Assessing Surface Sediment Contamination by PBDE in a Recharge Point of Guarani Aquifer in Ribeirão Preto, Brazil
Abstract
:1. Introduction
2. Experimental
2.1. Chemicals and Reagents
2.2. Study Site and Sampling
2.3. PBDE Extraction and Quantification
3. Results and Discussion
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Congeners | Retention time/min | LOD/(ng g−1) b | LOQ/(ng g−1) c | Recovery/% d |
---|---|---|---|---|
BDE-28 | 28.1 | 0.14 | 0.48 | 98.5 ± 2.5 |
BDE-47 | 33.1 | 0.15 | 0.52 | 98.2 ± 4.3 |
BDE-66 | 34.1 | 0.17 | 0.57 | 97.8 ± 4.7 |
BDE-85 | 40.4 | 0.17 | 0.58 | 92.9 ± 6.0 |
BDE-99 | 38.0 | 0.2 | 0.67 | 97.9 ± 6.0 |
BDE-100 | 36.9 | 0.17 | 0.57 | 97.6 ± 6.5 |
BDE-138 | 45.6 | 0.24 | 0.80 | 89.8 ± 2.8 |
BDE-153 | 43.0 | 0.21 | 0.72 | 90.5 ± 4.5 |
BDE-154 | 41.4 | 0.17 | 0.57 | 92.4 ± 7.1 |
BDE-209 | 23.5 a | 0.14 | 0.48 | 94.2 ± 5.3 |
Congeners | Point 1 | Point 2 | Point 3 |
---|---|---|---|
BDE-28 | nd | 0.68 ± 0.04 | 0.58 ± 0.03 |
BDE-47 | nd | 2.10 ± 0.06 | 2.7 ± 0.1 |
BDE-66 | nd | 0.76 ± 0.03 | nd |
BDE-85 | nd | 0.24 ± 0.02 | 0.80 ± 0.05 |
BDE-99 | nd | 0.25 ± 0.02 | 0.94 ± 0.08 |
BDE-100 | nd | Nd | 0.35 ± 0.02 |
BDE-138 | nd | Nd | nd |
BDE-153 | nd | Nd | nd |
BDE-154 | nd | Nd | nd |
BDE-209 | nd | Nd | nd |
Ʃ10PBDE | - | 4.03 ± 0.09 | 5.4 ± 0.2 |
Country | Aquatic System | n a | ∑PBDEs b | References |
---|---|---|---|---|
Brazil | Saibro Lagoon | 10 | nd c–5.4 | This Study |
Brazil | Paranoá Lake | 9 | 2.5–8.1 | [51] |
Chile | Copncepción Bay | 10 | 0.02–21 | [72] |
China | Baiyangdian Lake | 8 | 0.05–5.03 | [73] |
China | Fuhe River | 8 | 0.13–6.39 | [73] |
China | Shanghai rivers | 16 | 0.44–12.0 | [74] |
China | Jiaojiang River | 10 | 8.93–45.0 | [42] |
South Korea | Shihwa Lake | 23 | 1.13–18700 | [39] |
Canada | Nigara River | 9 | 1.10–148 | [75] |
USA | White Lake | 23 | 0.39–2,4 | [76] |
USA | Muskegon Lake | 23 | 0.98–3.9 | [76] |
Italy | Maggiore Lake | 8 | 0.02–27.1 | [70] |
Russia | Olkhon Island | 40 | 0.164–0.670 | [69] |
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Ferrari, R.S.; de Souza, A.O.; Annunciação, D.L.R.; Sodré, F.F.; Dorta, D.J. Assessing Surface Sediment Contamination by PBDE in a Recharge Point of Guarani Aquifer in Ribeirão Preto, Brazil. Water 2019, 11, 1601. https://doi.org/10.3390/w11081601
Ferrari RS, de Souza AO, Annunciação DLR, Sodré FF, Dorta DJ. Assessing Surface Sediment Contamination by PBDE in a Recharge Point of Guarani Aquifer in Ribeirão Preto, Brazil. Water. 2019; 11(8):1601. https://doi.org/10.3390/w11081601
Chicago/Turabian StyleFerrari, Raissa S., Alecsandra O. de Souza, Daniel L. R. Annunciação, Fernando F. Sodré, and Daniel J. Dorta. 2019. "Assessing Surface Sediment Contamination by PBDE in a Recharge Point of Guarani Aquifer in Ribeirão Preto, Brazil" Water 11, no. 8: 1601. https://doi.org/10.3390/w11081601
APA StyleFerrari, R. S., de Souza, A. O., Annunciação, D. L. R., Sodré, F. F., & Dorta, D. J. (2019). Assessing Surface Sediment Contamination by PBDE in a Recharge Point of Guarani Aquifer in Ribeirão Preto, Brazil. Water, 11(8), 1601. https://doi.org/10.3390/w11081601