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Catalysts 2019, 9(3), 213; https://doi.org/10.3390/catal9030213

Recent Developments in the Suzuki–Miyaura Reaction Using Nitroarenes as Electrophilic Coupling Reagents

Laboratoire MOLTECH-Anjou, CNRS UMR 6200, UNIV Angers, 2 Bd Lavoisier, 49045 Angers CEDEX, France
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Received: 29 January 2019 / Revised: 8 February 2019 / Accepted: 13 February 2019 / Published: 26 February 2019
(This article belongs to the Special Issue Catalysts for Suzuki–Miyaura Coupling Reaction)
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Abstract

Palladium-catalyzed cross-coupling reactions are nowadays essential in organic synthesis for the construction of C–C, C–N, C–O, and other C-heteroatom bonds. The 2010 Nobel Prize in Chemistry to Richard F. Heck, Ei-ichi Negishi, and Akira Suzuki was awarded for the discovery of these reactions. These great advances for organic chemists stimulated intense research efforts worldwide dedicated to studying these reactions. Among them, the Suzuki–Miyaura coupling (SMC) reaction, which usually involves an organoboron reagent and an organic halide or triflate in the presence of a base and a palladium catalyst, has become, in the last few decades, one of the most popular tools for the creation of C–C bonds. In this review, we present recent progress concerning the SMC reaction with the original use of nitroarenes as electrophilic coupling partners reacting with the organoboron reagent. View Full-Text
Keywords: Suzuki–Miyaura; nitroarene; palladium-catalyzed cross-coupling Suzuki–Miyaura; nitroarene; palladium-catalyzed cross-coupling
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Rocard, L.; Hudhomme, P. Recent Developments in the Suzuki–Miyaura Reaction Using Nitroarenes as Electrophilic Coupling Reagents. Catalysts 2019, 9, 213.

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