Grain Size Evolution and Mechanical Properties of Nb, V–Nb, and Ti–Nb Boron Type S1100QL Steels
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Chemical Analysis
C | Si | Mn | S * | Cr | Ni | Cu | Mo | Al | Ti | Nb | V | B * | N * | Fe | |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Nb | 0.19 | 0.24 | 0.85 | 30 | 0.52 | 1.30 | 0.38 | 0.42 | 0.06 | / | 0.013 | / | 11 | 29 | bal. |
V–Nb | 0.17 | 0.23 | 0.88 | 30 | 0.51 | 1.28 | 0.37 | 0.40 | 0.05 | / | 0.013 | 0.02 | 11 | 46 | bal. |
Ti–Nb | 0.18 | 0.23 | 0.87 | 30 | 0.52 | 1.30 | 0.35 | 0.41 | 0.06 | 0.013 | 0.014 | / | 11 | 31 | bal. |
3.2. Thermodynamic Predictions
3.3. Microstructure
3.4. Non-Metallic Inclusions
3.5. CCT Diagram
3.6. PAG Size and Distribution
3.7. Mechanical Properties
4. Conclusions
- Microstructures in the hot-forged, hot-rolled, and QT conditions are similar, regardless of the microalloying system used. The microstructures were mostly bainitic after hot forging and hot rolling, followed by air cooling. Fine lath martensite formed after water-quenching.
- Due to microalloying, low-density coarse primary Nb(C,N) and (Ti,Nb)(C,N) non-metallic inclusions formed, however, no V-rich inclusions were observed. No harmful clusters of non-metallic inclusions were detected which resulted in optimal toughness and tensile properties.
- The selection of a microalloying system played a major role in PAG size and distribution. When only Nb was micro-alloyed the resulting PAG size was coarsest, and the widest grain size distribution was obtained. The combination of V–Nb resulted in finer grains and a narrower grain size distribution. However, the combination of Ti–Nb had the smallest PAG size and the narrowest grain size distribution, which is attributed to the pinning effect of TiN.
- Results show that the combination of microalloying elements provides the most favorable mechanical characteristics and grain size distribution compared to the addition of sole microalloying elements, Nb in this paper.
- All three microalloying systems can provide the necessary mechanical properties using appropriate rolling schedules with final reductions done under the Tnr resulting in an elongated austenite structure with an increased dislocation density for the nucleation of finely dispersed pinning particles of Nb, V, and Ti, that inhibited the austenite grain growth.
- The V and Nb micro-alloyed steel showed the best response in terms of Rp0.2 increment at low-temperature tempering at 200 °C, while the Ti–Nb steel achieved the best impact toughness, which correlates well to PAG size and distribution results.
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Steel | Condition | davg (µm) | dmax (µm) | St. dev. | G |
---|---|---|---|---|---|
Nb | Hot-forged | 88.3 | 585.9 | 62 | 0.15 |
Nb | Hot-rolled | 71.1 | 212.7 | 31.4 | 0.33 |
Nb | QT | 18.8 | 51.1 | 7.6 | 0.37 |
V–Nb | Hot-forged | 71 | 181.5 | 32.6 | 0.39 |
V–Nb | Hot-rolled | 58 | 164.9 | 29.2 | 0.35 |
V–Nb | QT | 17.8 | 48.4 | 7.3 | 0.37 |
Ti–Nb | Hot-forged | 58.9 | 147.2 | 23.8 | 0.40 |
Ti–Nb | Hot-rolled | 46.3 | 150.1 | 26.9 | 0.31 |
Ti–Nb | QT | 17.1 | 42.4 | 6.1 | 0.40 |
Steel | Rp0.2 (MPa) | Rm (MPa) | KV2 (J) | A5 (%) | ||||
---|---|---|---|---|---|---|---|---|
Q | QT | Q | QT | Q | QT | Q | QT | |
Nb | 1144 ± 25 | 1196 ± 26 | 1474 ± 30 | 1395 ± 29 | 40 ± 0.7 | 38 ± 0.7 | 13.0 ± 0.4 | 11.0 ± 0.3 |
V–Nb | 1074 ± 23 | 1186 ± 26 | 1400 ± 29 | 1384 ± 29 | 39 ± 1.0 | 40 ± 0.6 | 13.0 ± 0.4 | 12.0 ± 0.4 |
Ti–Nb | 1093 ± 24 | 1160 ± 25 | 1426 ± 30 | 1377 ± 29 | 43 ± 1.4 | 45 ± 1.2 | 12.5 ± 0.4 | 13.5 ± 0.4 |
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Foder, J.; Burja, J.; Klančnik, G. Grain Size Evolution and Mechanical Properties of Nb, V–Nb, and Ti–Nb Boron Type S1100QL Steels. Metals 2021, 11, 492. https://doi.org/10.3390/met11030492
Foder J, Burja J, Klančnik G. Grain Size Evolution and Mechanical Properties of Nb, V–Nb, and Ti–Nb Boron Type S1100QL Steels. Metals. 2021; 11(3):492. https://doi.org/10.3390/met11030492
Chicago/Turabian StyleFoder, Jan, Jaka Burja, and Grega Klančnik. 2021. "Grain Size Evolution and Mechanical Properties of Nb, V–Nb, and Ti–Nb Boron Type S1100QL Steels" Metals 11, no. 3: 492. https://doi.org/10.3390/met11030492