Synchronization in Non-Mirror-Symmetrical Chirogenesis: Non-Helical π–Conjugated Polymers with Helical Polysilane Copolymers in Co-Colloids
Abstract
:1. Introduction
2. Results
2.1. Sergeants-and-Soldiers and Majority-Rule of Type I HCPS and Type II HCPS
2.1.1. Sergeants-and-Soldiers of Type I HCPS-S and -R in Isooctane and Homo-Colloids in CHCl3-MeOH Cosolvents
2.1.2. Majority-Rule of Type II HCPS in Isooctane and Homo-Colloids in CHCl3-MeOH Cosolvents
2.2. Sergeants-and-Soldiers in PFV8 Co-Colloids with Type I HCPS-S and -R
2.3. Majority-Rule in PFV8 Co-Colloids with Type II HCPS
2.4. Retention in CD and CPL Signals of PFV8 Co-Colloids with Type I HCPS and Type II HCPS by Si–Si Bond Selective Photolysis
2.5. Sergeants-and-Soldiers in PF8 Co-Colloids with Type I HCPS
2.6. Majority Rule in PF8 Co-Colloids with Type II HCPS
3. Discussion
3.1. Main-Chain Rigidity of HPS-S, HPS-R, HPS-IB, Type I HCPS, and Type II HCPS in Solution
3.2. Higher-Order Structures of Helical Polysilane Homo- and Copolymers in the Homo- and Co-Colloids
3.3. Possible Structures of Highly Emmisive PFV8 and PF8 in the Co-Colloids
3.4. Co-Colloidal Stucture of PFV8 and HPS-S by Atomic Force Microscopy
3.5. Possible Inter-Macromolecular Interactions of PFV8/PF8 with HPS/HCPS in the Co-Colloids
3.6. Film-State CD Spectra of PFV8 with Type I HCPS and Type II HCPS
4. Perspectives
5. Methods and Materials
5.1. Instrumentation
5.2. Preparation and Fractionation of Polysilanes and the Corresponding Dialkyldichlorosilanes
5.3. Fractionations of PFV8, PF8, and Polysilanes
5.4. Prepararing PFV8 and PF8 Co-Colloids with HPS, Type I HCPS, and Type II HCPS
5.5. Optimizing Optofluidic Effect of PFV8 Co-Colloids with HPS-S
5.6. Choosing Good-and-Poor Co-Solvent to Maximize Ser-Sol and Maj Effects of PFV8 and PF8 Co-Colloids with HPS and Type I HCPS
5.7. Calculating Mulliken Charges for Oigomeric Models of HPS-S, PFV8, and PF8
6. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Fujiki, M.; Okazaki, S.; Rahim, N.A.A.; Yamada, T.; Nomura, K. Synchronization in Non-Mirror-Symmetrical Chirogenesis: Non-Helical π–Conjugated Polymers with Helical Polysilane Copolymers in Co-Colloids. Symmetry 2021, 13, 594. https://doi.org/10.3390/sym13040594
Fujiki M, Okazaki S, Rahim NAA, Yamada T, Nomura K. Synchronization in Non-Mirror-Symmetrical Chirogenesis: Non-Helical π–Conjugated Polymers with Helical Polysilane Copolymers in Co-Colloids. Symmetry. 2021; 13(4):594. https://doi.org/10.3390/sym13040594
Chicago/Turabian StyleFujiki, Michiya, Shun Okazaki, Nor Azura Abdul Rahim, Takumi Yamada, and Kotohiro Nomura. 2021. "Synchronization in Non-Mirror-Symmetrical Chirogenesis: Non-Helical π–Conjugated Polymers with Helical Polysilane Copolymers in Co-Colloids" Symmetry 13, no. 4: 594. https://doi.org/10.3390/sym13040594