Next Article in Journal
Modified Distributed Bragg Reflectors for Color Stability in InGaN Red Micro-LEDs
Next Article in Special Issue
Synthesis of Multiple Emission Carbon Dots from Dihydroxybenzoic Acid via Decarboxylation Process
Previous Article in Journal
Highly Dispersed Pt-Incorporated Mesoporous Fe2O3 for Low-Level Sensing of Formaldehyde Gas
Previous Article in Special Issue
Super-Branched PdCu Alloy for Efficiently Converting Carbon Dioxide to Carbon Monoxide
 
 
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Noble Metal Nanoparticle-Loaded Porphyrin Hexagonal Submicrowires Composites (M-HW): Photocatalytic Synthesis and Enhanced Photocatalytic Activity

1
Key Laboratory for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-Efficiency Display and Lighting Technology, School of Materials Science and Engineering, Collaborative Innovation Center of Nano Functional Materials and Applications, Henan University, Kaifeng 475004, China
2
International Joint Centre for Biomedical Innovation, School of Life Sciences, Henan University, Kaifeng 475004, China
*
Authors to whom correspondence should be addressed.
Nanomaterials 2023, 13(4), 660; https://doi.org/10.3390/nano13040660
Submission received: 5 January 2023 / Revised: 21 January 2023 / Accepted: 29 January 2023 / Published: 8 February 2023
(This article belongs to the Special Issue Nano-Composites for Photo- and Electrocatalysis and Its Application)

Abstract

Surface plasmon resonance (SPR) photocatalysts have attracted considerable attention because of their strong absorption capacity of visible light and enhanced photogenic carrier separation efficiency. However, the separate production of metal nanoparticles (NPs) and semiconductors limits the photogenic charge transfer. As one of the most promising organic photocatalysts, porphyrin self-assemblies with a long-range ordered structure-enhance electron transfer. In this study, plasmonic noble metal-based porphyrin hexagonal submicrowires composites (M-HW) loaded with platinum (Pt), silver (Ag), gold (Au), and palladium (Pd) NPs were synthesized through a simple in situ photocatalytic method. Homogeneous and uniformly distributed metal particles on the M-HW composites enhanced the catalytic or chemical properties of the organic functional nanostructures. Under the same loading of metal NPs, the methyl orange photocatalytic degradation efficiency of Ag-HW [kAg-HW (0.043 min−1)] composite was three times higher than that of HW, followed by Pt-HW [kPt-HW (0.0417 min−1)], Au-HW [kAu-HW (0.0312 min−1)], and Pd-HW [kPd-HW (0.0198 min−1)]. However, the rhodamine B (RhB) and eosin B photocatalytic degradations of Pt-HW were 4 times and 2.6 times those of HW, respectively. Finally, the SPR-induced electron injection, trapping, and recombination processes of the M-HW system were investigated. These results showed that M-HW plasmonic photocatalysts exhibited excellent photocatalytic performances, making them promising materials for photodegrading organic pollutants.
Keywords: porphyrin; self-assemblies; surface plasmon resonance; photocatalytic porphyrin; self-assemblies; surface plasmon resonance; photocatalytic

Share and Cite

MDPI and ACS Style

Liu, S.; Huang, G.; Wang, J.; Bao, J.; Wang, M.; Wei, Y.; Zhong, Y.; Bai, F. Noble Metal Nanoparticle-Loaded Porphyrin Hexagonal Submicrowires Composites (M-HW): Photocatalytic Synthesis and Enhanced Photocatalytic Activity. Nanomaterials 2023, 13, 660. https://doi.org/10.3390/nano13040660

AMA Style

Liu S, Huang G, Wang J, Bao J, Wang M, Wei Y, Zhong Y, Bai F. Noble Metal Nanoparticle-Loaded Porphyrin Hexagonal Submicrowires Composites (M-HW): Photocatalytic Synthesis and Enhanced Photocatalytic Activity. Nanomaterials. 2023; 13(4):660. https://doi.org/10.3390/nano13040660

Chicago/Turabian Style

Liu, Shuanghong, Guan Huang, Jiefei Wang, Jianshuai Bao, Mengyue Wang, Yaqun Wei, Yong Zhong, and Feng Bai. 2023. "Noble Metal Nanoparticle-Loaded Porphyrin Hexagonal Submicrowires Composites (M-HW): Photocatalytic Synthesis and Enhanced Photocatalytic Activity" Nanomaterials 13, no. 4: 660. https://doi.org/10.3390/nano13040660

APA Style

Liu, S., Huang, G., Wang, J., Bao, J., Wang, M., Wei, Y., Zhong, Y., & Bai, F. (2023). Noble Metal Nanoparticle-Loaded Porphyrin Hexagonal Submicrowires Composites (M-HW): Photocatalytic Synthesis and Enhanced Photocatalytic Activity. Nanomaterials, 13(4), 660. https://doi.org/10.3390/nano13040660

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop