1. Introduction
Changes in climate system parameters, the ozone layer, and ultraviolet radiation (UV) fluxes are linked via numerous feedback sources, including dynamic, radiation, and photochemical processes. Therefore, to project the evolution of UV surface radiation, it is necessary to exploit chemistry–climate models (CCM), which consider the main interactions between the above-mentioned processes [
1]. At the same time, the calculation of surface UV radiation fluxes is currently carried out using radiation transfer models, which consider all the main factors affecting UV radiation fluxes, including the effects of multiple scattering and reflection of light within the Earth’s atmosphere and on its surface [
2]. These models have been used in recent decades to evaluate the changes in the surface UV irradiance during the 21st century (see, e.g., [
3], Section 9 and the references therein). In particular, many model projections have been performed to estimate the century-long evolution of surface UV radiation causing negative effects on human health and the biosphere: redness of the human skin (erythema), suppression of plant growth, and so on [
4,
5,
6,
7,
8,
9]. These studies helped to elucidate, along with astronomical (nearly periodic) factors (changes in the Earth–Sun position, the solar zenith angle, the tilt of the Earth’s rotation axis, and solar activity), the main atmospheric (non-periodic) factors that crucially control the surface UV fluxes: (1) the total ozone column (TOC); (2) the cloud parameters liquid cloud water column (LWCC) and total cloud cover); (3) the reflective properties of the Earth’s surface; (4) atmospheric aerosol properties (aerosol optical depth (AOD) and other optical parameters); and (5) concentrations of some minor gases in the atmosphere [
3].
The century-long evolution of the surface erythemal UV irradiance at local noon was evaluated in [
4,
5] based on CCM projections but without considering variations in cloud parameters, aerosol content, and surface albedo. The calculations show a significant decrease in noon erythemal UV fluxes during the 21st century in middle and high latitudes in both hemispheres, especially in polar regions, as a response to the total ozone recovery. The results of [
5] were reevaluated by [
6], considering the influence of the cloud parameter variations. They found that the erythemal surface irradiance will decrease until 2100 at the middle and high latitudes of the Northern Hemisphere and even fall below its 1980 level. At low latitudes, surface erythemal radiation is projected to increase slightly in some regions (~2%) by the end of the 21st century.
The changes in the surface erythemal UV radiation using the 21st-century projections were evaluated by [
7] utilizing the outputs from models participating in the 5th Phase of the Model Intercomparison Project (CMIP-5) driven by the socioeconomic scenario RCP 4–5. They considered changes in all main atmospheric factors (1)–(4), controlling the UV fluxes at the surface. The results of the calculations were found to be similar to those from [
6] for low and middle latitudes in both hemispheres, despite the additional consideration of the surface albedo and aerosol load changes. However, in the Arctic, the variation in surface reflectivity emerged as the dominant factor affecting changes in erythemal radiation in the 21st century. The impact of the aerosol changes on the surface erythema doses calculated in [
7] was considered to be rather uncertain.
More recent evaluations of the century-long changes in the UV index (erythemal daily maximum dose rate in mW/m
2 divided by 25 mW/m
2) and the plant growth-weighted irradiance were discussed in [
9]. The authors considered the evolution of factors (1)–(4) according to three Shared Socioeconomic Pathway (SSP) scenarios—SSP1-2.6, SSP3-7.0, and SSP5-8.5—in the model projections from CMIP6 modeling outputs for the 21st century. The most significant negative changes in the UV index occurred at middle and high latitudes in both hemispheres under the SSP5-8.5 scenario, primarily due to the super-recovery of the ozone layer. However, in the tropics, TOC decreases due to changes in dynamics, which leads to a small increase in the UV index (~2%) over some regions. At high and partly middle latitudes of both hemispheres, changes in cloudiness parameters and surface albedo lead to a significant decrease in surface erythemal radiation for all seasons. However, July is an exception because the attenuation of cloudiness significantly increases the UV index over Europe, Asia, and North America, despite an increase in total ozone content over these areas.
Along with this, the variations of surface UV radiation, which can have beneficial effects (vitamin D production in the human body skin (UVpD)), may be of significant interest [
10,
11,
12,
13,
14,
15]. According to modern research, human beings require significantly higher doses of vitamin D for optimal functioning than was previously believed [
16]. These adequate levels of vitamin D cannot be solely obtained from food and dietary supplements, and exposure to sufficient UVpD is also required. Consequently, a decrease in surface UV radiation during the 21st century could result in a considerable increase in the number of people worldwide who are deficient in vitamin D.
However, only a limited number of studies have been devoted to the possible changes in UVpD during the 21st century. In [
14], the influence of TOC and AOD variations on UVpD irradiance was investigated over Europe for two RCP scenarios in the 21st century (RCP-2.6 and RCP-8.5). It was found that UVpD doses are very sensitive to TOC variability for RCP-8.5. The decrease in UVpD can reach up to 20% for all seasons and latitudes from 2006 to 2100 as a result of ozone layer recovery according to the Montreal Protocol implementation [
17]. The exception is the summertime period when decreasing UVpD is minimal due to the decline in aerosol loading, which compensates for the negative effect of the TOC recovery on the production of vitamin D.
Fountoulakis and Bais [
15] evaluated UVpD changes at high latitudes in the Northern Hemisphere between 2010–2020 and 2085–2095 according to RCP-4.5 and RCP-8.6 scenarios. Their analysis included variations of the total ozone column, surface reflectivity, and aerosol optical depth based on data from the corresponding CMIP5 model runs. They found a substantial decrease in UVpD fluxes (up to 50%) for clear-sky conditions (only the effect of the TOC variations was considered) compared to cases when the changes in all atmospheric factors mentioned above were considered.
In all published papers, the uncertainties and differences between models were estimated as rather high; therefore, more models should be applied to reach a better understanding of the future UVpD changes and responsible processes. To achieve this goal, a century-long (2000–2099) numerical experiment was performed using the Earth’s system model SOCOLv4 [
18], forced by the SSP5-8.5 scenario for the evolution of atmospheric greenhouse gases and ozone-depleting substances in the 21st century [
19]. This model helps to assess global changes in daily doses of surface UV radiation, which is important for the production of vitamin D, through to the end of the 21st century as a result of the corresponding variations of TOC, cloud parameters, and surface reflectivity. In this paper, we limited our consideration to the influence of the main radiation factors on changes in UV radiation: (1) variations in TOC, (2) changes in cloud parameters (cloud liquid water column and total cloud cover), and (3) surface albedo. The corresponding changes in the aerosol content and NO
x (nitrogen oxides) concentration in the atmosphere of urbanized territories may also significantly impact the variations in UVpD during the 21st century. However, there are currently no reliable data on the likely changes in the atmospheric concentration mentioned above. For example, powerful explosive volcanic eruptions can substantially disturb the atmospheric aerosol layer during the 21st century [
2]. Also, UVpD changes have a spectral response mainly in the UV-B (290–315 nm wavelengths) range of the solar spectrum and consequently depend on the first line of the TOC, surface reflectivity, and cloudiness variation [
3,
15]. Therefore, in the model experiment performed, the concentrations of nitrogen oxides and atmospheric aerosol were set by their values at the beginning of the 21st century [
15]. The values of factors (1)–(3) obtained from SOCOLv4 in the model experiment were used as input information in the FASTRT (Fast simulations of downward UV doses, indices, and irradiances at the Earth’s surface) model for calculating radiation fluxes on the surface [
10] to estimate doses of UVpD radiation over the two time intervals (2015–2024 and 2090–2099) for each model grid cell.
Further, we evaluated the contributions of each factor from (1)–(3) to the changes in UVpD doses from the period of 2015–2024 to the period of 2090–2099. All cells of the SOCOLv4 surface model grid have been grouped into geographical regions. In each region, all factors affecting UVpD doses changed in the same direction by the end of the 21st century. This approach enabled us to identify the areas of the Earth’s surface most sensitive to global warming regarding UVpD irradiance. Additionally, it allowed us to accurately estimate the UVpD response to each factor in these regions.
3. Results and Discussion
Model calculations conducted with the SOCOLv4 for the SSP5-8.5 scenario indicate that the 21st century will witness substantial changes in total ozone content, cloud parameters, and surface albedo in the UV radiation spectral range.
Figure 1 illustrates the geographical distribution of the monthly and ensemble-averaged TOC evolution between 2015–2024 and 2090–2099 for January (top-left), April (top-right), July (bottom-left), and October (bottom-right). In both hemispheres outside the tropics, TOC is projected to increase in the middle latitudes by 5–20% in January, April, and July and 10–20% in October. Notably, during the 2090–2099 period, the ozone “hole” over Antarctica in October is anticipated to be filled with excess, and the TOC changes will be up to 80% over the South Pole region. This super-recovery is significantly influenced by the Montreal Protocol’s restrictions on ozone-depleting substances [
17], alongside changes in middle atmosphere temperature and circulation.
Conversely, in tropical latitudes, there is a 2–3% decrease in TOC between 2015–2024 and 2090–2099, attributed to strengthened meridional circulation leading to increased ascending motions in the upper troposphere and lower stratosphere, causing a decline in ozone column content in the tropics [
25]. This can be explained by the fact that, if the strengthening of the meridional circulation contributes to the ozone layer recovery in the middle and high latitudes, along with a decrease in atmospheric concentrations of halogen-containing ODSs and a decrease in temperature, then this strengthening in the tropics leads to an increase in ascending atmospheric currents in the upper troposphere and lower stratosphere, and thus, a predominant decrease in ozone concentration in the 21st century [
25].
Figure 2 illustrates the latitude–longitude distribution of the monthly and ensemble mean changes in LWCC between 2015–2024 and 2090–2099 for January (top-left), April (top-right), July (bottom-left), and October (bottom-right). It shows that, except in the low and partly middle latitudes of both hemispheres and for all seasons, the liquid water column of clouds increased significantly (by 50% on average and up to 100% for individual regions) during the 21st century. The exception is the middle latitude over land in July (North America, Europe, and Russia in NH and Southern America in SH), where the projected cloud liquid water column decreases significantly by 2090–2099. These LWCC behaviors are consistent with the climate change influence on cloudiness [
26] and are in good qualitative agreement with the corresponding results from projection outputs of CMIP6 models for the SSP5-8.5 scenario [
27]. The corresponding changes in the total cloud cover between 2015–2024 and 2090–2099 for January (top-left), April (top-right), July (bottom-left), and October (bottom-right) are shown in
Figure A1 (
Appendix A). The geographical distributions of these changes are close to the LWCC changes (
Figure 2), but the magnitudes of the total cloud cover variations are significantly smaller in size than the LWCC changes. Also, the FASTRT UVpD doses depend linearly on the total cloud cover (see Equation (1)), but their dependence on the LWCC values is exponential. Thus, UVpD sensitivity is substantially higher than LWCC changes in comparison with the corresponding sensitivity to the total cloud cover.
Figure 3 depicts the changes in the surface reflectivity for UV radiation during the 21st century for January (top-left), April (top-right), July (bottom-left), and October (bottom-right). The figure indicates a notable decline in the monthly and ensemble mean albedo values across this period. This decrease is primarily driven by the poleward movement of the snow cover boundary, which is linked to rising surface air temperatures and the overall warming attributed to the greenhouse effect (North America, Europe, and Asia in January and April). Furthermore, a substantial factor contributing to this reduction in albedo is the diminishing of the ice-covered area observed in both hemispheres. This trend is especially pronounced in the Northern Hemisphere in July and October, as shown in the bottom panels of
Figure 3. By the end of the 21st century in autumn, the Arctic Ocean is projected to be largely ice-free, with glaciation becoming seasonal [
28]. This shift causes a decline in the UV radiation levels at the surface, as lower albedo leads to increased absorption of short-wavelength solar irradiance and diminishes their multiscattering in the surface layer.
Figure 4 for January (top-left) and April (bottom-left) and
Figure 5 for July (top-left) and October (bottom-left), respectively, depict the latitude–longitude distributions of changes in the daily dose of UVpD radiation between 2015–2024 and 2090–2099, considering the corresponding changes in all radiation factors, which are considered. At the same time, here and further, only statistically significant changes in doses of UVpD during the 21st century are shown with a significance of more than 90%. It can be seen from the figures that the daily dose of UVpD reaches its maximum decrease at the middle and high latitudes of both hemispheres. The evolution of radiation factors that weaken the level of UV radiation at the surface (increasing in TOC and liquid water column of clouds, decreasing in albedo) contributes to the reduction in the daily UV radiation dose by 20–50% in the middle latitudes of the Northern Hemisphere and by 10–30% in the Southern Hemisphere.
To evaluate the individual contribution of TOC, LWCC/total cloud cover, and surface albedo, three additional simulations with FASTRT (UVSPEC) were performed. In addition to calculating the impact of all factors for the 2090–2099 time period (referred to as ALL), which is described in
Section 2.2, we also calculated the daily dose when only one of these factors applied to the 2090–2099 range, while the other two factors were maintained at their levels of the 2015–2025 time period. The results of these runs are named TOC (only TOC presents the 2090–2099 conditions), H2O (only the total cloud cover and LWCC present the 2090–2099 conditions), and ALB (only the surface albedo presents the 2090–2099 conditions).
