Ultrafine-Grained Ti-31Mo-Type Composites with HA and Ag, Ta2O5 or CeO2 Addition for Implant Applications
Abstract
:1. Introduction
2. Materials and Methods
2.1. Sample Preparation
- -
- ultrafine-grained Ti31Mo alloy—Ti31Mo
- -
- ultrafine-grained Ti31Mo alloy after NaOH 60 °C/24 h oxidation—Ti31Mo (Ox)
- -
- ultrafine-grained Ti31Mo alloy after hydrothermal treatment—Ti31Mo (HT)
- -
- ultrafine-grained Ti31Mo-5 wt. % HA composite—Ti31Mo5HA
- -
- ultrafine-grained Ti31Mo-5 wt. % HA-1 wt. % Ag composite—Ti31Mo5HA1Ag
- -
- ultrafine-grained Ti31Mo-5 wt. % HA-2 wt. % CeO2 composite—Ti31Mo5HA2CeO2
- -
- ultrafine-grained Ti31Mo-5wt. % HA-2 wt. % Ta2O5 composite—Ti31Mo5HA2Ta2O5
2.2. Materials Characterization
2.3. In Vitro Evaluation
3. Results
3.1. Crystal Structure, Phase Contents, the Morphology
3.2. Surface Properties
3.3. Corrosion and Surface Wetting Properties
3.4. Biocompatibility Studies
4. Discussion
5. Conclusions
Author Contributions
Funding
Informed Consent Statement
Conflicts of Interest
References
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Structure Parameters | Ti31Mo | sTi31Mo (Ox) | Ti31Mo (HT) | ||
---|---|---|---|---|---|
sig | - | 1.4629564 | 1.5791782 | 1.405559 | |
Rwp | [%] | 6.0970262 | 6.329574 | 5.535124 | |
Rexp | [%] | 4.167606 | 4.0081444 | 3.9381716 | |
Ti(β) | A | [%] | 100.00 | 95.07 | - |
a | [Å] | 3.2433(1) | 3.2426(1) | - | |
V | [Å3] | 34.1(0) | 33.5(0) | - | |
Ti3O | A | [%] | - | 4.93 | - |
a | [Å] | - | 5.1361(41) | - | |
c | [Å] | - | 9.5623(164) | - | |
V | [Å3] | - | 36.6(0) | - | |
Ca10(PO4)6(OH)2 | A | [%] | - | - | 81.23 |
a | [Å] | - | - | 9.4252(6) | |
c | [Å] | - | - | 6.8894(6) | |
V | [Å3] | - | - | 530.1(1) | |
CaHPO4·2H2O | A | [%] | - | - | 18.77 |
a | [Å] | - | - | 6.3748(32) | |
b | [Å] | - | - | 15.2564(58) | |
c | [Å] | - | - | 5.7910(31) | |
V | [Å3] | - | - | 487.8(7) |
Element | Line | Ti31Mo(Ox) | Ti31Mo(HT) |
---|---|---|---|
wt. % | wt. % | ||
Ti | Kα1 | 50.07 | 0.00 |
Mo | Lα1 | 41.63 | 0.00 |
Ca | Kα1 | 0.00 | 45.07 |
P | Kα1 | 0.00 | 24.28 |
O | Kα1 | 6.07 | 16.56 |
Na | Kα1 | 2.22 | 6.81 |
K | Kα1 | 0.00 | 7.28 |
Total | - | 100.00 | 100.00 |
2D Parameters | Ti31Mo | Ti31Mo (Ox) | Ti31Mo (HT) |
---|---|---|---|
Ra | 1.04 ± 0.13 | 2.40 ± 0.36 | 9.22 ± 1.93 |
Rt | 14.55 ± 0.78 | 22.18 ± 1.85 | 62.52 ± 10.85 |
Rz | 10.59 ± 0.77 | 15.70 ± 1.69 | 45.39 ± 5.95 |
Parameter | Unit | Ti31Mo | Ti31Mo (Ox) | Ti31Mo (HT) |
---|---|---|---|---|
W | (mg/day) | 0.0496(16) | 0.0357(22) | 0.0150(25) |
Diiodomethane CA | (°) | 58.76 ± 4.54 | 46.16 ± 5.71 | impossible to measure |
Glycerol CA | (°) | 50.12 ± 1.39 | 55.97 ± 5.31 | 31.28 ± 2.78 |
Surface free energy | (mN/m) | 43.16 ± 0.37 | 42.54 ± 3.07 | - |
Disperse | (mN/m) | 29.29 ± 2.61 | 36.37 ± 3.10 | - |
Polar | (mN/m) | 13.87 ± 2.87 | 6.17 ± 1.41 | - |
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Sochacka, P.; Jurczyk, M.U.; Kowalski, K.; Wirstlein, P.K.; Jurczyk, M. Ultrafine-Grained Ti-31Mo-Type Composites with HA and Ag, Ta2O5 or CeO2 Addition for Implant Applications. Materials 2021, 14, 644. https://doi.org/10.3390/ma14030644
Sochacka P, Jurczyk MU, Kowalski K, Wirstlein PK, Jurczyk M. Ultrafine-Grained Ti-31Mo-Type Composites with HA and Ag, Ta2O5 or CeO2 Addition for Implant Applications. Materials. 2021; 14(3):644. https://doi.org/10.3390/ma14030644
Chicago/Turabian StyleSochacka, Patrycja, Mieczyslawa U. Jurczyk, Kamil Kowalski, Przemyslaw K. Wirstlein, and Mieczyslaw Jurczyk. 2021. "Ultrafine-Grained Ti-31Mo-Type Composites with HA and Ag, Ta2O5 or CeO2 Addition for Implant Applications" Materials 14, no. 3: 644. https://doi.org/10.3390/ma14030644