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Open AccessArticle

Solid-State Solar Energy Conversion from WO3 Nano and Microstructures with Charge Transportation and Light-Scattering Characteristics

by 1,†, 2,†, 1,* and 2,*
1
Department of Chemical Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Korea
2
Department of Chemistry, Kwangwoon University, 20 Gwangwoon-ro, Nowon-gu, Seoul 01897, Korea
*
Authors to whom correspondence should be addressed.
These authors contributed equally to this work.
Nanomaterials 2019, 9(12), 1797; https://doi.org/10.3390/nano9121797
Received: 19 November 2019 / Revised: 5 December 2019 / Accepted: 12 December 2019 / Published: 17 December 2019
(This article belongs to the Special Issue Metal-Oxide Nanomaterials for Energy Application)
Solar energy conversion devices composed of highly crystalline gel polymers with disk-WO3 nanostructure and plate-WO3 microstructures (D-WO3 and P-WO3, respectively) exhibited higher power conversion efficiency than those with a gel electrolyte. In this study, D-WO3 and P-WO3 were prepared using a hydrothermal process and their structural and morphological features were investigated for application in solar energy conversion devices. The P-WO3 solid-state electrolyte significantly enhanced the cell performance owing to its charge transportation and light-scattering characteristics. The P-WO3 solid-state electrolyte showed a power conversion efficiency of 6.3%, which is higher than those of the gel (4.2%) and D-WO3 solid-state (5.5%) electrolytes. The electro-chemical impedance spectroscopy (EIS), intensity-modulated voltage spectroscopy (IMVS), diffuse reflectance, and incident photon-to-current conversion efficiency (IPCE) analysis results showed that the P-WO3 solid-state electrolyte showed improved charge transportation and light scattering, and hence enhanced the cell performance. View Full-Text
Keywords: solid-state electrolyte; tungsten oxide (WO3); hydrothermal; charge transportation; solar energy conversion; light scattering; dye-sensitized solar cell solid-state electrolyte; tungsten oxide (WO3); hydrothermal; charge transportation; solar energy conversion; light scattering; dye-sensitized solar cell
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MDPI and ACS Style

Moon, J.; Shin, W.; Park, J.T.; Jang, H. Solid-State Solar Energy Conversion from WO3 Nano and Microstructures with Charge Transportation and Light-Scattering Characteristics. Nanomaterials 2019, 9, 1797. https://doi.org/10.3390/nano9121797

AMA Style

Moon J, Shin W, Park JT, Jang H. Solid-State Solar Energy Conversion from WO3 Nano and Microstructures with Charge Transportation and Light-Scattering Characteristics. Nanomaterials. 2019; 9(12):1797. https://doi.org/10.3390/nano9121797

Chicago/Turabian Style

Moon, Juyoung; Shin, Woojun; Park, Jung T.; Jang, Hongje. 2019. "Solid-State Solar Energy Conversion from WO3 Nano and Microstructures with Charge Transportation and Light-Scattering Characteristics" Nanomaterials 9, no. 12: 1797. https://doi.org/10.3390/nano9121797

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