 | 10 | 83 |
| Nausodis | 2,107,141.674 | 42,946.523 | 14 | 75 |
| Diegliai | 1,623,752.633 | 0 | 6 | 82.9 |
| Kretinga | 1,319,346.659 | 8488.2 | 9 | 70.2 |
| Siupariai | 872,572.994 | 372.661 | 6 | 76.3 |
| Pociai | 559,226.701 | 8377.844 | 5 | 84.3 |
| Vezaiciai | 543,463.32 | 10,453.455 | 12 | 76 |
| Girkaliai | 370,381.596 | 8571.187 | 6 | 71.7 |
| Liziai | 365,821.766 | 3949.233 | 4 | |
| Sakuciai | 152,549.824 | 3843.274 | 4 | 84 |
| Ablinga | 61,134.015 | 0 | 3 | 80.8 |
| Agluonenai | 45,666.05 | 419.345 | 2 | |
| Uoksai | 10,358.773 | 0 | 1 | 84.3 |
| Silale | 3246.94 | 0 | 2 | 82.4 |
| Auksoras | 2522.611 | 0 | 1 | |
| Zadeikiai | 1794.846 | 0 | 1 | |
| North Vezaiciai | 1221.246 | 141.685 | 1 | 76 |
Table 2.
Petrophysical parameters of the five screened sites [
1].
Table 2.
Petrophysical parameters of the five screened sites [
1].
| Reservoir Parameters | Genciai | Vilkyciai | South Siupariai | Nausodis | Diegliai |
|---|
| Effective porosity, % | 6–8–10 | 4.6–6.5–9.7 | 5.4–6.2–7.7 | 0.3–8–15 | 6–8.5–11.3 |
| Permeability, mD | 0.1–12–219 | 0.1–10.4–41.4 | 0.01–16.7–45.14 | 0.01–9.4–895.6 | 0.1–10.8–47 |
| Depth, m | 1800–1826.4 | 1975–1992.5 | 1958–1988 | 1765–1860.6 | 1940–1990 |
| Average temperature, °C | 73.64 | 88 | 83 | 75 | 85 |
| Water salinity, mg/L | 146,217.33 | 229,000 | - | 138,241.18 | 200,000 |
| Injection water temperature, °C | 55 | 55 | 55 | 55 | 55 |
| Reservoir Pressure, bars | 191.66 | 222 | 216 | 190.491 | 213 |
| Reservoir thickness, m | 26.4; 16.19 | 68; 17.5 | 30; 16 | 95.6; 82.28 | 61; 25 |
| NTG (Net-to-Gross), units | 0.61 | 0.26 | 0.53 | 0.86 | 0.41 |
Table 3.
Research gaps in the study.
Table 3.
Research gaps in the study.
| Sr. No | Research Items | Description |
|---|
| 1 | Seismic (4D) | Nature of reservoir, Temperature front monitoring, Depth & Thickness maps. |
| 2 | Thermal conductivity | Heat calculations, Heat Flow. |
| 3 | Well logs | Reservoir description, Temperature corrections, Geothermal temperature, and pressure gradient analysis. |
| 4 | Core samples | Reservoir Description, Laboratory analysis. |
| 5 | Dynamic field data | Production, Temperature, and Bottom hole pressure history for history matching and predictions. |
| 6 | Reactive Transport Modelling (RTM) | Mineral changes, study dissolution and precipitation of minerals |
| 7 | Thermal-Hydraulic-Mechanical-Chemical (THMC) Modelling | Study mechanical behavior of rocks during production and injection of fluids. |
| 8 | Economic Modelling | To develop business case model. |
Table 4.
Primary aqueous composition of Cambrian aquifer.
Table 4.
