Electrically Self-Healing Thermoset MWCNTs Composites Based on Diels-Alder and Hydrogen Bonds
Abstract
:1. Introduction
2. Materials and Methods
2.1. Functionalization of Polyketone with Furan and Propyl Alcohol Groups
2.2. Preparation of PK30xFUyA2Pz/B-Ma/MWCNT Composite
2.3. Characterization
3. Results and Discussion
3.1. PK Functionalized with Furan and Propyl Alcohol Groups Via Paal-Knorr Reaction
3.2. PK-Fu-A2P / B-Ma/ MWCNT Composite
3.3. Mechanical Properties
3.4. Electrical Conductivity Properties
3.5. Thermal and Electrical Self-Healing
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample | x (%) | y (%) | z (%) | CO (%) | Mn (×103 M) | Mw (×103 M) | PDI |
---|---|---|---|---|---|---|---|
PK30 | 100 | - | - | - | 2.4 | 5.4 | 2.2 |
PK30x-FUy | 35 | 65 | - | 65 | 2.1 | 5.4 | 2.6 |
PK30x-FUy-A2Pz | 28 | 55 | 17 | 72 | 1.8 | 5.0 | 2.7 |
PK30x-FUy-A2Pz | 27 | 47 | 26 | 73 | 2.0 | 5.4 | 2.7 |
PK30x-FUy-A2Pz | 28 | 36 | 36 | 72 | 1.9 | 5.3 | 2.7 |
PK30x-A2Pz | 28 | - | 72 | 72 | 1.7 | 4.1 | 2.4 |
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Macedo R. Lima, G.; Orozco, F.; Picchioni, F.; Moreno-Villoslada, I.; Pucci, A.; Bose, R.K.; Araya-Hermosilla, R. Electrically Self-Healing Thermoset MWCNTs Composites Based on Diels-Alder and Hydrogen Bonds. Polymers 2019, 11, 1885. https://doi.org/10.3390/polym11111885
Macedo R. Lima G, Orozco F, Picchioni F, Moreno-Villoslada I, Pucci A, Bose RK, Araya-Hermosilla R. Electrically Self-Healing Thermoset MWCNTs Composites Based on Diels-Alder and Hydrogen Bonds. Polymers. 2019; 11(11):1885. https://doi.org/10.3390/polym11111885
Chicago/Turabian StyleMacedo R. Lima, Guilherme, Felipe Orozco, Francesco Picchioni, Ignacio Moreno-Villoslada, Andrea Pucci, Ranjita K. Bose, and Rodrigo Araya-Hermosilla. 2019. "Electrically Self-Healing Thermoset MWCNTs Composites Based on Diels-Alder and Hydrogen Bonds" Polymers 11, no. 11: 1885. https://doi.org/10.3390/polym11111885