Preparation and Characterization of di- and Tricarboxylic Acids-Modified Arabinogalactan Plasticized Composite Films
Abstract
:1. Introduction
2. Materials and Methods
2.1. Reagents
2.2. Synthesis of the Arabinogalactan Derivatives with the Polybasic Carboxylic Acids
2.3. Physicochemical Study
2.3.1. Gel Permeation Chromatography
2.3.2. Fourier-Transform Infrared Spectroscopy
2.3.3. X-ray Diffraction
2.3.4. Scanning Electron Microscopy
2.3.5. Thermogravimetry Analysis
2.3.6. Sorption Capacity Analysis
3. Results
3.1. Gel Permeation Chromatography
3.1.1. Thermal Drying of the Arabinogalactan Films
3.1.2. Freeze-Drying of the Arabinogalactan Films
3.2. Fourier-Transform Infrared Spectroscopy of the Arabinogalactan Films
3.3. X-ray Diffraction Analysis of the Arabinogalactan Films
3.4. Scanning Electron Microscopy of the Arabinogalactan Films
3.5. Thermogravimetry Analysis of the Arabinogalactan Films
3.6. Sorption Capacity of the Arabinogalactan Films
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Sample | Mn, g/mol | Mw, g/mol | PDI |
---|---|---|---|
Initial AG | 9101 | 11,580 | 1.27 |
AG/AA | 8758 | 11,619 | 1.33 |
AG/CA | ‒ | ‒ | ‒ |
AG/OA | 8484 | 10,567 | 1.25 |
AG/SA | 15,344 | 33,346 | 2.17 |
Samples | Mn, g/mol | Mw, g/mol | PDI |
---|---|---|---|
Initial AG | 9101 | 11,580 | 1.27 |
AG/AA | 8219 | 10,138 | 1.23 |
AG/CA | 8547 | 10,381 | 1.22 |
AG/OA | 8279 | 10,266 | 1.24 |
AG/SA | 8209 | 10,222 | 1.25 |
Sample | Drying Method | Residue at 700 °C, % | |||
---|---|---|---|---|---|
AG | ‒ | 19.89 | |||
AG/AA | Thermal drying | 37.26 | |||
AG/CA | 36.12 | ||||
AG/OA | 34.60 | ||||
AG/SA | 37.38 | ||||
AG/AA | Freeze-drying | 34.14 | |||
AG/CA | 33.56 | ||||
AG/OA | 32.29 | ||||
AG/SA | 37.68 |
Sample | Concentration, g/L | Sorption Efficiency (H), % | |
---|---|---|---|
Control | 0.00625 | ‒ | |
AG/AA | Thermal drying | 0.003307 | 70.64 |
AG/CA | 0.003438 | 67.49 | |
AG/OA | 0.005099 | 27.63 | |
AG/SA | 0.003399 | 68.43 | |
AG/AA | Freeze-drying | 0.004028 | 53.33 |
AG/CA | 0.004805 | 34.68 | |
AG/OA | 0.004380 | 44.88 | |
AG/SA | 0.002812 | 82.52 |
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Malyar, Y.N.; Borovkova, V.S.; Kazachenko, A.S.; Fetisova, O.Y.; Skripnikov, A.M.; Sychev, V.V.; Taran, O.P. Preparation and Characterization of di- and Tricarboxylic Acids-Modified Arabinogalactan Plasticized Composite Films. Polymers 2023, 15, 1999. https://doi.org/10.3390/polym15091999
Malyar YN, Borovkova VS, Kazachenko AS, Fetisova OY, Skripnikov AM, Sychev VV, Taran OP. Preparation and Characterization of di- and Tricarboxylic Acids-Modified Arabinogalactan Plasticized Composite Films. Polymers. 2023; 15(9):1999. https://doi.org/10.3390/polym15091999
Chicago/Turabian StyleMalyar, Yuriy N., Valentina S. Borovkova, Alexander S. Kazachenko, Olga Yu. Fetisova, Andrey M. Skripnikov, Valentin V. Sychev, and Oxana P. Taran. 2023. "Preparation and Characterization of di- and Tricarboxylic Acids-Modified Arabinogalactan Plasticized Composite Films" Polymers 15, no. 9: 1999. https://doi.org/10.3390/polym15091999