Multicolor Photochromism of Two-Component Diarylethene Crystals Containing Oxidized and Unoxidized Benzothiophene Groups
Abstract
:1. Introduction
2. Materials and Methods
2.1. General
2.2. Synthesis of 2a
3. Results and Discussion
3.1. Photochromism of 1 and 2 in Solution
3.2. Single-Component Crystals of 1a and 2a
3.3. Two-Component Mixed Crystals Containing 1a and 2a
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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1a | 2a | 1a·2a | |
---|---|---|---|
Crystallization solvent | Acetone | Diethyl ether | Acetone |
Formula | C25H18F6O4S2 | C25H18F6O2S2 | C25H18F6O3.57S2 |
Formula weight | 560.51 | 528.51 | 553.60 |
T/K | 223 (2) | 100 (2) | 223 (2) |
Crystal system | Monoclinic | Monoclinic | Monoclinic |
Space group | C2/c | P21/c | C2/c |
a/Å | 15.0346 (11) | 13.1649 (8) | 15.0533 (5) |
b/Å | 15.1774 (11) | 10.5410 (6) | 15.1878 (5) |
c/Å | 10.7072 (7) | 16.5297 (10) | 10.6375 (3) |
β/° | 107.706 (2) | 99.859 (2) | 107.8093 (13) |
V/Å3 | 2327.5 (3) | 2260.0 (2) | 2315.47 (13) |
Z | 4 | 4 | 4 |
R1 (I > 2σ(I)) | 0.0328 | 0.0571 | 0.0529 |
wR2 (all data) | 0.0906 | 0.1265 | 0.1420 |
CCDC No. | 2217447 | 2217448 | 2217449 |
Entry | Feed Ratio in Solution (1a:2a) | Composition Ratio in Crystal (1a:2a) |
---|---|---|
1 | 90:10 | 97:3 |
2 | 70:30 | 85:15 |
3 | 50:50 | 53:47 |
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Nishimura, R.; Nagakawa, Y.; Morimoto, M. Multicolor Photochromism of Two-Component Diarylethene Crystals Containing Oxidized and Unoxidized Benzothiophene Groups. Crystals 2022, 12, 1730. https://doi.org/10.3390/cryst12121730
Nishimura R, Nagakawa Y, Morimoto M. Multicolor Photochromism of Two-Component Diarylethene Crystals Containing Oxidized and Unoxidized Benzothiophene Groups. Crystals. 2022; 12(12):1730. https://doi.org/10.3390/cryst12121730
Chicago/Turabian StyleNishimura, Ryo, Yurika Nagakawa, and Masakazu Morimoto. 2022. "Multicolor Photochromism of Two-Component Diarylethene Crystals Containing Oxidized and Unoxidized Benzothiophene Groups" Crystals 12, no. 12: 1730. https://doi.org/10.3390/cryst12121730