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Open AccessArticle

Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes

1
Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 1192/12, 771 46 Olomouc, Czech Republic
2
Central European Institute of Technology, CEITEC BUT, Technická 3058/10, 61600 Brno, Czech Republic
3
Material sciences, Darmstadt University of Technology, D-64287 Darmstadt, Germany
*
Author to whom correspondence should be addressed.
Metals 2019, 9(8), 849; https://doi.org/10.3390/met9080849
Received: 10 July 2019 / Revised: 23 July 2019 / Accepted: 31 July 2019 / Published: 2 August 2019
(This article belongs to the Special Issue Molecular Magnetism of Transition Metal Complexes)
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Abstract

The synthesis, crystal structure, and magnetic properties of three new mononuclear complexes [Fe(R-LA)(L1)](BPh4), where R-LA2− is a doubly deprotonated pentadentate Schiff base ligand and L1 is a monodentate benzimidazole or furopyridine ligand, are reported. Ligand- and anion-driven changes in crystal structures and magnetic behavior were investigated in terms of the magnetic susceptibility measurements and theoretical calculations. View Full-Text
Keywords: spin crossover; Schiff base ligands; iron (III) complex; structure; magnetism spin crossover; Schiff base ligands; iron (III) complex; structure; magnetism
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Nemec, I.; Svoboda, I.; Herchel, R. Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes. Metals 2019, 9, 849.

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