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Open AccessArticle

Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes

1
Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 1192/12, 771 46 Olomouc, Czech Republic
2
Central European Institute of Technology, CEITEC BUT, Technická 3058/10, 61600 Brno, Czech Republic
3
Material sciences, Darmstadt University of Technology, D-64287 Darmstadt, Germany
*
Author to whom correspondence should be addressed.
Metals 2019, 9(8), 849; https://doi.org/10.3390/met9080849
Received: 10 July 2019 / Revised: 23 July 2019 / Accepted: 31 July 2019 / Published: 2 August 2019
(This article belongs to the Special Issue Molecular Magnetism of Transition Metal Complexes)
The synthesis, crystal structure, and magnetic properties of three new mononuclear complexes [Fe(R-LA)(L1)](BPh4), where R-LA2− is a doubly deprotonated pentadentate Schiff base ligand and L1 is a monodentate benzimidazole or furopyridine ligand, are reported. Ligand- and anion-driven changes in crystal structures and magnetic behavior were investigated in terms of the magnetic susceptibility measurements and theoretical calculations. View Full-Text
Keywords: spin crossover; Schiff base ligands; iron (III) complex; structure; magnetism spin crossover; Schiff base ligands; iron (III) complex; structure; magnetism
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MDPI and ACS Style

Nemec, I.; Svoboda, I.; Herchel, R. Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes. Metals 2019, 9, 849. https://doi.org/10.3390/met9080849

AMA Style

Nemec I, Svoboda I, Herchel R. Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes. Metals. 2019; 9(8):849. https://doi.org/10.3390/met9080849

Chicago/Turabian Style

Nemec, Ivan; Svoboda, Ingrid; Herchel, Radovan. 2019. "Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes" Metals 9, no. 8: 849. https://doi.org/10.3390/met9080849

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