Primary aqueous composition of Cambrian aquifer.
| Component | Ionic Composition (mol/kg of Water) |
|---|
| Ca+2 | 1.03 × 10−3 |
| Mg+2 | 1.66 × 10−6 |
| Na+ | 1.27 × 10−1 |
| Cl− | 1.42 × 10−1 |
| SiO2(aq) | 1.22 × 10−2 |
| HCO3− | 1.04 × 10−3 |
| So42− | 2.63 × 10−4 |
| K+ | 1.59 × 10−2 |
| AlO2− | 1.08 × 10−5 |
| Ba2+ | 1.50 × 10−5 |
| Sr2+ | 1.09 × 10−4 |
| Fe2+ | 1.02 × 10−2 |
| NH4+ | 8.10 × 10−3 |
| I− | 2.83 × 10−3 |
| Br− | 8.26 × 10−1 |
| B(OH)3 | 2.00 × 10−2 |
| HFeO2 | 2.63 × 10−4 |
Table 5.
Mineral and reaction parameters for reactive transport modelling.
Table 5.
Mineral and reaction parameters for reactive transport modelling.
| Minerals | Minerals | Mineral Initial Volume | Rate Constant | Activation Energy |
|---|
| Primary | Precipitation/Dissolution | Fraction | (mol/m2·s) | (kJ/mol) |
|---|
| Anhydrite | Equilibrium | 0.000 | | |
| Gypsum | Equilibrium | 0.000 | | |
| Anorthite | Equilibrium | 0.131 | | |
| Calcite | Kinetic | 0.004 | 1.60 × 10−9 | 41.87 |
| Illite | Kinetic | 0.054 | 3.16 × 10−13 | 58.6 |
| Quartz | Kinetic | 0.654 | 1.04 × 10−14 | 87.7 |
| Kaolinite | Kinetic | 0.051 | 1.78 × 10−13 | 58.6 |
| Muscovite | Kinetic | 0.000 | 3.16 × 10−13 | 58.6 |
| Dolomite-2 | Kinetic | 0.020 | 2.95 × 10−8 | 52.2 |
| Celestite | Kinetic | 0.000 | 0.00 × 100 | 0 |
| Barite | Kinetic | 0.000 | 1.26 × 10−8 | 30.8 |
| K-feldspar | Kinetic | 0.056 | 3.89 × 10−13 | 38 |
| Hematite | Kinetic | 0.011 | 2.51 × 10−15 | 66.2 |
Table 6.
Model properties used for reactive transport modelling.
Table 6.
Model properties used for reactive transport modelling.
| | Low Case | Hypothetical High Case |
|---|
| Parameters | Model 1 | Model 2 |
|---|
| Reservoir Parameters |
| Porosity (%) | 6.5 | 6.5 |
| Permeability (mD) | 11 | 11 |
| Specific heat of rock (J/Kg·°C) | 2.4 | 2.4 |
| Layers | 6 | 6 |
| Thickness of layer (m) | 2.4 | 2.4 |
| Density of water (Kg/m3) | 1129 | 1129 |
| Boundary Conditions |
| Reservoir Temperature (Produced water temperature) (°C) | 88 | 88 |
| Re-injection water temperature (°C) | 55/40/30/20/10 | 55/40/30/20/10 |
| Water re-injection rate (sm3/day) | 349 | 5800 |
| Time Steps |
| Simulation Time period (years) | 50/40/30/20/10 | 50/40/30/20/10 |
Table 7.
Average water production and injection rate for all screened sites (mid case model).
Table 7.
Average water production and injection rate for all screened sites (mid case model).
| Horizontal Well Length of 2500 m Long-Depth Sensitivity |
|---|
| Sr. No | Reservoirs | Depth Z (m) | Grid Block | Avg. Water Injection Rate (sm3/day) | Avg. Water Production Rate (sm3/day) |
|---|
| 1 | Nausodis | 37 | 53 | 481.69 | 604.31 |
| 2 | 50 | 71 | 529.26 | 786.28 |
| 3 | 63 | 89 | 428.74 | 700.26 |
| 4 | 76 | 107 | 475.62 | 751.68 |
| 1 | Diegliai | 24 | 53 | 204.48 | 250.61 |
| 2 | 32 | 71 | 219.46 | 277.14 |
| 3 | 40 | 89 | 195.2 | 328.12 |
| 4 | 48 | 107 | 176.37 | 331.85 |
| 1 | Vilkyciai | 30 | 53 | 122.9 | 182.06 |
| 2 | 40 | 71 | 133.88 | 235.45 |
| 3 | 50 | 89 | 112.24 | 223.15 |
| 4 | 60 | 107 | 108.92 | 208.04 |
| 1 | Siuparai | 13 | 53 | 170.93 | 234.76 |
| 2 | 17 | 71 | 174.24 | 279.06 |
| 3 | 22 | 89 | 188.36 | 257.45 |
| 4 | 26 | 107 | 204.18 | 294.15 |
| 1 | Genciai | 10 | 53 | 124.7 | 219.58 |
| 2 | 14 | 71 | 162.71 | 226.35 |
| 3 | 17 | 89 | 92.03 | 88.53 |
| 4 | 21 | 107 | 81.68 | 185.71 |
Table 8.
