Next Article in Journal
Dioxygen Activation by Laccases: Green Chemistry for Fine Chemical Synthesis
Next Article in Special Issue
Molecular Orientations Change Reaction Kinetics and Mechanism: A Review on Catalytic Alcohol Oxidation in Gas Phase and Liquid Phase on Size-Controlled Pt Nanoparticles
Previous Article in Journal
Selective Reduction of Ketones and Aldehydes in Continuous-Flow Microreactor—Kinetic Studies
Previous Article in Special Issue
Photocatalytic Degradation of Commercial Acetaminophen: Evaluation, Modeling, and Scaling-Up of Photoreactors
Open AccessArticle

Degradation and Loss of Antibacterial Activity of Commercial Amoxicillin with TiO2/WO3-Assisted Solar Photocatalysis

Escuela de Ingeniería Química, Universidad del Valle, Cali A.A. 25360, Colombia
School of Occupational and Public Health, Ryerson University, 350 Victoria Street, Toronto, ON M5B 2K3, Canada
Facultad de Ciencias Químicas, Universidad de Nuevo León, CP 64570 Monterrey, Nuevo Leon, Mexico
Chemical Engineering Program, Universidad de Cartagena, Av. El Consulado 48-152, Cartagena A.A. 130001, Colombia
Author to whom correspondence should be addressed.
Catalysts 2018, 8(6), 222;
Received: 30 April 2018 / Revised: 17 May 2018 / Accepted: 21 May 2018 / Published: 23 May 2018
(This article belongs to the Special Issue New Concepts in Oxidation Processes)
In this study, a TiO2 catalyst, modified with tungsten oxide (WO3), was synthesized to reduce its bandgap energy (Eg) and to improve its photocatalytic performance. For the catalyst evaluation, the effect of the calcination temperature on the solar photocatalytic degradation was analyzed. The experimental runs were carried out in a CPC (compound parabolic collector) pilot-scale solar reactor, following a multilevel factorial experimental design, which allowed analysis of the effect of the calcination temperature, the initial concentration of amoxicillin, and the catalyst load on the amoxicillin removal. The most favorable calcination temperature for the catalyst performance, concerning the removal of amoxicillin, was 700 °C; because it was the only sample that showed the rutile phase in its crystalline structure. Regarding the loss of the antibiotic activity, the inhibition tests showed that the treated solution of amoxicillin exhibited lower antibacterial activity. The highest amoxicillin removal achieved in these experiments was 64.4% with 100 ppm of amoxicillin concentration, 700 °C of calcination temperature, and 0.1 g L−1 of catalyst load. Nonetheless, the modified TiO2/WO3 underperformed compared to the commercial TiO2 P25, due to its low specific surface and the particles sintering during the sol-gel synthesis. View Full-Text
Keywords: sol-gel; bandgap energy; CPC; emergent pollutants; photodegradation sol-gel; bandgap energy; CPC; emergent pollutants; photodegradation
Show Figures

Graphical abstract

MDPI and ACS Style

Arce-Sarria, A.; Machuca-Martínez, F.; Bustillo-Lecompte, C.; Hernández-Ramírez, A.; Colina-Márquez, J. Degradation and Loss of Antibacterial Activity of Commercial Amoxicillin with TiO2/WO3-Assisted Solar Photocatalysis. Catalysts 2018, 8, 222.

Show more citation formats Show less citations formats
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Article Access Map

Back to TopTop