Lanthanide and Ladder-Structured Polysilsesquioxane Composites for Transparent Color Conversion Layers
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis of Ladder-Structured Poly(phenyl-co-glycidoxypropyl)silsesquioxane (LPGSQ64)
2.3. Fabrication of Lanthanide-Based Hybrid Polymer Composite Films
2.4. Measurements
3. Results and Discussion
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Formula | Chemical Shift (ppm) |
---|---|
1H NMR | |
t, Si(CH2CH2CH2OCH2CHOCH2), 2H | 0.35–0.75 |
m, Si(CH2CH2CH2OCH2CHOCH2), 2H | 1.3–1.7 |
d, Si(CH2CH2CH2OCH2CHOCH2), 1H | 2.5–2.7 |
m, Si(CH2CH2CH2OCH2CHOCH2), 2H | 2.8–3.0 |
m, Si(CH2CH2CH2OCH2CHOCH2), 2H | 3.0–3.3 |
m, Si(CH2CH2CH2OCH2CHOCH2), 2H | 3.2–3.4 |
m, Si(C6H5), 5H | 7.2–8.0 |
29Si NMR | |
Si(CH2CH2CH2OCH2CHOCH2) | −64 to −70 |
Si(C6H5) | −77 to −82 |
Sample | Pencil Hardness (10H = Best) | Cross-Cut Adhesion (5B = Best) |
---|---|---|
1 h curing | ||
LPGSQ64 | 2B | 3B |
LPGSQ64-Eu 3% | 2H | 5B |
LPGSQ64-Tb 3% | HB | 5B |
LPGSQ64-Eu 5% | 3H | 4B |
LPGSQ64-Tb 5% | H | 5B |
6 h curing | ||
LPGSQ64 | HB | 3B |
LPGSQ64-Eu 3% | 3H | 5B |
LPGSQ64-Tb 3% | H | 5B |
LPGSQ64-Eu 5% | 3H | 5B |
LPGSQ64-Tb 5% | 4H | 5B |
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Han, J.; Burak, D.; Poliukhova, V.; Lee, A.S.; Jang, H.; Hwang, S.; Baek, K.-Y.; Han, J.; Ju, B.-K.; Cho, S.-H. Lanthanide and Ladder-Structured Polysilsesquioxane Composites for Transparent Color Conversion Layers. Materials 2023, 16, 2537. https://doi.org/10.3390/ma16062537
Han J, Burak D, Poliukhova V, Lee AS, Jang H, Hwang S, Baek K-Y, Han J, Ju B-K, Cho S-H. Lanthanide and Ladder-Structured Polysilsesquioxane Composites for Transparent Color Conversion Layers. Materials. 2023; 16(6):2537. https://doi.org/10.3390/ma16062537
Chicago/Turabian StyleHan, Jaehyun, Darya Burak, Valeriia Poliukhova, Albert S. Lee, Hoseong Jang, Seungsang Hwang, Kyung-Youl Baek, Joonsoo Han, Byeong-Kwon Ju, and So-Hye Cho. 2023. "Lanthanide and Ladder-Structured Polysilsesquioxane Composites for Transparent Color Conversion Layers" Materials 16, no. 6: 2537. https://doi.org/10.3390/ma16062537