The Decomposition Mechanism of C₄F₇N–Ag Gas Mixture Under High Temperature Arc

The global phase-out of sulfur hexafluoride (SF6), an insulating gas with high global warming potential (GWP), has driven the search for eco-friendly alternatives in high-voltage equipment. Perfluoroisobutyronitrile (C4F7N) emerges as a promising candidate due to its low GWP and high dielectric strength. However, its chemical stability under circuit breaker conditions, especially when interacting with vaporized contact materials such as silver, remains a key concern. This study investigates the decomposition mechanisms of C4F7N in the presence of silver vapor using quantum chemical calculations at the B3LYP/LanL2DZ level. A reaction network comprising 35 pathways and 12 transition states were identified. All structures were confirmed as valid stationary points via frequency analysis and intrinsic reaction coordinate (IRC) calculations. Three primary reaction pathways between C4F7N and Ag were delineated, leading to secondary reactions that generate low-weight molecules and Ag-containing species such as AgF and AgCN. Key energy barriers and temperature-dependent equilibrium constants (K_eq) were determined to evaluate pathway feasibility. This work provides fundamental insights into the high-temperature interfacial chemistry of C4F7N with Ag, offering essential data for assessing its material compatibility and long-term reliability as a sustainable insulation medium in power systems.