Integrating Agro-Hydrological Modeling with Index-Based Vulnerability Assessment for Nitrate-Contaminated Groundwater
Abstract
1. Introduction
2. Study Area

3. Materials and Methods
3.1. Method for Groundwater Vulnerability Assessment
3.1.1. Data Collection
3.1.2. Adjustment of Parameters Classification and DRASTIC-AGRO Index
3.1.3. Sensitivity Analysis
3.2. SWAT Model
3.2.1. Input Data and Model Setup
3.2.2. Calibration and Validation Processes
3.2.3. Defining Agricultural Management Scenarios
4. Results
4.1. Groundwater Recharge and N-NO3 Load Leaching Through Unsaturated Zone (SWAT Model)
4.2. Assessment of Groundwater Vulnerability to Pollution
4.3. Scenarios of Agriculture Practice Impact on Groundwater Vulnerability
5. Discussion
6. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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| DRASTIC | DRASTIC-AGRO | Source |
|---|---|---|
| Depth to groundwater table (D) | Hydraulic resistance of the vadose zone (HR) | Borehole profiles Hydrogeological maps |
| Impact of the vadose zone (I) | ||
| Groundwater recharge (R) | Groundwater recharge (GR) | SWAT model output |
| Topography (T) | ||
| Topography (T) | N-NO3 load leaching from the unsaturated zone (NL) | |
| Soil (S) | ||
| Aquifer media (A) | Aquifer thickness (AT) | Borehole profiles |
| Hydraulic conductivity (C) | Groundwater velocity (GV) | MODFLOW model output |
| Parameter | Grading Method | Correlation Rank | Weight |
|---|---|---|---|
| HR | equal | 0.508 | 6.00 |
| GR | equal | 0.013 | 0.15 |
| NL | equal | 0.093 | 1.10 |
| AT | geometric | 0.198 | 2.34 |
| GV | equal | 0.035 | 0.41 |
| DRASTIC | Rating | Depth to groundwater (m) | Groundwater recharge (mm/year) | Aquifer media | Soil | Topography (%) | Impact of the vadose zone | Hydraulic conductivity (m/d) |
| 10 | 0.0–1.5 | Karst limestone | Thin or absent/Gravel | 0–2 | Karst limestone | >81.60 | ||
| 9 | 1.5–4.5 | >250 | Basalt | Sand | 2–6 | Basalt | ||
| 8 | 180–250 | Sand and gravel | Peat | Sand and gravel | 40.80–81.60 | |||
| 7 | 4.5–9.0 | – | Shrinking/Aggregated clay | – | ||||
| 6 | 100–180 | Massive limestone/Sandstone | Sandy loam | Limestone/Sandstone/Sand and gravel with significant silt and clay | 28.56–40.80 | |||
| 5 | 9.0–15.0 | Glacial till | Loam | 6–12 | – | |||
| 4 | Weathered metamorphic/ Igneous | Silty loam | Metamorphic/Igneous | 12.24–28.56 | ||||
| 3 | 15.0–22.0 | 50–100 | Metamorphic/Igneous | Clay loam | 12–18 | Silt/Clay/Shale | ||
| 2 | 22.0–30.0 | Massive shale | Muck | – | 4.08–12.24 | |||
| 1 | >30.0 | 0–50 | – | No shrinking/Aggregated clay | >18 | Confining layer | 0.04–4.08 | |
| DRASTIC-AGRO | Rating | Hydraulic resistance of the vadose zone layers (HR) (log HR) | Groundwater recharge (mm/year) | N-NO3 load leaching from the unsaturated zone (kg/ha/year) | Aquifer thickness (m) | Groundwater velocity (m/d) | ||
| 10 | <−1.1 | >210.3 | >92.3 | <9.8 | >1.15 | |||
| 9 | −1.1–−0.2 | 187.0–210.3 | 82.1–92.3 | 9.8–16.9 | 1.03–1.15 | |||
| 8 | −0.2–0.7 | 163.6–187.0 | 71.8–82.1 | 16.9–22.2 | 0.91–1.03 | |||
| 7 | 0.7–1.7 | 140.2–163.6 | 61.6–71.8 | 22.2–26.2 | 0.79–0.91 | |||
| 6 | 1.7–2.6 | 116.9–140.2 | 51.3–61.6 | 26.2–29.1 | 0.65–0.79 | |||
| 5 | 2.6–3.5 | 93.5–116.9 | 41.0–51.3 | 29.1–32.0 | 0.53–0.65 | |||
| 4 | 3.5–4.5 | 70.1–93.5 | 30.8–41.0 | 32.0–35.9 | 0.41–0.53 | |||
| 3 | 4.5–5.4 | 46.7–70.1 | 20.5–30.8 | 35.9–41.2 | 0.29–0.41 | |||
| 2 | 5.4–6.3 | 23.4–46.7 | 10.3–20.5 | 41.2–48.4 | 0.14–0.29 | |||
| 1 | >6.3 | <23.4 | <10.3 | >48.4 | <0.14 | |||