Average water production and injection rate from vertical segregation (Scenario–2).
Table 8.
Average water production and injection rate from vertical segregation (Scenario–2).
| Vertical Segregation of Horizontal Well-2500 m Long Without Fracturing |
|---|
| Sr. No | Reservoirs | Depth (m) | Length (m) | Avg. Water Injection Rate (sm3/day) | Avg. Water Production Rate (sm3/day) |
|---|
| | | Injector | Producer | | | |
|---|
| 1 | Nausodis | 50 | 50 | 2500 | 529.26 | 786.28 |
| 2 | 50 | 37 | 2500 | 489.79 | 605.82 |
| 3 | 63 | 50 | 2500 | 438.45 | 754.33 |
| 4 | 76 | 63 | 2500 | 468.17 | 713.08 |
| 1 | Diegliai | 32 | 40 | 2500 | 227.26 | 335.46 |
| 2 | 32 | 24 | 2500 | 216.38 | 252.66 |
| 3 | 40 | 32 | 2500 | 188.73 | 271.28 |
| 4 | 48 | 40 | 2500 | 175.26 | 323.33 |
| 1 | Vilkyciai | 40 | 40 | 2500 | 133.88 | 235.45 |
| 2 | 40 | 30 | 2500 | 129.65 | 182.81 |
| 3 | 50 | 40 | 2500 | 112.88 | 231.87 |
| 4 | 60 | 50 | 2500 | 109.95 | 222.85 |
| 1 | Siupariai | 26 | 26 | 2500 | 204.18 | 294.15 |
| 2 | 17 | 13 | 2500 | 167.32 | 233.61 |
| 3 | 22 | 17 | 2500 | 192.98 | 285.01 |
| 4 | 26 | 22 | 2500 | 198.98 | 260.67 |
| 1 | Genciai | 14 | 14 | 2500 | 162.71 | 226.35 |
| 2 | 14 | 10 | 2500 | 163.49 | 232.52 |
| 3 | 17 | 14 | 2500 | 106.64 | 208.46 |
| 4 | 21 | 17 | 2500 | 72.09 | 85.42 |
Table 9.
Power (Thermal) calculation for the screened sites using horizontal wells.
Table 9.
Power (Thermal) calculation for the screened sites using horizontal wells.
| Horizontal Well Length (2500 m Long)—With Fracturing Sensitivity-25 Years |
|---|
| Sr. No | Reservoirs | Fracture Intensity (m) | Case | Avg. Water Injection Rate (sm3/day) | Avg. Water Production Rate (sm3/day) | Heat Energy (W) | Heat Energy (GWh) | Power (MWth) |
|---|
| 1 | Nausodis | 125 | Low | 1232.59 | 1442.77 | 2.187 × 1015 | 607.36 | 2.77 |
| | | Mid | 1676.1 | 1955.71 | 2.964 × 1015 | 823.29 | 3.76 |
| | | High | 2212.37 | 2574.46 | 3.902 × 1015 | 1083.77 | 4.95 |
| 2 | 250 | Low | 857.25 | 1073.07 | 1.626 × 1015 | 451.73 | 2.06 |
| | | Mid | 1166.59 | 1454.96 | 2.205 × 1015 | 612.49 | 2.80 |
| | | High | 1541.84 | 1916.16 | 2.904 × 1015 | 806.65 | 3.68 |
| 3 | 500 | Low | 637.83 | 851.96 | 1.291 × 1015 | 358.65 | 1.64 |
| | | Mid | 867.69 | 1155.33 | 1.751 × 1015 | 486.36 | 2.22 |
| | | High | 1147.38 | 1521.98 | 2.307 × 1015 | 640.71 | 2.93 |
