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Article

Pd/DNA as Highly Active and Recyclable Catalyst of Suzuki–Miyaura Coupling

by 1, 2 and 1,*
1
Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie, 50-383 Wrocław, Poland
2
Faculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wroclaw, Poland
*
Author to whom correspondence should be addressed.
Catalysts 2018, 8(11), 552; https://doi.org/10.3390/catal8110552
Received: 27 October 2018 / Revised: 12 November 2018 / Accepted: 13 November 2018 / Published: 16 November 2018
(This article belongs to the Special Issue Catalysts for Suzuki–Miyaura Coupling Reaction)
Pd/DNA catalysts were prepared in a mixed H2O/EtOH solvent using palladium precursors, Pd(OAc)2 and PdCl2, in different dosages and salmon fish sperm DNA. As prepared, the Pd/DNA contained Pd(II) and Pd(0) nanoparticles of various sizes and morphologies, depending on the preparation method. Pd/DNA efficiently catalyzed the Suzuki–Miyaura cross-coupling of various aryl bromides with phenylboronic acids. The catalyst was recovered by simple phase separation and then reused in seven consecutive cycles with a high activity. View Full-Text
Keywords: palladium; nanoparticles; DNA; Suzuki–Miyaura; carbonylative coupling palladium; nanoparticles; DNA; Suzuki–Miyaura; carbonylative coupling
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MDPI and ACS Style

Mart, M.; Tylus, W.; Trzeciak, A.M. Pd/DNA as Highly Active and Recyclable Catalyst of Suzuki–Miyaura Coupling. Catalysts 2018, 8, 552. https://doi.org/10.3390/catal8110552

AMA Style

Mart M, Tylus W, Trzeciak AM. Pd/DNA as Highly Active and Recyclable Catalyst of Suzuki–Miyaura Coupling. Catalysts. 2018; 8(11):552. https://doi.org/10.3390/catal8110552

Chicago/Turabian Style

Mart, M., W. Tylus, and A. M. Trzeciak 2018. "Pd/DNA as Highly Active and Recyclable Catalyst of Suzuki–Miyaura Coupling" Catalysts 8, no. 11: 552. https://doi.org/10.3390/catal8110552

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