Silicone Composites with CNT/Graphene Hybrid Fillers: A Review
Abstract
:1. Introduction
2. Architecture and Fabrication of CNT-Graphene Hybrid Fillers
3. Fabrication and Properties of CNT/G/PDMS Composites
3.1. Non-Foamed CNT/G Hybrid Silicone Composites with Assembled Structure
3.2. Non-Foamed CNT/G Hybrid Silicone Composites with Seamless Structure
3.3. Silicone Composites with a Foamed Matrix and Assembled CNT/G Hybrid Fillers
3.4. Silicone Composites with Foamed and Seamlessly Bonded CNT/G Hybrid Fillers
3.5. Silicone Composites with Foamed and Assembled CNT/G Hybrid Fillers
4. Summary and Perspectives
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Appendix A
Filler * | Matrix | CNT/G Ratio * | Filler Loads *, (wt%) | Fabrication Techniques | Key Properties | Applications | Ref. |
---|---|---|---|---|---|---|---|
non-foamed assembled hMWCNT/G | non- foamed PDMS | 2:1 2.5:1 3:1 | 3.0 3.5 4.0 | THF solution blending/ sonication | σe = 1.25 mS/m Δ = 0.123 m2/s | electrostatic discharge, EMI shielding. | [34] |
1:1 | 0.375 0.5 0.75 1.0 1.5 | THF solution blending/ sonication | σts = 0.67 MPa ε = 194% T0 = 441 °C q800 = 56% | EMI shielding, flame retarding | [35] | ||
1:1 7:3 9:1 | 0.4 0.6 1.0 | THF solution blending/ sonication | σe = 0.617 S/m ε = 215% εr = 60% | stretchable electronics | [36] | ||
3:1 | 0.5 1.0 1.5 2.0 3.0 4.0 | THF solution blending/ sonication | pc = 0.92 wt% GF = 19.2 εr = 30% | strain sensing for health monitoring | [27] | ||
2:1 | 1.0 2.0 3.0 4.0 5.0 | n-hexane solution blending/sonication/ stirring | pc = 2.0 wt% GF = 11.6 εr = 30% | strain sensing for health monitoring | [37] | ||
1:1 | 9.0 | hexane solution blending/stirring | GF = ~4.4 ε = ~70% εr = 33% | strain sensing for tremor detection | [38] | ||
3.5:1.5 | 5.0 | IPA + Stoddard solvent solution blending/ sonication | pc = 5.0 wt% GF = > 100 εr = 40% | strain sensing for health monitoring | [39] | ||
1:9 3:7 1:1 7:3 9:1 | 1.0 | acetate solution blending/ultrasonication | σe = 1.37 S/m hrc = 7.46 mW/°C T10 = 488 °C q800 = 56% | flexible electric heating elements | [40] | ||
1:3 | 0.25 0.5 0.75 1.0 | toluene solution blending/ultrasonication/stirring | k = 22.5 | selective membranes for ethanol-water separation | [41] | ||
1:3 1:1 3:1 | n/a | ethanol solution blending/sonication/ stirring/infiltration | GF = 10.9 ε = 71% εr = 33% | strain sensing for gait monitoring | [42] | ||
6:4 7:3 8:2 9:1 | 1.0 | planetary mixing | σe = 1 S/m ε = ~100% εr = 30% | conductive dry adhesives for ECG monitoring | [43] | ||
1:9 2:8 4:6 6:4 8:2 | 10.0 15.0 20.0 | aqueous solution blending/stirring/ ultrasonication/ calendering in a three-roll mill | σe = 0.6 … 1 S/m ε = 60 … 100% εr = 30% | biosensors and bioelectronics | [44] | ||
non-foamed seamless v(2, 3, or 6) WCNT/G | n/a | n/a | plasma-enhanced CVD/ infiltration | β = 14500 Eto = 0.4 V/ μ m εr = 45% | field-emission stretchable electronics | [28] | |
non-foamed seamless hCNT/G | n/a | n/a | CVD/ infiltration | GF = ~0.36 εr = 20% | strain sensing for wearable electronics | [46] | |
