Next Article in Journal
Effect of Time Delay on Laser-Triggered Discharge Plasma for a Beyond EUV Source
Next Article in Special Issue
Homochirality: A Perspective from Fundamental Physics
Previous Article in Journal
Intelligent Supply Chain Information System Based on Internet of Things Technology under Asymmetric Information
Previous Article in Special Issue
Сhiral and Racemic Fields Concept for Understanding of the Homochirality Origin, Asymmetric Catalysis, Chiral Superstructure Formation from Achiral Molecules, and B-Z DNA Conformational Transition
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Symmetry
Volume 11
Issue 5
10.3390/sym11050657
symmetry-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Review

Overview of Low-Temperature Heat Capacity Data for Zn2(C8H4O4)2.C6H12N2 and the Salam Hypothesis

by
Svetlana Kozlova
1,2,*,
Maxim Ryzhikov
1,2,
Denis Pishchur
1 and
Irina Mirzaeva
1,2
1
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Lavrentyev Av., 3, RU-630090 Novosibirsk, Russia
2
Novosibirsk State University, Pirogova Street, 2, RU-630090 Novosibirsk, Russia
*
Author to whom correspondence should be addressed.
Symmetry 2019, 11(5), 657; https://doi.org/10.3390/sym11050657
Submission received: 29 March 2019 / Revised: 8 May 2019 / Accepted: 9 May 2019 / Published: 11 May 2019
(This article belongs to the Special Issue Possible Scenarios for Homochirality on Earth)
Browse Figures
Versions Notes

Abstract

The review presents the progress in the analysis of low-temperature heat capacity of the metal-organic framework Zn2(C8H4O4)2.C6H12N2 (Zn-DMOF). In Zn-DMOF, left-twisted D3(S) and right-twisted D3(R) DABCO molecules (C6H12N2) can transform into each other by tunneling to form a racemate. Termination of tunneling leads to a phase transition in the subsystem of twisted molecules. It is suggested that Zn-DMOF may be considered a model system to study the mechanisms of phase transitions belonging to the same type as hypothetical Salam phase transitions.
Keywords: heat capacity; metal-organic framework; triethylenediamine (DABCO) molecules; racemate; Salam hypothesis heat capacity; metal-organic framework; triethylenediamine (DABCO) molecules; racemate; Salam hypothesis

Share and Cite

MDPI and ACS Style

Kozlova, S.; Ryzhikov, M.; Pishchur, D.; Mirzaeva, I. Overview of Low-Temperature Heat Capacity Data for Zn2(C8H4O4)2.C6H12N2 and the Salam Hypothesis. Symmetry 2019, 11, 657. https://doi.org/10.3390/sym11050657

AMA Style

Kozlova S, Ryzhikov M, Pishchur D, Mirzaeva I. Overview of Low-Temperature Heat Capacity Data for Zn2(C8H4O4)2.C6H12N2 and the Salam Hypothesis. Symmetry. 2019; 11(5):657. https://doi.org/10.3390/sym11050657

Chicago/Turabian Style

Kozlova, Svetlana, Maxim Ryzhikov, Denis Pishchur, and Irina Mirzaeva. 2019. "Overview of Low-Temperature Heat Capacity Data for Zn2(C8H4O4)2.C6H12N2 and the Salam Hypothesis" Symmetry 11, no. 5: 657. https://doi.org/10.3390/sym11050657

APA Style

Kozlova, S., Ryzhikov, M., Pishchur, D., & Mirzaeva, I. (2019). Overview of Low-Temperature Heat Capacity Data for Zn2(C8H4O4)2.C6H12N2 and the Salam Hypothesis. Symmetry, 11(5), 657. https://doi.org/10.3390/sym11050657

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop