1. Introduction
The understanding of storm properties and processes that induce differing charge structures is important due to its relation to storm severity [
1,
2,
3,
4], polarity of cloud-to-ground lightning which affects lightning safety [
5], lightning-induced wildfires [
6], NOx production [
7], and severe storm nowcasting [
2,
8]. The region of central Argentina near Cordoba has some of the most intense thunderstorms in the world [
9], and has a storm charge structure archetype uncommon in U.S. storms, with a predominance of negative intra-cloud lightning in the low-levels and no lightning-active upper positive charge layer [
10]. Hence, studying charge structure in thunderstorms in different regions of the world expands our understanding of the conceptual model of thunderstorm charging.
Specific internal thunderstorm properties and processes are conducive to the distribution of regions of charge with a dominant net polarity. A region of charge is formed in the mixed-phase zone between the 0 °C and −40 °C isotherm levels of a thunderstorm, and a region of charge with the opposite polarity is formed above it, at or just above the −40 °C isotherm level. These two main regions of charge constitute the dominant dipole charge structure of a storm [
11]. A third charge region with opposite polarity to the one in the mixed-phase layer is sometimes present in the lower levels, leading to a tripole charge structure [
12]. A mixed-phase layer with dominant negative charge and positive charge aloft is referred to as a normal charge structure [
11,
13], while a net positive charge region in the mixed-phase zone with negative charge aloft is called an anomalous charge structure [
14,
15,
16,
17]. The main mechanism that induces particle-level charging is the non-inductive charging mechanism [
18,
19,
20], which is independent of pre-existing electric field effects on particles and is able to explain the generation of the main dipole and tripole charge structures. In the mixed-phase layer, rebounding collisions of graupel (and hail) particles with ice crystals in the presence of supercooled cloud water lead to charge exchange between hydrometeors. In a mixed-phase environment with high temperature and high cloud liquid water content (LWC), rebounding collisions between graupel and ice crystals lead to net positive charging of graupel and net negative charging of ice crystals [
18,
19,
21,
22,
23]. For low temperature and low LWC in the mixed-phase zone, graupel acquires negative charge, while ice crystals acquire positive charge during rebounding collisions. Additionally, particles that grow faster by diffusion during this process end up with positive charge [
24,
25,
26]. Differential particle terminal fall speeds and vertically varying updrafts lead to storm-scale charge separation in which graupel typically resides in the mixed-phase layer, and smaller ice crystals are carried to near the cloud top, forming the main charge layers of a dipole. The lower positive charge layer of a normal tripole can be explained by this mechanism, as graupel will assume positive charge at warm temperatures [
18,
27].
Because cloud LWC in the mixed-phase layer is a vital ingredient in inducing a storm’s dominant charge structure, a careful exploration of this feature is needed. An increase in LWC in the mixed-phase layer can occur through kinematic and microphysical processes inside a thunderstorm. Vertical motion can induce an upward transport of liquid droplets originally formed in the warm region of the cloud. As cloud droplets can retain their liquid phase in sub-freezing temperatures, increased updraft strength is thought to be associated with an increase in the cloud LWC in the mixed-phase layer [
28,
29].
Graupel and hail form through accretion of cloud water droplets to an ice particle, which releases latent heat. If the rate of latent heat release is insufficient, the graupel surface remains with temperature near to 0 °C, warmer than the environmental temperature. Hence, a droplet does not freeze in contact with graupel, and the liquid water spreads out through the graupel surface, which is called the wet-growth regime. The formation of spongy hail may occur when the hail particle consists of a mix of ice and water. Under the wet-growth regime, particle density can be as high as 0.91 g cm
−3 [
30]. For colder temperatures and lower LWC, a droplet may immediately freeze in contact with the graupel surface, which leads to the dry-growth regime. Under dry growth, air may get trapped inside graupel/hail, reducing the density of the particle, which can be as low as 0.05 g cm
−3 [
31]. A particle density value of 0.55 g cm
−3 can serve as a cutoff value for low-density and high-density graupel particles [
32]. On the basis of the temperature and LWC conditions, the Schumann–Ludlam Limit separates the wet- and dry-growth regimes [
33].
The direct quantitative estimate of cloud LWC through remote sensing means is a challenge [
34], and therefore qualitative and indirect methods are often used to infer the presence of high cloud LWCs. Reflectivity (Z
h) measurement by radar is proportional to the sixth power of a particle’s diameter in the Rayleigh scattering regime. Hence, the coexistence of particles of different sizes leads to a larger signal contribution from the largest particles. Graupel and hail hydrometeors that are grown from cloud liquid water or riming can be inferred from radars. The size and tumbling effects of hail [
35] lead to large reflectivity and near zero differential reflectivity (Z
dr) for S-band [
36,
37]. For C-band radars, Rayleigh scattering is not valid for particles of about 5 mm or greater in diameter, then resonance effects from large raindrops and melting hail with a water torus and stable orientation [
38] causes Z
dr to be greater than 3 dB, and the correlation coefficient to be lower than 0.95 [
38,
39,
40]. The dielectric effect of water around the hail particle also contributes to the increase in Z
h and Z
dr. The most likely dominant hydrometeor type over a radar pixel can be obtained from hydrometeor classification algorithms [
41,
42]. From dual-polarization radar measurements, most current algorithms use fuzzy logic to obtain the dominant or bulk hydrometeor in the radar resolution volume such as hail, high-density graupel, low-density graupel, ice crystals, rain, and aggregates, among others [
32,
43].
High LWC leads to an increase in graupel and hail particles size and density. Then, in order to obtain a signal of elevated supercooled cloud LWC using dual-polarization radar data, the mass and volume of riming precipitation ice with high density are estimated. A hydrometeor classification algorithm can be used to obtain regions inside thunderstorms with dominant graupel and hail, and storm volumes and precipitation masses of graupel and hail can be calculated from the measured reflectivity [
44,
45]. It is hypothesized that relatively more high-density graupel and hail within the storm will indirectly indicate relatively elevated supercooled cloud LWC. On the other hand, storms with significant mass of low-density graupel would be indicative of low LWC. Hence, as high supercooled cloud LWC is thought to be associated with positive charging of graupel (and hail) in the mixed-phase layer of anomalous storms, we use these radar metrics to indirectly and qualitatively infer the presence of relatively elevated LWC and associate them with thunderstorms with archetypal charge structures [
3,
4]. An additional analysis of the reflectivity data from events is performed, as this radar variable is proportional to the sixth power of particle diameter, being a suitable measure of large particles that grow in benefit from high supercooled cloud LWC during riming. It is thought that anomalous storms would have higher reflectivities caused by hail grown from high LWCs, which also induced the rimer to charge positively [
3,
28]. Well-known metrics for updraft intensity possibly associated with the enhancement of LWC in the mixed-phase layer include echo-top height [
46,
47,
48,
49] and the identification of Z
dr columns of enhanced Z
dr values associated with the lifting of large oblate rain drops to sub-freezing temperatures [
50,
51,
52,
53,
54]. Kinematic and microphysical conditions for the low-level anomalous storms unique to Argentina are explored and compared to other charge structure archetypes in order to understand the processes that lead to the development of this charge structure.
4. Discussion
In this study, we made the assumption that elevated supercooled cloud LWC in the mixed-phase layer encourages more high-density graupel and hail, which contributes to their total mass and storm volumes. Hence, the mass and volume of high-density rimer particles would be a signature of high supercooled cloud LWCs. Because supercooled cloud LWC is thought to contribute to the charging polarity of ice particles through the non-inductive charging mechanism [
18,
19,
20], we hypothesized that these radar-inferred parameters would indirectly indicate LWCs leading to storms with anomalous or normal charge structure. An investigation of the statistical distribution of reflectivity data for each charge structure archetype was also performed, since reflectivity is closely associated with the diameter of hydrometeors. We hypothesized that high values of reflectivity would be associated with large hail production as grown in the presence of elevated supercooled cloud LWC [
36,
37,
40], which would therefore favor positive charging of rimed precipitation ice and the formation of anomalous charge structures in the mixed-phase layer. Radar-inferred kinematic proxy parameters of updraft strength, namely echo top and Z
dr column heights, were also explored. These are hypothesized to contribute to the lifting of cloud liquid water to the mixed-phase layer [
28,
29], the growth of high-density graupel and hail in the mixed-phase layer, positive charging of the rimers, and the generation of anomalous charge structures.
Anomalous datasets for mass of hail, fraction of hail mass in relation to all rimer particles, and volume of hail presented larger values than low-level anomalous and normal datasets, most of them with high statistical confidence. When considering high-density graupel together with hail in these parameters, similar results were obtained, but with lower statistical confidence, i.e., the differences between datasets were less clear. Other studies found the co-location of positive charging in the mixed-phase zone associated with rimer particles [
75] or ice mass possibly associated with graupel [
3]. In this study, hail was found to be a better signature for inferring the presence of high supercooled cloud LWCs than considering high-density graupel together with hail. This finding is consistent with the hypothesis that anomalous storms have higher LWC in the mixed-phase layer, leading to hail growth and positive charging of these and other rimed particles.
Low-level anomalous datasets presented similar values to anomalous datasets, and higher-than-normal values for the following parameters: mass of hail from 0 °C to −10 °C, fraction of mass and volume of hail from 0 °C to −20 °C, fraction of mass of high-density graupel and hail above −20 °C, fraction of volume of hail from 0 °C to −10 °C and above 0 °C, and fraction of volume of high-density graupel and hail above −20 °C and above 0 °C. These results suggest that sufficiently elevated supercooled cloud LWCs charge rimed precipitation in the lower region of the mixed-phase zone for LLA, while for normal storms, lower LWC favors the growth of low-density graupel in the mixed-phase layer, which contributes to negative charging of rimed precipitation. Some parameters indicated LWCs for low-level positive charging for LLA storms. The elevated temperatures also contribute to positive charging of rimer particles in the lower portion of the LLA mixed-phase layer, but elevated LWC increases the magnitude of positive charging to rimer particles [
18,
20,
27].
Anomalous storms presented a higher frequency of high reflectivity values at all altitudes when compared to LLA and normal storms, as displayed in the CFAD analysis. With a similar outcome, Ref. [
76] found that Colorado storms with flash rate mode in the mixed-phase layer (anomalous) had higher reflectivity values in this layer. This was an expected result, as higher supercooled cloud LWC contributes to the growth of large hail and positive charging in the mixed-phase layer for these events. LLA storms presented lower frequency of large reflectivities when compared to normal storms due to the shallow nature of these events.
Kinematic proxy parameters showed that LLA storms had weaker updrafts than other charge structure categories. This result is reasonable, because the transport of liquid water from the warm cloud depth to the mixed-phase layer is limited to the lower portion of this zone, contributing to charging of graupel and hail in that region. No strong vertical development occurs for these events, which contributes to limited or absent upper positive charge being developed. Ref. [
77] analyzed the environmental conditions in Argentina that contributed to LLA storms, and they also found weak inferred updrafts from the convective available potential energy (CAPE) parameter, although their LLA sample size was small. In [
77], no distinction between anomalous and normal storm datasets was found for kinematic proxy parameters indicative of updraft strength using both soundings and reanalysis datasets. Past studies observed that anomalous charge structure storms have stronger updrafts than normal storms [
28,
78], while for an environmental analysis of storms in Argentina based on radiosonde data, anomalous storms had lower CAPE than normal storms [
77]. Kinematic effects shown in this study alongside the results presented in [
77] suggest that updrafts are not an important factor for inducing high LWCs in the mixed-phase zone and anomalous storms, but other factors such as dry low-level humidity and shallow warm cloud depth are more crucial in suppressing growth of droplets in the warm cloud depth, leading to more small droplets that can be lifted, contributing to positive charging of rimer particles in the mixed-phase zone, and anomalously charged thunderstorms to develop.
Figure 11 shows the schematics of normal, anomalous, and LLA storms near Cordoba, Argentina, with their main regions of charge, hydrometeors, and updrafts. Concepts explained above such as anomalous storms having larger amounts of cloud supercooled liquid water caused by higher LCL, lower 0 °C height, and shallower warm cloud depth [
77], leading to higher precipitation ice mass and positive charging of rimer particles, can be observed. For all charge structure archetypes, rimer particles (graupel and hail) were the main carriers of charge for the lower charge region of the main dipole, while ice crystals were the carriers of charge for the upper charge region of the dipole. Charging on other particles and possible extra charge layers are speculated to be secondary in relation to the main carriers of charge on the two regions of charge.
Due to the unique occurrence of LLA storms in Argentina, their main characteristics are hereby emphasized (
Figure 11), with weaker updrafts, and higher LWC in the lower portion of the mixed-phase layer, leading to higher precipitation ice mass and positive charging of rimer particles in this layer compared to normal storms.
The microphysical and kinematic characteristics of LLA events were explored in relation to anomalous and normal storms. As pointed out by [
10], this charge structure is uncommon in U.S. storms; hence, continued investigation of these events is justified. In the future, we will perform a careful case study of a well-observed storm with this charge structure that was within the dual-Doppler lobes of mobile radars operating during the RELAMPAGO intensive operational period [
58].