non-foamed seamless hMWCNT/G | 1:4 | 0.25 0.5 0.75 1.0 2.0 3.0 | aqueous solution blending/ultrasonication/annealing/acetate solution blending/ magnetic stirring | σe = 2 mS/m λ = 0.29 W/m·K T0 = 419 °C | conductive and thermal management elastomer materials | [47] | |
non-foamed assembled hMWCNT/G | foamed PDMS | 1:4 1:1 4:1 | ~2.0 | aqueous solution blending/stirring/ foaming | σe = 0.12 mS/m λ = 0.548 W/m·K σts = 0.6 MPa ε = 110% | stretchable and soft electronics | [29] |
1:3 1:1 3:1 | 1.0 | aqueous solution blending/stirring/ fermentation | σe = 1.4 nS/m ε = 96% σts = 0.17 MPa | biomedical stretchable electronics | [48] | ||
1:1 | 2.0 | aqueous solution blending/ultrasonication/Ni template replication/ forced infiltration | σe = 27 S/m pc = 0.2 wt% εr = 50% | next-generation stretchable electronics | [50] | ||
1:1 | 1.0 | aqueous solution blending/ultrasonication/PLA template replication/infiltration | σe = 5.12 S/m ε = 340% εr = 50% | next-generation stretchable electronics | [51] | ||
foamed seamless hSWCNT/G | non- foamed PDMS | 1:6 1:5 1:3 1:1 | 0.25 0.27 0.28 0.35 | sol-gel self-assembly/ ultrasonication/stirring/ freeze-drying/annealing/ vacuum backfilling | σe = 120 S/m SE = 31 dB SSE = 110 dB·cm3/g RS = 7.94 MPa | EMI shielding | [56] |
foamed seamless hMWCNT/G | 1:3 | 0.95 0.96 0.97 0.98 1.03 1.05 | ethanol solution blending/ultrasonication/freeze-drying/annealing/ vacuum infiltration | σe = 100.99 S/m SE = 54.43 dB SSE = 87.86 dB·cm3/g RS = 3.34 MPa λ = 0.29 W/m·K | EMI shielding | [30] | |
1:1 | 1.3 | sol-gel synthesis/ ultrasonication/freeze-drying/pyrolysis/ vacuum infiltration | σe = 280 S/m εr = 20% | electronic textiles and smart clothing | [58] | ||
foamed seamless vMWCNT/G | n/a | 2.5 5.0 10.0 | aqueous solution blending/ freeze-drying/CVD/stirring | Γ = −55 dB SE = 10 dB | EMI shielding | [59] | |
n/a | n/a | Ni template-directed CVD/CVD/infiltration | GF = 35 εr = 85% | strain sensing for wearable electronics, health monitoring, etc. | [57] | ||
foamed assembled hMWCNT/G | 2:2.7 | 4.7 | Ni template-directed CVD/ethyl acetate solution blending/ ultrasonication/ infiltration | σe = 3150 S/m SE = 75 dB SSE = 833 dB·cm3/g | EMI shielding | [60] | |
1:1 | 2.0 | Ni template-directed CVD/ethyl acetate solution blending/ sonication/ stirring/infiltration | α = 0.3 | low-frequency noise shielding | [62] |
References
- Mani, V.; Chen, S.M.; Lou, B. Three dimensional graphene oxide-carbon nanotubes and graphene-carbon nanotubes hybrids. Int. J. Electrochem. Sci. 2013, 8, 11641–11660. [Google Scholar]
- Fan, W.; Zhang, L.; Liu, T. Strategies for the hybridization of CNTs with graphene. In Graphene-Carbon Nanotube Hybrids for Energy and Environmental Applications; Springer: Singapore, 2017; pp. 21–51. [Google Scholar]
- Matsumoto, T.; Saito, S. Geometric and electronic structure of new carbon-network materials: Nanotube array on graphite sheet. J. Phys. Soc. Jpn. 2002, 71, 2765–2770. [Google Scholar] [CrossRef] [Green Version]
- Liang, X.; Cheng, Q. Synergistic reinforcing effect from graphene and carbon nanotubes. Compos. Commun. 2018, 10, 122–128. [Google Scholar] [CrossRef]
- Zhang, H.; Zhang, G.; Tang, M.; Li, J.; Fan, X.; Shi, X.; Qin, J. Synergistic effect of carbon nanotube and graphene nanoplates on the mechanical, electrical and electromagnetic interference shielding properties of polymer composites and polymer composite foams. Chem. Eng. J. 2018, 353, 381–393. [Google Scholar] [CrossRef]
- Yu, J.; Choi, H.; Kim, H.; Kim, S. Synergistic effect of hybrid graphene nanoplatelet and multi-walled carbon nanotube fillers on the thermal conductivity of polymer composites and theoretical modeling of the synergistic effect. Compos. Part A Appl. Sci. Manuf. 2016, 88, 79–85. [Google Scholar] [CrossRef]
- Li, Y. Synergistic effect of carbon nanotube and graphene on multifunctional properties of their polymer composites. In Multifunctionality of Polymer Composites; Elsevier: Amsterdam, The Netherlands, 2015; Chapter 16; pp. 527–548. [Google Scholar]
- Singh, N.P.; Gupta, V.K.; Singh, A.P. Graphene and carbon nanotube reinforced epoxy nanocomposites: A Review. Polymer 2019, 180, 121724. [Google Scholar] [CrossRef]
- Wang, J.; Jin, X.; Wu, H.; Guo, S. Polyimide reinforced with hybrid graphene oxide @ carbon nanotube: Toward high strength, toughness, electrical conductivity. Carbon 2017, 123, 502–513. [Google Scholar] [CrossRef]
- Joseph, J.; Munda, P.R.; John, D.A.; Sidpara, A.M.; Paul, J. Graphene and CNT filled hybrid thermoplastic composites for enhanced EMI shielding effectiveness. Mater. Res. Express 2019, 6, 085617. [Google Scholar] [CrossRef]
- Srivastava, S.K.; Mishra, Y.K. Nanocarbon reinforced rubber nanocomposites: Detailed Insights about mechanical, dynamical mechanical properties, payne, and mullin effects. Nanomaterials 2018, 8, 945. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Kausar, A. Polydimethylsiloxane-based nanocomposite: Present research scenario and emergent future trends. Polym. Plast. Technol. Mater. 2020, 59, 1–19. [Google Scholar] [CrossRef]
- Ma, Y.; Chen, Y. Three-dimensional graphene networks: Synthesis, properties and applications. Natl. Sci. Rev. 2015, 2, 40–53. [Google Scholar] [CrossRef] [Green Version]
- Wallace, J.; Shao, L. Defect-induced carbon nanoscroll formation. Carbon 2015, 91, 96–102. [Google Scholar] [CrossRef] [Green Version]
- Dang, V.T.; Nguyen, D.D.; Cao, T.T.; Le, P.H.; Tran, D.L.; Phan, N.M.; Nguyen, V.C. Recent trends in preparation and application of carbon nanotube–graphene hybrid thin films. Adv. Nat. Sci. Nanosci. Nanotechnol. 2016, 7, 033002. [Google Scholar] [CrossRef] [Green Version]
- Zhang, C.; Ren, L.; Wang, X.; Liu, T. Graphene Oxide-Assisted Dispersion of Pristine Multiwalled Carbon Nanotubes in Aqueous Media. J. Phys. Chem. C 2010, 114, 11435–11440. [Google Scholar] [CrossRef]
- Zhang, L.; Xiong, Z.; Zhao, X. Pillaring Chemically Exfoliated Graphene Oxide with Carbon Nanotubes for Photocatalytic Degradation of Dyes under Visible Light Irradiation. ACS Nano 2010, 4, 7030–7036. [Google Scholar] [CrossRef]