Further, to correctly assess the contribution of various factors to the change in UVpD, for each month, we divided all cells of the model grid into two main groups: a group in which all the factors act toward reducing the daily dose of UVpD (named
); and a group of cells in which all the factors increase the daily dose (named
). It should be noted that the ALB effect associated with the melting of sea ice and snow cover is completely negative for changes in UVpD. Therefore, all ALB cells fall into group (1). Thus, the following groups of model cells are calculated for each month:
Figure 4 shows the changes in daily doses of UVpD for runs of ALL (top-left for January, bottom-left for April) and
(bottom-left for January, bottom-right for April). In just the same order, the UVpD dose variations for ALL and
runs are presented in
Figure 5, but for July and October instead of January and April, respectively. By comparing the ALL and SUM distributions of the UVpD values in
Figure 4 and
Figure 5, we can identify geographical areas where all factors influence UVpD changes in either a negative (ALB impact is always negative) or a positive direction. This is true for geographical regions where ALL and SUM distributions are closely aligned. From the figures, we can see that the ALL and
approaches yield fairly similar results in most cells of the horizontal model grid.
However, there are some areas where UVpD dose changes in both the ALL and
show significant differences. The model grid cells in these regions do not fall into either of groups (2) or (3). In these areas, the TOC/ALB and H2O factors impact UVpD dose variations in opposite ways, compensating for each other’s effects. Specifically, the influence of H2O is positive, which overlaps with the negative impact of TOC/surface albedo. These regions are notably found in Southern Africa and South America in January, and Southern America in April (
Figure 4, top and bottom, respectively). However, this situation is particularly evident in July over land in the mid-latitudes of North America, Europe, and Russia. The total ozone column increases between 2015–2024 and 2090–2099 (see
Figure 1, bottom-left), and the cloud parameters (LWCC and total cloud cover) decrease, which means the clouds become thinner and their fractions are reduced (see
Figure 2, bottom-left, and
Figure A1, bottom-left). Thus, the TOC changes over the 21st century led to a diminution of UVpD doses, but the H2O changes led to an increase in them. The TOC and H2O effects compensate for each other, but the positive changes in UVpD are clearly visible for the ALL group (
Figure 5, top-left), especially for Europe and North America. It means the changes in cloud parameters have a much greater impact on UVpD than TOC, resulting in a substantial increase (0–30%) in daily doses of UVpD by the end of the 21st century (
Figure 5, top-left).
By dividing all model grid cells at the surface into groups (2) and (3), we identify the geographical areas where all factors have the same sign of their impact on the UVpD variations (positive or negative). In these regions, the surface UVpD doses are particularly sensitive to climate change, as the factors do not compensate for each other but instead amplify each other’s effects. Additionally, this grouping allows for more accurate attribution of the influence of each factor on the long-term changes in the surface UVpD irradiance.
Figure 6 and
Figure 7 illustrate the relative contribution of variations in TOC, cloud parameters, and surface albedo to the changes in the daily dose of UVpD between the periods 2015–2024 and 2090–2099. This is shown as a percentage for July (on the left side) and October (on the right side). By “relative contribution”, we refer to the ratio of daily dose changes from one factor to the absolute values of the daily dose changes from all factors. For the
group, these are TOC/abs(
), H2O/abs(
), and ALB/abs(
), while for the
group, these are TOC/abs(
) and H2O/abs(
).
The percentage contributions of the factors from the
group are shown in
Figure 6 for TOC (top-left), H2O (center-left), and ALB (bottom-left) in July and for TOC (top-right), H2O (center-right), and ALB (bottom-right) in October. An analysis of the data shows that significant reductions in daily UV doses have occurred in July and October during the 21st century. These reductions are observed across all factors and are particularly evident in the middle and high latitudes of both hemispheres.
The primary factor affecting changes in the daily dose of ultraviolet radiation (UVpD) is the recovery of the ozone layer, which accounts for 50 to 80% of these changes. In contrast, changes in cloud cover contribute 20 to 30%, while alterations in surface reflectivity contribute no more than 20%. However, an exception exists in the polar regions of the Northern Hemisphere, where changes in albedo can reach 50%. This is linked to the diminishing reflective properties of the surface due to the loss of Arctic Ocean ice cover during the warmer half of the year by the end of the 21st century. Similar findings apply to the attribution of UVpD changes observed in January and April (see
Appendix A,
Figure A2). It is also important to consider the seasonal shift between the Northern and Southern Hemispheres, which switch from July to January and from April to October. During polar night conditions, low UVpD values and minor changes in the UVpD dose result in significant uncertainty in the attribution results. The percentage contributions of the factors from the
group are presented in
Figure 7 for TOC (top-left) and H2O (bottom-left) in July and for TOC (top-right) and H2O (bottom-right) in October. By the end of the 21st century, there is an increase in daily UVpD doses, primarily in the low latitudes of both hemispheres, including Southeast Asia, the Hawaii region, and Southern America. The main factor contributing to the variations of the daily UVpD doses is the LWCC decrease, which accounts for the 60–80% increase in UVpD doses. The corresponding contribution of the TOC changes in the UVpD dose increase does not exceed 20–40%. The exclusions are part of the Hawaii region and the Central Pacific Ocean, where the TOC changes are the primary drivers of the UVpD variation during the 21st century.
