Photocatalytic CO2 Reduction and Electrocatalytic H2 Evolution over Pt(0,II,IV)-Loaded Oxidized Ti Sheets
Abstract
:1. Introduction
2. Materials and Methods
2.1. Preparation of Sputter-Deposited Pt on Ti Sheets and Pt NP on Ti Sheets
2.2. Characterisation of the Samples
2.3. Photocatalytic CO2 Reduction and Electrochemical Hydrogen Evolution
3. Results and Discussion
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Pt/Ti-Oxide Catalysts [Reference] | Photoreactor Conditions | Major Products and Yields |
---|---|---|
1% Pt-loading on TiO2 with {001} facets [27] | 300 W Hg-lamp, 0.1 g on 28 cm2 watch glass in 350 mL reactor | CH4: 2.6 μmol g−1 h−1 No CO |
Pt (0.2 wt.%)/TiO2: impregnation and thermal treatment [34] | 0.1 g catalyst, 423 K, 400 W Hg lamp, CO2 flow (4.5 mL/min) saturated with H2O vapor | CH4: 1.46 μmol g−1 h−1 H2: 5.28 μmol g−1 h−1 |
Pt (1.82 nm)/TiO2 NPs [24] | 132 mL stainless steel reactor, 500 W Xe lamp, 20 mg catalyst, 5 mL H2O | CH4: 60.1 μmol g−1 h−1 C2H6: 2.8 μmol g−1 h−1 H2: 87.5 μmol g−1 h−1 |
1.5 wt.% Pt/TiO2 photocatalyst [35] | UV 8 W Hg lamp (peak intensity at 254 nm) 0.1 g catalyst, 10 mL H2O, Pressured CO2 in the 348 mL reactor | CO: 7 μmol g−1 for 12 h CH4: 15 μmol g−1 for 12 h H2: 270 μmol g−1 for 12 h |
Pt (3–4 nm)/TiO2 nanosheet porous film [36] | 300 W Hg lamp (10.4 mW/cm2) 20 mL 0.1 mol/L KHCO3 solution | CH4: 20.5 ppm cm−1 h−1 |
Pt on ultrathin TiO2 [20] | 10 mg catalyst, 50 cm3 of chamber volume. 300 W Xe lamp | CH4: 47 μmol for 10 h CO: 35 μmol for 10 h |
Pt-loaded TiO2 spheres (>500 μm) [19] | 200 mg catalyst, 100 μL of DI water, pressurized CO2 (50 PSI), UV (20 mW/cm2, 254 nm) | CO: 18 μmol g−1 h−1 CH4: 3.5 μmol g−1 h−1 H2: 230 μmol g−1 h−1 |
Pt NPs (5–12 nm) on TiO2 nanofibers through electrospinning [10] | 5 mg catalyst on 2 cm × 2 cm glass, 500 W Xe lamp, 0.1 mL of deionized water, 90 mL gastight reactor | CO: 0.08 μmol h−1 CH4: 0.42 μmol g−1 h−1 |
Pt2+–Pt0/TiO2 NPs by sol-gel method [37] | 300 W Xe arc lamp, 0.1 g on glass-fiber cloth in 85 mL reactor, a mixture of CO2, and water vapor flow | CO: 20 μmol g−1 for 14 h CH4: 264 μmol g−1 for 7 h H2: 2763 μmol g−1 for 7 h |
Sputter deposited Pt (1 nm) on TiO2 by aerosol chemical vapor deposition [22] | 400 W Xe lamp (250–388 nm, 19.6 mW/cm2), a mixture of CO2 and water vapor, flow reactor system | CH4: 1361 μmol g−1 h−1 CO: 200 μmol g−1 h−1 |
Platinum-impregnated P25, Pt/TiO2 [17] | UV-curing 100 W high-pressure Hg lamp (170 mW cm−2), 353 and 423 K, gas-phase continuous flow reactor. | CH4: 1.08 μmol g−1 h−1 H2: 11.4 μmol g−1 h−1 |
Pt/TiO2 nanotube [21] | a 300 W high-pressure Hg lamp (wavelength 365 nm), a fixed-bed photocatalysis reactor, 50 mg on the flat quartz plate | CH4 yield with 0.0565 μmol h−1 g−1 after 7 h UV irradiation. |
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Yang, J.H.; Park, S.J.; Rhee, C.K.; Sohn, Y. Photocatalytic CO2 Reduction and Electrocatalytic H2 Evolution over Pt(0,II,IV)-Loaded Oxidized Ti Sheets. Nanomaterials 2020, 10, 1909. https://doi.org/10.3390/nano10101909
Yang JH, Park SJ, Rhee CK, Sohn Y. Photocatalytic CO2 Reduction and Electrocatalytic H2 Evolution over Pt(0,II,IV)-Loaded Oxidized Ti Sheets. Nanomaterials. 2020; 10(10):1909. https://doi.org/10.3390/nano10101909
Chicago/Turabian StyleYang, Ju Hyun, So Jeong Park, Choong Kyun Rhee, and Youngku Sohn. 2020. "Photocatalytic CO2 Reduction and Electrocatalytic H2 Evolution over Pt(0,II,IV)-Loaded Oxidized Ti Sheets" Nanomaterials 10, no. 10: 1909. https://doi.org/10.3390/nano10101909