The Synthesis of Different Series of Cobalt BEA Zeolite Catalysts by Post-Synthesis Methods and Their Characterization
Abstract
:1. Introduction
2. Results and Discussion
2.1. Evidence for Cobalt Incorporation into SiBEA Framework
2.1.1. XRD
2.1.2. FTIR Investigation
2.2. The Local Environment of Cobalt in Co-BEA Zeolites
2.2.1. NMR Investigation
2.2.2. DR UV-vis Investigation
2.2.3. XPS Investigation
2.3. Reducibility of the Cobalt Species Present in the Co-BEA Zeolites
2.4. Acidic Properties of Catalytic Systems
2.4.1. Pyridine Adsorption Followed by FTIR
2.4.2. FTIR Study of Adsorbed CO
3. Materials and Methods
3.1. Catalysts Preparation
3.2. Catalysts Characterization
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Samples | Brønsted Acid Sites (µmol g−1) a | Lewis Acid Sites (µmol g−1) a |
---|---|---|
HAlBEA | 235 | 134 |
Co1.0HAlBEA(II) | 127 | 212 |
Co5.0HAlBEA(II) | 35 | 341 |
SiBEA | 0 | 0 |
Co1.0SiBEA(I) | 0 | 136 |
Co5.0SiBEA(I) | 0 | 204 |
Co1.0SiBEA(III) | 0 | 33 |
Co5.0SiBEA(III) | 0 | 80 |
Core Excitation | AP-Co1.0SiBEA(III) BE(eV) Area(%) | AP-Co3.0SiBEA(III) BE(eV) Area(%) | AP-Co5.0SiBEA(III) BE(eV) Area(%) | Co5.0SiBEA(III) BE(eV) Area(%) | Co9.0SiBEA(III) BE(eV) Area(%) |
---|---|---|---|---|---|
Co 2p3/2 | --- | --- | --- | 780.4 6.9 | 780.2 17.2 A |
782.1 100 | 781.2 63.6 | 781.2 69.3 | 781.8 59.4 | 781.6 71.2 B | |
--- | 783.0 36.4 | 783.1 30.7 | 783.6 33.7 | 783.7 11.6 C | |
Co 2p1/2 | --- | --- | --- | 795.5 | 795.3 |
797.8 --- | 797.1 798.7 | 797.2 798.6 | 797.5 799.4 | 797.2 799.4 | |
ΔA | --- | --- | --- | 15.1 | 15.1 |
ΔB | 15.7 | 15.9 | 16.0 | 15.7 | 15.6 |
ΔC | --- | 15.7 | 15.7 | 15.8 | 15.7 |
Core Excitation | AP-Co3.0SiBEA(I) BE(eV) Area(%) | AP-Co5.0SiBEA(I) BE(eV) Area(%) | AP-Co9.0SiBEA(I) BE(eV) Area(%) | Co9.0SiBEA(I) BE(eV) Area(%) |
---|---|---|---|---|
Co 2p3/2 | --- | --- | --- | 780.2 6.6 A |
781.7 57.8 | 781.6 66.4 | 781.6 63.0 | 782.0 44.0 B | |
783.3 42.2 | 783.3 33.6 | 783.2 37.0 | 783.7 49.4 C | |
Co 2p1/2 | --- | --- | --- | 795.4 |
797.5 799.2 | 797.3 798.8 | 797.3 798.7 | 797.6 799.2 | |
ΔA | --- | --- | --- | 15.2 |
ΔB | 15.8 | 15.7 | 15.7 | 15.6 |
ΔC | 15.9 | 15.5 | 15.5 | 15.5 |
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Sadek, R.; Chalupka-Spiewak, K.; Krafft, J.-M.; Millot, Y.; Valentin, L.; Casale, S.; Gurgul, J.; Dzwigaj, S. The Synthesis of Different Series of Cobalt BEA Zeolite Catalysts by Post-Synthesis Methods and Their Characterization. Catalysts 2022, 12, 1644. https://doi.org/10.3390/catal12121644
Sadek R, Chalupka-Spiewak K, Krafft J-M, Millot Y, Valentin L, Casale S, Gurgul J, Dzwigaj S. The Synthesis of Different Series of Cobalt BEA Zeolite Catalysts by Post-Synthesis Methods and Their Characterization. Catalysts. 2022; 12(12):1644. https://doi.org/10.3390/catal12121644
Chicago/Turabian StyleSadek, Renata, Karolina Chalupka-Spiewak, Jean-Marc Krafft, Yannick Millot, Laetitia Valentin, Sandra Casale, Jacek Gurgul, and Stanislaw Dzwigaj. 2022. "The Synthesis of Different Series of Cobalt BEA Zeolite Catalysts by Post-Synthesis Methods and Their Characterization" Catalysts 12, no. 12: 1644. https://doi.org/10.3390/catal12121644