- Dong, X.; Xing, G.; Chan-Park, M.; Shi, W.; Xiao, N.; Wang, J.; Yan, Q.; ChienSum, T.; Huang, W.; Chen, P. The formation of a carbon nanotube–graphene oxide core–shell structure and its possible applications. Carbon 2011, 49, 5071–5078. [Google Scholar] [CrossRef]
- Gorkina, A.; Tsapenko, A.; Gilshteyn, E.; Koltsova, T.; Larionova, T.; Talyzin, A.; Anisimov, A.; Anoshkin, I.; Kauppinen, E.; Tolochko, O.; et al. Transparent and conductive hybrid graphene/carbon nanotube films. Carbon 2016, 100, 501–507. [Google Scholar] [CrossRef] [Green Version]
- Badhulika, S.; Terse-Thakoor, T.; Villarreal, C.; Mulchandani, A. Graphene hybrids: Synthesis strategies and applications in sensors and sensitized solar cells. Front. Chem. 2015, 3, 38. [Google Scholar] [CrossRef] [Green Version]
- Paul, R.; Vincent, M.; Etacheri, V.; Roy, A.K. Carbon nanotubes, graphene, porous carbon, and hybrid carbon-based materials: Synthesis, properties, and functionalization for efficient energy storage. In Carbon Based Nanomaterials for Advanced Thermal and Electrochemical Energy Storage and Conversion; Elsevier: Amsterdam, The Netherlands, 2019; pp. 1–24. [Google Scholar]
- Zhu, Y.; Li, L.; Zhang, C.; Casillas, G.; Sun, Z.; Yan, Z.; Ruan, G.; Peng, Z.; Raji, A.-R.O.; Kittrell, C.; et al. A seamless three-dimensional carbon nanotube graphene hybrid material. Nat. Commun. 2012, 3, 1225–1228. [Google Scholar] [CrossRef] [PubMed]
- Kosynkin, D.; Higginbotham, A.; Sinitskii, A.; Lomeda, J.R.; Dimiev, A.; Price, B.K.; Tour, J.M. Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. Nature 2009, 458, 872–876. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Li, Y.; Li, Z.; Lei, L.; Lan, T.; Li, Y.; Li, P.; Lin, X.; Liu, R.; Huang, Z.; Fen, X.; et al. Chemical vapor deposition-grown carbon nanotubes/graphene hybrids for electrochemical energy storage and conversion. FlatChem 2019, 15, 100091. [Google Scholar] [CrossRef]
- Aravind, S.; Eswaraiah, V.; Ramaprabhu, S. Facile synthesis of one dimensional graphene wrapped carbon nanotube composites by chemical vapour deposition. J. Mater. Chem. 2011, 21, 15179. [Google Scholar] [CrossRef]
- Creighton, J.R.; Ho, P. Introduction to chemical vapourdeposition (CVD). In Chemical Vapour Deposition; Park, J.H., Ed.; ASM International: Materials Park, OH, USA, 2001; pp. 1–10. [Google Scholar]
- Yang, H.; Yuan, L.; Yao, X.; Zheng, Z.; Fang, D. Monotonic strain sensing behavior of self-assembled carbon nanotubes/graphene silicone rubber composites under cyclic loading. Compos. Sci. Technol. 2020, 200, 108474. [Google Scholar] [CrossRef]
- Lee, D.H.; Kim, J.E.; Han, T.H.; Hwang, J.W.; Jeon, S.; Choi, S.; Hong, S.H.; Lee, W.J.; Ruoff, R.S.; Kim, S.O. Versatile carbon hybrid films composed of vertical carbon nanotubes grown on mechanically compliant graphene films. Adv. Mater. 2010, 22, 1247–1252. [Google Scholar] [CrossRef] [PubMed]
