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Polymers 2019, 11(1), 113; https://doi.org/10.3390/polym11010113

Integrating Nano-Cu2[email protected] into In Situ Polymerized Polyethylene Terephthalate (PET) Fibers with Enhanced Mechanical Properties and Antibacterial Activities

State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, International Joint Laboratory for Advanced Fiber and Low-dimension Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
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Received: 4 December 2018 / Revised: 5 January 2019 / Accepted: 7 January 2019 / Published: 10 January 2019
(This article belongs to the Special Issue Polymer Matrix Composites for Advanced Applications)
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Abstract

The approach of in situ polymerization modification has proven to be an effective route for introducing functions for polyester materials. In this work, Cu2[email protected] nanosheets with excellent dispersity and high antibacterial activity were integrated into in situ polymerized polyethylene terephthalate (PET) fibers, revealing an enhanced mechanical performance in comparison with the PET fibers fabricated directly via a traditional melt blending method. Additionally, such an in situ polymerized PET/Cu2[email protected] fibers displayed highly enhanced mechanical properties; and great antibacterial activities against multi-types of bacterium, including S. aureus, E. coli and C. albicans. For the as-obtained two types of PET/Cu2[email protected] fibers, we have detailed their molecular weight (detailed molecular weight) and dispersibility of nano-Cu2[email protected] and fibers crystallinity was investigated by Gel chromatography (GPC), Scanning electron microscope (SEM), and X-ray diffractometer (XRD), respectively. The results showed that the aggregation of the nano-Cu2[email protected] in the resultant PET matrix could be effectively prevented during its in situ polymerization process, hence we attribute its highly enhanced mechanical properties to its superior dispersion of nano-Cu2[email protected] View Full-Text
Keywords: nano-Cu2[email protected]; PET; antibacterial fibers; in situ polymerization nano-Cu2[email protected]; PET; antibacterial fibers; in situ polymerization
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Zhou, J.; Fei, X.; Li, C.; Yu, S.; Hu, Z.; Xiang, H.; Sun, B.; Zhu, M. Integrating Nano-Cu2[email protected] into In Situ Polymerized Polyethylene Terephthalate (PET) Fibers with Enhanced Mechanical Properties and Antibacterial Activities. Polymers 2019, 11, 113.

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