| 1 | Diegliai | 125 | Low | 511.19 | 639.23 | 1.246 × 1015 | 345.98 | 1.58 |
| | | Mid | 637.34 | 800.36 | 1.559 × 1015 | 433.19 | 1.98 |
| | | High | 776.02 | 978.41 | 1.906 × 1015 | 529.56 | 2.42 |
| 2 | 250 | Low | 357.68 | 474.21 | 9.240 × 1014 | 256.66 | 1.17 |
| | | Mid | 448.63 | 599.87 | 1.169 × 1015 | 324.68 | 1.48 |
| | | High | 550.04 | 740.57 | 1.443 × 1015 | 400.83 | 1.83 |
| 3 | 500 | Low | 276.93 | 382.63 | 7.456 × 1014 | 207.10 | 0.95 |
| | | Mid | 347.58 | 486.79 | 9.485 × 1014 | 263.47 | 1.20 |
| | | High | 426.8 | 604.14 | 1.177 × 1015 | 326.99 | 1.49 |
| 1 | Vilkyciai | 125 | Low | 339.34 | 469.22 | 9.752 × 1014 | 270.89 | 1.24 |
| | | Mid | 408.8 | 573.6 | 1.192 × 1015 | 331.16 | 1.51 |
| | | High | 495.84 | 704.28 | 1.464 × 1015 | 406.60 | 1.86 |
| 2 | 250 | Low | 233.81 | 350.45 | 7.284 × 1014 | 202.33 | 0.92 |
| | | Mid | 280.43 | 428.69 | 8.910 × 1014 | 247.50 | 1.13 |
| | | High | 339.08 | 527.17 | 1.096 × 1015 | 304.35 | 1.39 |
| 3 | 500 | Low | 173.02 | 276.64 | 5.750 × 1014 | 159.71 | 0.73 |
| | | Mid | 206.22 | 338.42 | 7.034 × 1014 | 195.38 | 0.89 |
| | | High | 247.82 | 416.4 | 8.654 × 1014 | 240.40 | 1.10 |
| 1 | Siupariai | 125 | Low | 432.68 | 519.69 | 9.676 × 1014 | 268.78 | 1.23 |
| | | Mid | 530.29 | 640.97 | 1.193 × 1015 | 331.50 | 1.51 |
| | | High | 637.51 | 775.14 | 1.443 × 1015 | 400.90 | 1.83 |
| 2 | 250 | Low | 310.76 | 395.22 | 7.359 × 1014 | 204.40 | 0.93 |
| | | Mid | 380.08 | 487.88 | 9.084 × 1014 | 252.33 | 1.15 |
| | | High | 456.33 | 590.56 | 1.100 × 1015 | 305.43 | 1.39 |
| 3 | 500 | Low | 241.6 | 321.79 | 5.991 × 1014 | 166.43 | 0.76 |
| | | Mid | 294.76 | 397.37 | 7.399 × 1014 | 205.52 | 0.94 |
| | | High | 353.41 | 481.33 | 8.962 × 1014 | 248.94 | 1.14 |
| 1 | Genciai | 125 | Low | 301.36 | 353.71 | 5.152 × 1014 | 143.12 | 0.65 |
| | | Mid | 416.5 | 483.26 | 7.039 × 1014 | 195.53 | 0.89 |
| | | High | 556 | 638.29 | 9.297 × 1014 | 258.26 | 1.18 |
| 2 | 250 | Low | 217.35 | 269.88 | 3.931 × 1014 | 109.20 | 0.50 |
| | | Mid | 303.11 | 372.3 | 5.423 × 1014 | 150.64 | 0.69 |
| | | High | 408.45 | 496.2 | 7.228 × 1014 | 200.77 | 0.92 |
| 3 | 500 | Low | 169.5 | 219.99 | 3.204 × 1014 | 89.01 | 0.41 |
| | | Mid | 237.05 | 305.15 | 4.445 × 1014 | 123.47 | 0.56 |
| | | High | 320.52 | 408.75 | 5.954 × 1014 | 165.39 | 0.76 |