Alkaline Prehydrolysis Prolongs Resin Life and Enhances the Adsorption of Phenolic Compounds
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Methods
2.2.1. Alkaline Prehydrolysis Experiment
2.2.2. Macroporous Resin Adsorption Experiment
2.2.3. Regeneration Life Test of the Macroporous Resin Adsorption–Desorption
2.2.4. Liquid Chromatography–Mass Spectrometry (LC–MS) Detection
3. Results
3.1. Effect of the Hydrolysis pH on the Flocculation and Phenol Removal
3.2. Effect of the Alkaline Hydrolysis Time on the COD Removal
3.3. The Putative Metabolism Pathway of the BHT
3.4. FTIR Characteristic Analysis of the Functional Groups on the Surface of the Flocs after Hydrolysis
3.5. Effect of the Prehydrolysis on Improving the Service Life of the Resin Adsorption
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Models | Parameters | |
---|---|---|
Pseudo-first-order kinetic model | K1 | 0.432 |
R2 | 0.93453 | |
Pseudo-second-order dynamics model | K2 | 0.01616 |
R2 | 0.93947 | |
Elovich kinetic model | α | 8891.15855 |
β | 0.1939 | |
R2 | 0.78161 | |
Intra-particle diffusion model | K3 | 2.90067 |
R2 | 0.6252 |
Different Treatments | Composition |
---|---|
Raw wastewater | m-cresol; 3-methylbenzaldehyde |
Alkaline hydrolysis | m-tolylmethanol |
Alkaline hydrolysis + PAC | 3-hydroxy-5-methylbenzyl chloride; 1-methyl-3-[(3-methylphenyl) methylperoxymethyl]benzene |
Alkaline hydrolysis + PAC + resin adsorption | 6-{[3,5-bis(tert-butyl)-4-hydroxyphenyl]methyl}-2-(tert-butyl)-4-chlorophenol |
Material | Long | Wide | High | Volume | Diameter |
---|---|---|---|---|---|
m-Cresol | 8.653 | 7.189 | 4.018 | 249.95 | 6.3 |
4,6-di-tert-butyl-m-cresol | 10.752 | 8.196 | 6.505 | 573.24 | 8.306 |
2,6-di-tert-butyl-4-methylphenol (BHT) | 11.453 | 8.990 | 6.505 | 669.77 | 8.75 |
3-Methylbenzaldehyde | 9.022 | 7.316 | 4.018 | 265.21 | 6.424 |
m-tolylmethanol | 8.868 | 7.736 | 4.019 | 275.71 | 6.508 |
3-hydroxy-5-methylbenzyl chloride | 11.116 | 8.087 | 4.019 | 361.29 | 8.322 |
1-methyl-3-[(3-methylphenyl) methylperoxymethyl]benzene | 15.773 | 8.040 | 4.545 | 576.37 | 8.255 |
6-{[3,5-bis(tert-butyl)-4-hydroxyphenyl]methyl}-2-(tert-butyl)-4-chlorophenol | 15.372 | 10.212 | 8.312 | 1304.8 | 10.928 |
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Gu, C.; Yan, K.; Bo, L.; Zhou, X.; He, Y.; Feng, J.; Qin, J. Alkaline Prehydrolysis Prolongs Resin Life and Enhances the Adsorption of Phenolic Compounds. Water 2023, 15, 2566. https://doi.org/10.3390/w15142566
Gu C, Yan K, Bo L, Zhou X, He Y, Feng J, Qin J. Alkaline Prehydrolysis Prolongs Resin Life and Enhances the Adsorption of Phenolic Compounds. Water. 2023; 15(14):2566. https://doi.org/10.3390/w15142566
Chicago/Turabian StyleGu, Chao, Kailing Yan, Lei Bo, Xin Zhou, Yiwen He, Jiacheng Feng, and Jinyi Qin. 2023. "Alkaline Prehydrolysis Prolongs Resin Life and Enhances the Adsorption of Phenolic Compounds" Water 15, no. 14: 2566. https://doi.org/10.3390/w15142566