Preparation and Properties of Transparent, Thermally Insulating, and Flexible SiO₂ Aerogels

SiO₂ aerogels are promising candidates for energy-efficient glazing because of their low thermal conductivity and optical transparency; however, conventional formulations often fail to reconcile optical, thermal, and mechanical performance. This work aimed to resolve this bottleneck via controllable sol–gel synthesis and ambient pressure drying. Using methyltrimethoxysilane (MTMS) as the single silicon source, this study systematically explored the effects of alkaline catalyst type, water-to-MTMS ratio, and surfactant selection, and further developed an MTMS–dimethyl dimethoxy silicane (DMDMS) composite silicon source. Tetramethylammonium hydroxide (TMAOH) catalysis, a water-to-MTMS molar ratio of 7:1, and Pluronic F-127 (F127) surfactant yielded a uniform, hydrophobic aerogel with 93.50% porosity and 89.74% transmittance at 800 nm. The optimized composite system (MTMS:DMDMS = 9:1, 6 mL water, 2.0 g F127) enhanced compressive strength by 22.4% relative to pure MTMS aerogel, with 70.15% visible transmittance and thermal conductivity of 0.027 W/(m·K). These results demonstrate that multi-parameter formulation control can achieve a practical balance among mechanical robustness, optical transparency, and thermal insulation. This study provides a theoretical and process foundation for the engineering application of high-performance transparent thermal insulation materials.