Microtextural Characteristics of Ultramafic Rock-Forming Minerals and Their Effects on Carbon Sequestration

Ultramafic rocks are promising candidates for carbon sequestration by enhanced carbon dioxide (CO₂) mineralization strategies due to their highly CO₂-reactive mineral composition and their abundant availability. This study reports the mineralogy and microtextures of a representative ultramafic rock from the Ma-Hin Creek in northern Thailand and provides evidence of CO₂ mineralization occurring through the interaction between CO₂ and the rock in the presence of water under ambient conditions. After sample collection, rock description was determined by optical petrographic analysis. The rock petrography revealed a cumulated wehrlite comprising over 50% olivine and minor amounts of clinopyroxene, plagioclase, and chromian spinel. Approximately 25% of the wehrlite had altered to serpentine and chlorite. A series of CO₂ batch experiments were conducted on six different rock sizes at a temperature of 40 °C and pressure of 1 atm over five consecutive days. The post-experimental products were dried, weighed, and geochemically analyzed to detect changes in mineral species. Experimental results showed that product weight and the presence of calcite increased with reducing grain size. Additionally, the modal mineralogy of the wehrlite theoretically suggests potential CO₂ uptake of up to 53%, which is higher than the average uptake values of mafic rocks. These findings support the rock investigation approach used and the preliminary assessment of carbon mineralization potential, contributing to enhanced rock weathering techniques for CO₂ removal that could be adopted by mining and rock supplier industries.