- Zhang, Y.L.; Zang, C.G.; Jiao, Q.J. Electrical, thermal, and mechanical properties of silicone foam composites filled with carbon-based nanofillers. J. Appl. Polym. Sci. 2020, 137, 49191. [Google Scholar] [CrossRef]
- Jia, H.; Kong, Q.Q.; Liu, Z.; Wei, X.-X.; Li, X.M.; Chen, J.-P.; Li, F.; Yang, X.; Sun, G.-H.; Chen, C.-M. 3D graphene/carbon nanotubes/polydimethylsiloxane composites as high-performance electromagnetic shielding material in X-band. Compos. Part A Appl. Sci. Manuf. 2020, 129, 105712. [Google Scholar] [CrossRef]
- Fink, K. Liquid Silicone Rubber: Chemistry, Materials, and Processing; Wiley: Hoboken, NJ, USA, 2019; p. 324. [Google Scholar]
- Ghaleb, Z.; Jaafar, M.; Rashid, A. Fabrication methods of carbon-based rubber nanocomposites and their applications. In Carbon-Based Nanofiller and Their Rubber Nanocomposites; Elsevier: Amsterdam, The Netherlands, 2019; pp. 49–63. [Google Scholar]
- Liang, A.; Jiang, X.; Hong, X.; Jiang, Y.; Shao, Z.; Zhu, D. Recent developments concerning the dispersion methods and mechanisms of graphene. Coatings 2018, 8, 33. [Google Scholar] [CrossRef] [Green Version]
- Hu, H.; Zhao, L.; Liu, J.; Liu, Y.; Cheng, J.; Luo, J.; Liang, Y.; Tao, Y.; Wang, X.; Zhao, J. Enhanced dispersion of carbon nanotube in silicone rubber assisted by graphene. Polymer 2012, 53, 3378–3385. [Google Scholar] [CrossRef]
- Pradhan, B.; Srivastava, S. Synergistic effect of three-dimensional multi-walled carbon nanotube–graphene nanofiller in enhancing the mechanical and thermal properties of high-performance silicone rubber. Polym. Int. 2014, 63, 1219–1228. [Google Scholar] [CrossRef]
- Oh, J.; Jun, G.; Jin, S.; Ryu, H.; Hong, S. Enhanced electrical networks of stretchable conductors with small fraction of CNT/graphene hybrid fillers. ACS Appl. Mater. Interfaces 2016, 8, 3319–3325. [Google Scholar] [CrossRef]
- Yang, H.; Yao, X.; Yuan, L.; Gong, L.; Liu, Y. Strain-sensitive electrical conductivity of carbon nanotube-graphene-filled rubber composites under cyclic loading. Nanoscale 2019, 11, 578–586. [Google Scholar] [CrossRef]
- Kantarak, E.; Rucman, S.; Kumpika, T.; Sroila, W.; Tippo, P.; Panthawan, A.; Sanmuangmoon, P.; Sriboonruang, A.; Jhuntama, N.; Wiranwetchayan, O.; et al. Fabrication, design and application of stretchable strain sensors for tremor detection in parkinson patient. Appl. Compos. Mater. 2020, 27, 955–968. [Google Scholar] [CrossRef]
- Lee, C.; Jug, L.; Meng, E. High strain biocompatible polydimethylsiloxane-based conductive graphene and multiwalled carbon nanotube nanocomposite strain sensors. Appl. Phys. Lett. 2013, 102, 183511. [Google Scholar] [CrossRef] [Green Version]
- Yan, J.; Jeong, Y.G. Synergistic effect of hybrid carbon fillers on electric heating behavior of flexible polydimethylsiloxane-based composite films. Compos. Sci. Technol. 2015, 106, 134–140. [Google Scholar] [CrossRef]
- Amrei, S.S.; Asghari, M.; Esfahanian, M.; Zahraei, Z. Highly selective CNT-coupled-GO-incorporated polydimethylsiloxane membrane for pervaporative membrane bioreactor ethanol production. J. Chem. Technol. Biotechnol. 2020, 95, 1604–1613. [Google Scholar] [CrossRef]