In January and April, the total increases in UVpD doses from all factors are negligible from the years 2015–2024 to 2090–2099 (see
Appendix A,
Figure A3).
4. Summary and Conclusions
The SOCOLv4 model of the Earth’s climate system and the FASTRT (UVSPEC) code for calculating radiation fluxes in the atmosphere were used to estimate changes in daily doses of surface UV radiation necessary for vitamin D production, considering the Earth’s climate and atmospheric ozone layer changes in the 21st century. From the model experiments driven by the SSP5-8.5 scenario of greenhouse gas concentrations and the WMO scenario of reducing the atmospheric content of ozone-depleting substances, significant changes in radiation factors affecting the surface daily doses of UVpD (TOC, cloud parameters, and surface albedo) have been obtained.
As a result of the Montreal Protocol implementation [
17], atmospheric ozone levels are expected to increase by 5–15% in the middle latitudes and up to 80% in the polar regions from the period 2015–2024 to the period 2090–2099. However, in lower latitudes, a corresponding decline in total ozone column values of 2–3% is anticipated, primarily due to climate warming and the intensification of meridional atmospheric circulation.
The application of the SSP5-8.5 scenario leads to an increase in the liquid water column and total cloud cover by the end of the 21st century, particularly in middle and high latitudes. However, a decrease in surface albedo is expected due to the reduced land snow cover and loss of sea ice. The decline in albedo will be especially noticeable in the high latitudes of the Northern Hemisphere, mainly as a result of melting sea ice in the Arctic Ocean during the summer and autumn seasons. Additionally, significant reductions in cloud liquid water column are anticipated in certain areas of lower latitudes by the years 2090–2099.
The output from the model runs provided evaluations based on the relative contributions of variations in total ozone content, cloud parameters, and surface albedo to the corresponding changes in ultraviolet radiation (UVpD) during the 21st century. The comparison of the obtained results with the evaluations of the UVpD changes at the end of the 21st century over Europe [
14] and over the high and middle latitudes of the NH [
15] demonstrates a strong qualitative agreement. Consequently, we can draw the following conclusions regarding the projected changes in UVpD at the surface:
In the middle and high latitudes of both hemispheres across all seasons, changes in the above-mentioned radiation factors are expected to lead to a decrease in UVpD daily doses by 20–80% from the years 2015–2024 to 2090–2099. The primary contributor to the reduction in UV doses is the variation in total ozone content (TOC), accounting for 50–80% of the decrease. This effect is further supplemented by the influence of cloud parameters, which contribute an additional 20–30%, while variations in surface albedo contribute less than 20%. However, in the polar regions of the Northern Hemisphere, this contribution can reach up to 50%.
The most pronounced exception to changes in UVpD behavior occurs during the summer months. In July, across the mid-latitudes of North America, Europe, and Russia, the effects of changes in cloud parameters and total ozone column (TOC) tend to compensate for each other. However, the diminishing impact of LWCC/total cloud cover significantly outweighs the recovery effect of the TOC. As a result, this leads to a substantial (up to 30%) increase in daily UVpD doses by the end of the 21st century.
In the tropics of both hemispheres, during July and October, the combined effects of the TOC and LWCC/total cloud cover changes are expected to increase UVpD daily doses by 30–40% from the years 2015–2024 to 2090–2099 in certain areas of the lower latitudes (South-East Asia, the Hawaii region, and Southern America,
Figure 7).
These findings highlight the significant public health concerns associated with decreased UV exposure, particularly regarding vitamin D synthesis and overall health. As we navigate a world where outdoor activities may be limited due to lifestyle changes or environmental factors, it is imperative to recognize and address the ramifications of decreased UV exposure on public health, ensuring that communities are informed and equipped to maintain optimal health conditions. Therefore, understanding and addressing the implications of decreased UV exposure is vital for promoting long-term well-being in the population. The impact of decreasing UV levels on human health is not covered in this discussion, as it requires insights from experts in various fields, including biology, medicine, and nutrition. It is important to clarify that we do not make predictions. Instead, we concentrate solely on the most severe scenario outlined by the Intergovernmental Panel on Climate Change (IPCC) to inform society about the potential negative consequences of future climate conditions. The likelihood of this scenario is uncertain; therefore, its accuracy cannot be assessed.