| Data Category | Data | Data Source |
|---|---|---|
| Thematic maps | Digital Elevation Model (DEM) | GUGiK 1 |
| Land use | GIOŚ 2 | |
| Soil cover | PIG-PIB 3 | |
| Weather data | Daily precipitation | CFSR 4 IMGW-PIB 5 |
| Daily max and min temperature | ||
| Mean daily relative humidity | ||
| Daily solar radiation sum | ||
| Mean daily wind speed | ||
| Agricultural practices | Farmer surveys | WaterPUCK 6 |
| Output Type | Unit | Model Values | Reference Values | |
|---|---|---|---|---|
| Calibration | Groundwater recharge | mm/y | 24–236 1 76 2 | 19–186 [86,87] |
| Evapotranspiration (incl. REVAP) | mm/y | 453 2 | 450–495 [88] | |
| Forest biomass production | t/ha/y | 6–20 1 | 4.2–12.1 [89] | |
| Validation | Total runoff | mm/y | 179 2 | 47–268 [97] |
| Yield: Winter wheat | t/ha/y | 6.0–8.5 1 | 5.5 [55] | |
| Yield: Canola | t/ha/y | 2.9–3.1 1 | 3.4 [55] | |
| Yield: Silage corn | t/ha/y | 9.8–9.9 1 | 13.5 [55] | |
| Yield: Hay | t/ha/y | 2.2–9.2 1 | 4.0–10.0 [98] | |
| Scenario Category | Scenario No. | Description |
|---|---|---|
| Baseline | W0 | current land use and agricultural management |
| Crop type | S1 | winter wheat |
| S2 | silage corn | |
| S3 | canola | |
| S4 | mixture of spring cereals (represented by barley) | |
| S5 | potatoes | |
| S6 | peas (Pisum) | |
| Fertilizer management | S7 | two-fold dose reduction |
| S8 | doubling the dose | |
| Tillage | S9 | minimum depth (reduced by half) |
| S10 | maximum depth (increased two-fold) | |
| Grazing | S11 | 1 cow/ha |
| S12 | 5 cows/ha |
| Groundwater Vulnerability Class | NO3 Concentration in Groundwater | ||||
|---|---|---|---|---|---|
| MIN | MAX | x | δ | M | |
| Very Low | 0.5 | 3.0 | 0.9 | 0.7 | 0.5 |
| Low | 0.5 | 19.0 | 4.2 | 5.8 | 1.4 |
| Medium | 0.5 | 20.0 | 7.5 | 8.9 | 2.0 |
| High | 4.0 | 34.0 | 12.3 | 9.2 | 9.8 |
| Very High | 5.0 | 49.0 | 28.0 | 17.7 | 29.5 |
| DRASTIC-AGRO Parameter | Effective Weight (%) | |||
|---|---|---|---|---|
| MIN | MAX | x | δ | |
| HR | 14.79 | 89.63 | 61.30 | 14.42 |
| GR | 0.21 | 5.86 | 1.39 | 0.74 |
| NL | 1.28 | 40.64 | 6.22 | 4.87 |
| AT | 4.64 | 73.7 | 29.59 | 13.01 |
| GV | 0.44 | 8.75 | 1.51 | 0.79 |
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Potrykus, D.; Szymkiewicz, A.; Jaworska-Szulc, B.; Busico, G.; Gumuła-Kawęcka, A.; Gorczewska-Langner, W.; Mastrocicco, M. Integrating Agro-Hydrological Modeling with Index-Based Vulnerability Assessment for Nitrate-Contaminated Groundwater. Sustainability 2026, 18, 729. https://doi.org/10.3390/su18020729
Potrykus D, Szymkiewicz A, Jaworska-Szulc B, Busico G, Gumuła-Kawęcka A, Gorczewska-Langner W, Mastrocicco M. Integrating Agro-Hydrological Modeling with Index-Based Vulnerability Assessment for Nitrate-Contaminated Groundwater. Sustainability. 2026; 18(2):729. https://doi.org/10.3390/su18020729
Chicago/Turabian StylePotrykus, Dawid, Adam Szymkiewicz, Beata Jaworska-Szulc, Gianluigi Busico, Anna Gumuła-Kawęcka, Wioletta Gorczewska-Langner, and Micol Mastrocicco. 2026. "Integrating Agro-Hydrological Modeling with Index-Based Vulnerability Assessment for Nitrate-Contaminated Groundwater" Sustainability 18, no. 2: 729. https://doi.org/10.3390/su18020729
APA StylePotrykus, D., Szymkiewicz, A., Jaworska-Szulc, B., Busico, G., Gumuła-Kawęcka, A., Gorczewska-Langner, W., & Mastrocicco, M. (2026). Integrating Agro-Hydrological Modeling with Index-Based Vulnerability Assessment for Nitrate-Contaminated Groundwater. Sustainability, 18(2), 729. https://doi.org/10.3390/su18020729