- Kumpika, T.; Kantarak, E.; Sriboonruang, A.; Sroila, W.; Tippo, P.; Thongpan, W.; Pooseekheaw, P.; Panthawan, A.; Jumrus, N.; Sanmuangmoon, P.; et al. Stretchable and compressible strain sensors for gait monitoring constructed using carbon nanotube/graphene composite. Mater. Res. Express 2020, 7, 035006. [Google Scholar] [CrossRef]
- Kim, T.; Park, J.; Sohn, J.; Cho, D.; Jeon, S. Bioinspired, highly stretchable, and conductive dry adhesives based on 1D–2D hybrid carbon nanocomposites for all-in-one ECG electrodes. ACS Nano 2016, 10, 4770–4778. [Google Scholar] [CrossRef]
- Barshutina, M.; Volkov, V.; Arsenin, A.; Yakubovsky, D.; Melezhik, A.; Blokhin, A.; Tkachev, A.; Lopachev, A.; Kondrashov, V. Biocompatible, electroconductive, and highly stretchable hybrid silicone composites based on few-layer graphene and CNTs. Nanomaterials 2021, 11, 1143. [Google Scholar] [CrossRef]
- Gaertner, G.; Knapp, W.; Forbes, R.G. Modern Developments in Vacuum Electron Sources; Springer: Berlin/Heidelberg, Germany, 2020. [Google Scholar]
- Shi, J.; Li, X.; Cheng, H.; Liu, Z.; Zhao, L.; Yang, T.; Dai, Z.; Cheng, Z.; Shi, E.; Yang, L.; et al. Graphene reinforced carbon nanotube networks for wearable strain sensors. Adv. Funct. Mater. 2016, 26, 2078–2084. [Google Scholar] [CrossRef]
- Zhao, S.; Bai, L.; Zheng, J. Facile preparation of carbon nanotubes–graphene hybrids and the effect of aspect ratio of carbon nanotubes on electrical and thermal properties of silicone rubber based composites. Mater. Res. Express 2018, 5, 015301. [Google Scholar] [CrossRef]
- Valentini, L.; Bittolo Bon, S.; Pugno, N.M. Graphene and carbon nanotube auxetic rubber bionic composites with negative variation of the electrical resistance and comparison with their nonbionic counterparts. Adv. Funct. Mater. 2017, 27, 1606526. [Google Scholar] [CrossRef]
- Abdelaal, O.; Darwish, S. Analysis, fabrication and a biomedical application of auxetic cellular structures. Int. J. Eng. Innov. Technol. 2012, 2, 218–223. [Google Scholar]
- Chen, M.; Zhang, L.; Duan, S.; Jing, S.; Jiang, H.; Li, C. Highly stretchable conductors integrated with a conductive carbon nanotube/graphene network and 3D porous poly(dimethylsiloxane). Adv. Funct. Mater. 2014, 24, 7548–7556. [Google Scholar] [CrossRef]
- Duan, S.; Yang, K.; Wang, Z.; Chen, M.; Zhang, L.; Zhang, H.; Li, C. Fabrication of highly stretchable conductors based on 3D printed porous poly(dimethylsiloxane) and conductive carbon nanotubes/graphene network. ACS Appl. Mater. Interfaces 2016, 8, 2187–2192. [Google Scholar] [CrossRef] [PubMed]
- Fang, Q.; Shen, Y.; Chen, B. Synthesis, decoration and properties of three-dimensional graphene-based macrostructures: A review. Chem. Eng. J. 2015, 264, 753–771. [Google Scholar] [CrossRef]
- Wang, Y.; Zhou, W.; Cao, K.; Hu, X.; Gao, L.; Lu, Y. Architectured graphene and its composites: Manufacturing and structural applications. Compos. Part A Appl. Sci. Manuf. 2020, 140, 106177. [Google Scholar] [CrossRef]
