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Open AccessArticle

Halide Ion Embraces in Tris(2,2′-bipyridine)metal Complexes

Department of Chemistry, University of Basel, BPR 1096, Mattenstrasse 24a, CH-4058 Basel, Switzerland
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Crystals 2020, 10(8), 671; https://doi.org/10.3390/cryst10080671
Received: 27 July 2020 / Revised: 30 July 2020 / Accepted: 1 August 2020 / Published: 3 August 2020
(This article belongs to the Special Issue Halogen Bonding in Supramolecular Self-Assembly)
An analysis of the [M(bpy)3]n+ (bpy = 2,2′-bipyridine) complexes with halide counterions in the Cambridge Structural Database reveals a common structural motif in two thirds of the compounds. This interaction involves the formation of 12 short C–H…X contacts between halide ions lying within sheets of the cations and H-3 and H-3′ of six [M(bpy)3]n+ complex cations. A second motif, also involving 12 short contacts, but with H-6 and H-5, is identified between halide ions lying between sheets of the [M(bpy)3]n+ cations. View Full-Text
Keywords: metal complexes; 2,2′-bipyridine; halide; C–H…X interactions metal complexes; 2,2′-bipyridine; halide; C–H…X interactions
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MDPI and ACS Style

Constable, E.C.; Housecroft, C.E. Halide Ion Embraces in Tris(2,2′-bipyridine)metal Complexes. Crystals 2020, 10, 671.

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