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The Effect of Citric Acid Concentration on the Properties of LaMnO3 as a Catalyst for Hydrocarbon Oxidation

1
Université de Lyon, Université Lyon 1, CNRS, UMR 5256, IRCELYON, 69626 Villeurbanne CEDEX, France
2
Istituto per lo Studio dei Materiali Nanostrutturati (ISMN)-CNR, 90146 Palermo, Italy
3
Facultad de Ciencias y Tecnologías Quimicas, Departamento de Ingenieria Quimica, Universidad de Castilla-La Mancha, 13071 Ciudad Real, Spain
*
Authors to whom correspondence should be addressed.
Catalysts 2019, 9(3), 226; https://doi.org/10.3390/catal9030226
Received: 21 December 2018 / Revised: 21 February 2019 / Accepted: 23 February 2019 / Published: 1 March 2019
(This article belongs to the Special Issue Catalytic Oxidation of Methane)
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Abstract

LaMnO3 (LM) catalysts with a molar ratio of citric acid (CA) to metal (La3+ + Mn2+) nitrates ranging from 0.5 to 2 (LM0.5 to LM2) were synthesized by the citrate sol–gel method with the aim of studying the effect of the citric acid ratio on the physicochemical properties and the catalytic performance in hydrocarbon oxidation. Structural and morphological properties of these catalysts were characterized by X-ray diffraction (XRD) and specific surface area (N2 adsorption) measurements, while the chemical composition was determined by inductively coupled plasma atomic emission spectroscopy (ICP-OES). In the selected samples, additional characterizations were carried out by thermogravimetric and differential thermal analysis (TGA/DTA), Fourier Transform Infrared Spectroscopy (FT-IR), temperature-programmed reduction by hydrogen (H2-TPR), and X-ray photoelectron spectroscopy (XPS). The results showed that the amount of citric acid used significantly influenced the TGA/DTA profile of gels along with the physicochemical properties of the catalysts. The XRD patterns are consistent with the perovskite formation as the main phase. The segregation of a small amount of Mn3O4, detected for molar ratios ranging between 0.5 and 1.5, suggested the formation of a slightly nonstoichiometric LaMn1−xO3 phase with a relatively high content of Mn4+. The catalytic performance was evaluated in the total oxidation of two selected hydrocarbons, toluene and propene, which represent typical volatile organic compounds (VOCs). Typically, three consecutive catalytic cycles were performed in order to reach steady-state performance in toluene and propene oxidation. Moreover, the stability of the catalysts under reaction conditions was investigated through 24-h experiments at 17% of toluene conversion. The catalysts LM1.2, LM1.3, and LM1.5 showed the best catalytic performance in both hydrocarbon oxidations, well comparing with the Pd/Al2O3 used as a reference. View Full-Text
Keywords: LaMnO3 perovskite; citric acid/metal nitrates molar ratio; structural and morphological characterization; toluene and propene total oxidation LaMnO3 perovskite; citric acid/metal nitrates molar ratio; structural and morphological characterization; toluene and propene total oxidation
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Sihaib, Z.; Puleo, F.; Pantaleo, G.; La Parola, V.; Valverde, J.L.; Gil, S.; Liotta, L.F.; Giroir-Fendler, A. The Effect of Citric Acid Concentration on the Properties of LaMnO3 as a Catalyst for Hydrocarbon Oxidation. Catalysts 2019, 9, 226.

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