- Goh, P.S.; Ismail, A.F.; Ng, B.C. Directional alignment of carbon nanotubes in polymer matrices: Contemporary approaches and future advances. Compos. Part A Appl. Sci. Manuf. 2014, 56, 103–126. [Google Scholar] [CrossRef]
- Khan, F.; Kausar, A.; Siddiq, M. A Review on properties and fabrication techniques of polymer/carbon nanotube composites and polymer intercalated buckypapers. Polym. Plast. Technol. Eng. 2015, 54, 1524–1539. [Google Scholar] [CrossRef]
- Zhao, S.; Yan, Y.; Gao, A.; Zhao, S.; Cui, J.; Zhang, G. Flexible polydimethylsilane nanocomposites enhanced with a three-dimensional graphene/carbon nanotube bicontinuous framework for high-performance electromagnetic interference shielding. ACS Appl. Mater. Interfaces 2018, 10, 26723–26732. [Google Scholar] [CrossRef] [PubMed]
- Cai, Y.; Shen, J.; Dai, Z.; Zang, X.; Dong, Q.; Guan, G.; Li, L.-J.; Huang, W.; Dong, X. Extraordinarily stretchable all-carbon collaborative nanoarchitectures for epidermal sensors. Adv. Mater. 2017, 29, 1606411. [Google Scholar] [CrossRef] [PubMed]
- Chen, M.; Tao, T.; Zhang, L.; Gao, W.; Li, C. Highly conductive and stretchable polymer composites based on graphene/MWCNT network. Chem. Commun. 2013, 49, 1612–1614. [Google Scholar] [CrossRef] [PubMed]
- Kong, L.; Yin, X.; Yuan, X.; Zhang, Y.; Liu, X.; Cheng, L.; Zhang, L. Electromagnetic wave absorption properties of graphene modified with carbon nanotube/poly(dimethyl siloxane) composites. Carbon 2014, 73, 185–193. [Google Scholar] [CrossRef]
- Sun, X.; Liu, X.; Shen, X.; Wu, Y.; Wang, Z.; Kim, J. Reprint of graphene foam/carbon nanotube/poly(dimethyl siloxane) composites for exceptional microwave shielding. Compos. Part A Appl. Sci. Manuf. 2017, 92, 190–197. [Google Scholar] [CrossRef]
- Xia, Q.; Li, Y.; Cao, C.; Zhang, G.; Tang, L. Preparation, properties and application of silicone rubber foam composites. Mater. China 2018, 37, 168–177. [Google Scholar]
- Wu, Y.; Sun, X.; Wu, W.; Xu, L.; Xiuyi, L.; Xi, S.; Zhenyu, W.; Li, R.K.Y.; Zhiyu, Y.; Kin-Tak, L.; et al. Graphene foam/carbon nanotube/poly(dimethyl siloxane) composites as excellent sound absorber. Compos. Part A Appl. Sci. Manuf. 2017, 102, 391–399. [Google Scholar] [CrossRef]
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. |
© 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Barshutina, M.N.; Volkov, V.S.; Arsenin, A.V.; Nasibulin, A.G.; Barshutin, S.N.; Tkachev, A.G. Silicone Composites with CNT/Graphene Hybrid Fillers: A Review. Materials 2021, 14, 2418. https://doi.org/10.3390/ma14092418
Barshutina MN, Volkov VS, Arsenin AV, Nasibulin AG, Barshutin SN, Tkachev AG. Silicone Composites with CNT/Graphene Hybrid Fillers: A Review. Materials. 2021; 14(9):2418. https://doi.org/10.3390/ma14092418
Chicago/Turabian StyleBarshutina, Marie N., Valentyn S. Volkov, Aleksey V. Arsenin, Albert G. Nasibulin, Sergey N. Barshutin, and Alexey G. Tkachev. 2021. "Silicone Composites with CNT/Graphene Hybrid Fillers: A Review" Materials 14, no. 9: 2418. https://doi.org/10.3390/ma14092418