Discrete One-Stage Mechanochemical Synthesis of Titanium-Nitride in a High-Energy Mill
Abstract
:1. Introduction
- Structural factor, which determines the grinding of substances and the formation of an interfacial area required for chemical interactions;
- Kinetic factor, resulting in the accumulation of excess energy, which is accumulated in the formed structural defects of solid reagents and decreases the activation barrier of chemical reactions;
- Temperature factor, caused by heating of milling bodies, chamber walls, and a grinding substance (dissipative heat release), as well as by heat release from the relaxation of structural defects and chemical reactions.
2. Experimental Procedure
3. Mathematical Model
3.1. Thermal Balance Equation
3.2. Chemical Transformation Equation
3.3. Grinding Equation
3.4. Dynamics of Excess Energy
4. Solution of the Problem and Discussion
4.1. Estimation of Kinetic Parameters
4.2. Numerical Solution of the Problem
4.3. Morphology and X-ray Diffraction of the Final Product
5. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Lapshin, O.; Shkoda, O.; Ivanova, O.; Zelepugin, S. Discrete One-Stage Mechanochemical Synthesis of Titanium-Nitride in a High-Energy Mill. Metals 2021, 11, 1743. https://doi.org/10.3390/met11111743
Lapshin O, Shkoda O, Ivanova O, Zelepugin S. Discrete One-Stage Mechanochemical Synthesis of Titanium-Nitride in a High-Energy Mill. Metals. 2021; 11(11):1743. https://doi.org/10.3390/met11111743
Chicago/Turabian StyleLapshin, Oleg, Olga Shkoda, Oksana Ivanova, and Sergey Zelepugin. 2021. "Discrete One-Stage Mechanochemical Synthesis of Titanium-Nitride in a High-Energy Mill" Metals 11, no. 11: 1743. https://doi.org/10.3390/met11111743